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Plasma processing for carbon-based field-emission materials and their charactersit

Research Project

Project/Area Number 11450271
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Material processing/treatments
Research InstitutionNagoya University

Principal Investigator

SUGIMURA Hiroyuki  Nagoya Univ. Graduate School of Eng. Associate Professor, 工学研究科, 助教授 (10293656)

Co-Investigator(Kenkyū-buntansha) INOUE Yasushi  Nagoya Univ. Research Center for Nuclear Materials Recycle, Associate Professor, 環境量子リサイクル研究センター, 助教授 (10252264)
TAKAI Osamu  Nagoya Univ. Graduate School of Eng. Professor, 工学研究科, 教授 (40110712)
Project Period (FY) 1999 – 2001
Project Status Completed (Fiscal Year 2001)
Budget Amount *help
¥12,700,000 (Direct Cost: ¥12,700,000)
Fiscal Year 2001: ¥1,700,000 (Direct Cost: ¥1,700,000)
Fiscal Year 2000: ¥4,900,000 (Direct Cost: ¥4,900,000)
Fiscal Year 1999: ¥6,100,000 (Direct Cost: ¥6,100,000)
Keywordsdiamond / diamond-like carbor / carbon nitride / field emission / 窒素炭素 / 窒化欄素 / 微細加工 / プラズマ合成 / 電流計測 / 走査型プローブ顕微鏡
Research Abstract

Field emission characteristics of amorphous carbon nitride (a-C : N) thin films were studied in the applied field strength range of up to 20 V/μm with comparing the characteristics of amorphous carbon (a-C) thin films. Both a-C : N and a-C films were deposited on Si substrates by means of shielded arc ion plating (SAIP) using nitrogen or argon as an operating gas, respectively, and graphite as a solid carbon source. The a-C : N films showed better field emission characteristics, that is, lower threshold field strengths and higher maximum emission current densities, than the a C films. Nitrogen doping to a-C was found to be effective in order to improve the field emission characteristics. Among all of the fabricated a-C : N films, the film containing 23% nitrogen, prepared using a nitrogen arc plasma at a pressure of 1 Pa with applying a sample bias voltage of 100 V, showed the lowest thresholdrfield and the highest emission current density. Furthermore, thickness of this a-C : N was optimized to be ca. 40 nm in order to the best field emission characteristics , that is, a threshold field of 12 V/μm and a emission current density of 3.6 μA/cm^2 at a field of 20 V/μm.

Report

(4 results)
  • 2001 Annual Research Report   Final Research Report Summary
  • 2000 Annual Research Report
  • 1999 Annual Research Report
  • Research Products

    (22 results)

All Other

All Publications (22 results)

  • [Publications] H.Suhimura et al.: "Characterization of individual diamond crystals in micro diamond arrays using an AFM-based technique"Appi. Surf. Sci.. 144-145. 593-597 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y.Sakamoto et al.: "Site-selective plasma CVD based on catalytic nucleation enