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Charge-Orbital Ordered States in Manganese Oxides studied by High Resolution Electron Microscopy

Research Project

Project/Area Number 11440104
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 固体物性Ⅱ(磁性・金属・低温)
Research InstitutionTokyo Institute of Technology

Principal Investigator

YAMAMOTO Naoki  Tokyo Institute of Technology, Physics Department, Assoc. Professor, 大学院・理工学研究科, 助教授 (90108184)

Co-Investigator(Kenkyū-buntansha) MORI Shigeo  Osaka Prefecture University, Dept. Materials Science, Assoc. Professor, 総合科学部, 助教授 (20251613)
Project Period (FY) 1999 – 2001
Project Status Completed (Fiscal Year 2001)
Budget Amount *help
¥13,800,000 (Direct Cost: ¥13,800,000)
Fiscal Year 2001: ¥1,500,000 (Direct Cost: ¥1,500,000)
Fiscal Year 2000: ¥5,300,000 (Direct Cost: ¥5,300,000)
Fiscal Year 1999: ¥7,000,000 (Direct Cost: ¥7,000,000)
KeywordsManganese oxides / Correlated electron system / transition metal oxide / Nano-structure / Charge order / colossal magneto resistance / Lorenz electron microscopy / magnetic structure / 高分解能電子顕微鏡法 / 電荷・軌道秩序状態 / 高分解能電子顕微鏡 / 電荷・軌道秩序 / 金属-絶縁体転移 / 相分離
Research Abstract

Manganese oxides show several characteristic properties such as metal-insulator phase transition, colossal magneto resistance and charge-orbital ordered phases due to strong interactions among charge/orbitals of d electrons, their spin system, and lattice system, Recently by transmission electron microscopy we found the coexistence of the charge ordered (CO) phase and ferromagnetic metal (FM) phase, which are closely related to the colossal magneto resistance and charge-orbital ordered phases. In the present study we investigated nano-structure of the phase separated state and charge/orbital ordered structure using a high resolution transmission electron microscope and Lorenz electron microscope. We observed the coexistence of the CO phase and FM phase in La_<1-x>Ca_xMnO_3, and found that the paired Jahn-Teller stripes (PJTS) play an important role in forming nano-structures of the coexistence state. The effect of substitution of the Mn site with Cr ion is also studied. Lorenz electron microscope reveals that large domains of FM phase and CO phase coexist on a micrometer scale in (La_<5/8-x>Pr_x)Ca_<3/8>MnO_3.

Report

(4 results)
  • 2001 Annual Research Report   Final Research Report Summary
  • 2000 Annual Research Report
  • 1999 Annual Research Report
  • Research Products

    (38 results)

All Other

All Publications (38 results)

  • [Publications] R.Shoji, S.Mori, N.Yamamoto, A.Machida, Y.Moritom: "Phase separation and destabilization in the charge ordered state of the Cr-doped manganites"J.Phys.Soc.Jpn. 70. 267 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K.Matsuno, T.Katsufuji, S.Mori, Y.Moritomo, et al.: "Charge ordering in the geometrically frustrated spinelAlV_2O_4"J.Phys.Soc.Jpn. 70,No.6. 4801 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Katsufuji, S Mori, M.Masaki, Y.Moritomo, et al.: "Dielectric and magnetic anomalies and spin frustration in hexagonal RMnO3(R=Y, Yb, and Lu)"Phys.Rev.B. 64. 104419 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] A.Machida, Y.Moritomo, S.Mori, N.Yamamoto et al.: "Microscopic charge separation in Tb_<1-X>Ca_xMnO_3 (x〜1)"J.Phys.Soc.Jpn.. 71. 27 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S.Mori, R.Shoji, N.Yamamoto, T.Katsufuji, A.Machda et al.: "Charge ordered state in the impurity-doped manganites"J.Phys.Soc.Jpn. (In press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S.Mori, R.Shoji, N.Yamamoto, T.Katsufuji: "Impurity effect on the charge ordered state in mangnaites"J. Phys.and Chem. of Solids. (In press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 山本直紀: "実験物理学講座5「構造解析」3-2節"丸善(株). 54 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S.Mori, C.H.Chen and S-W. Cheong: "Pairing of charge-ordered stripes in La_<1-x>Ca_xMnO_3"Nature. 392. 473 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S.Mori, C.H.Chen and S-W. Cheong: "Paired and unpaired charge stripes in the ferromagnetic phase of La_<0.5>Ca_<0.5>MnO_3"Phys. Rev. Lett.. 81. 3972 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y.Moritomo, A.Machida, S.Mori, N.Yamamoto and A.Nakamura: "Electronic phase diagram of Cr-doped manganites"Phys. Rev.. B60. 9220 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S.Mori, T.Katsufuji, N.Yamamoto, C.H.Chen, and S-W.Cheong: "Microstructure related to charge and orbital ordering in Pr_<0.5>Ca_<0.5>MnO_3"Phys. Rev.. B59. 13573 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Katsufuji, S-W.Cheong, S.Mori and C.H.Chen: "Impurity effects on the Electronic/Magnetic ground states of Perovskite Manganites"J. Phys. Soc. Jpn.. 68. 1090 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] N.Fukumoto, S.Mori, N.Yamamoto, Y.Moritomo, T.Katsufuji, C.H.Chen and S-W.Cheong: "Structural feature related to charge ordering and metal-insulator transition in Nd_<0.5>Sr_<0.5>MnO_3"Phys. Rev. B60. 12963 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M.Uehara, S.Mori, C.H.Chen and S-W.Cheong: "Percolative phase separation and Colossal Magnetroresistance in mixed-valence manganites"Nature. 399. 560 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] C.H.Chen, S.Mori and S-W.Cheong: "Anomalous melting transition of the charge-ordered state in manganites"Phys. Rev. Lett.. 83. 4792 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] A.Machida, Y.Moritomo, N.Nishibori, M.Tanaka, M.Sakata, K.Ohyama, S.Mori, N.Yamamoto and A.Nakamura: "Phase separation and insulator-metal behavior of doped manganites"Phys. Rev.. B62. 3883-3887 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] A.Machida, M.Itoh, Y.Moritomo, S.Mori, N.Yamamoto, K.Ohoyama and A.Nakamura: "Electronic phase diagram in bandwidth controlled manganites"Physica. B281&282. 524 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] R.Shoji, S.Mori, N.Yamamoto, A.Machida and Y.Moritomi: "Phase separation and destabilization in the charge ordered state of the Cr-doped manganites"J. Phys. Soc. Jpn.. 70. 267 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K.Matsuno, T.Katsufuji, S.Mori, Y.Moritomo, A.Machida, and H.Takagi: "Charge ordering in the geometrically frustrated spinelAlV_2O_4"J. Phys. Soc. Jpn.. 70, No.6. 4801-4804 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Katsufuji, S. Mori, M. Masaki, Y. Moritomo, N. Yamamoto, and H. Takagi: "Dielectric and magnetic anomalies and spin frustration in hexagonal RMnO3(R=Y, Yb, and Lu)"Phys. Rev.. B64. 104419 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] A. Machida, Y. Moritomo, S. Mori, N. Yamamoto, K. Ohoyama, E. Nishibori, M. Takata, M. Sakata, T. Otomo, and A. Nakamura: "Microscopic charge separation in Tb_<1-x>Ca_xMnO_3 (x〜1)"J. Phys. Soc. Jpn.. 71, 27. (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S.Mori, R.Shoji, N.Yamamoto, T.Katsufuji, A.Machida and Y. Moritomo: "Charge ordered state in the impurity-doped manganites"J. Phys. Soc. Jpn.. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S.Mori, R.Shoji, N.Yamamoto, T.Katsufuji: "Impurity effect on the charge ordered state in mangnaites"J. Phys. and Chem. of Solids. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] R.Shoji, S.Mori, N.Yamamoto, A.Machida, Y.Moritom: "Phase separation and destabilization in the charge ordered state of the Cr-doped mangnites"J. Phys. Soc. Jpn.. 70. 267 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] K.Matsuno, T.Katsufuji, S.Mori, Y.Moritomo, et al.: "Charge ordering in the geometrically frustrated spineelAlV_2O_4"J. Phys. Soc. Jpn.. 70,No.6. 4801 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] T.Katsufuji, S.Mori, M.Masaki, Y.Moritomo, et al.: "Dielectric and magnetic anomalies and spin frustration in hexagonal RMnO3(R=Y, Yb, and Lu)"Phys. Rev. B.. 64. 104419 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] A.Machida, Y.Moritomo, S.Mori, N.Yamamoto, et al.: "Microscopic charge separation in Tb_<1-x>Ca_3MnO_3(x(8160)161)"J. Phys. Soc. Jpn.. 71. 27 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] R.Shoji,S.Mori,N.Yamamoto: "Phase separation and destabilization of Charge-Ordered State in Cr-doped Manganites"J.Phys.Soc.Jpn. 70. 267-271 (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] S.Mori et.al,: "Microstructure related to the charge and orbital ordered state in doped manganites"J.Appl Phys. (in press).

    • Related Report
      2000 Annual Research Report
  • [Publications] S.Mori et al.,: "Charge-ordered phase and ordering dyanamics in Cr-doped perovskite manganese oxides"Proceedings of the 7^<th>international symposium on advanced materials. 53 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] K.Fujishiro et al.,: "Optical and structural studies of long-range order development in relaxor ferroelectrics"J.Phys.Soc.Jpn. 69. 2331-2338 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] A.Machida et al,: "Phase separation and insulator-metal behavior of doped manganites"Physical Review B. 62. 3883-3887 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] M.Uehara.S.Mori.C.H.Chen and S-W.Cheong: "Percolative phase separation & colossal Magnetoresistance in Mixed-Valent Manganites"Nature (London). 399. 560-563 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] S.Mori,T.Katsufuji,N.Yamamoto C.H.Chen and S-W Cheong: "Microstructuve related to the charge and orbital ordering in Pro._5Cao._5MnO_3"Physical Review B. 59. 13555-13558 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Katsufuji,S.Mori,S.W.Cheong and C.H.Chen: "Impurity effect on the Rlectric/magnetic ground state of Perovskite Manganites"J.Phys.Soc.Jpn. 68. 1090-1093 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Y.Moritomo,A.Machida,S.Mori,N.Yamamoto and A.Nakamura: "Electronic phase diagram and phase separation in Cr-doped manganites"Physical Review B. 60. 9220-9223 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] N.Fukumoto,S.Mori,N.Yamamoto: "Microscopic electronic phase separation and metal-insulator transition in Ndo_5Sro._5MnO_3"Physical Review B. 60. 12963-12967 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] C.H.Chen,S.Mori and S-W Cheong: "Anomalous melting transition of charge-ordered state in Manganites"Physical Review Letters. 83. 4792-4795 (1999)

    • Related Report
      1999 Annual Research Report

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Published: 1999-04-01   Modified: 2020-05-15  

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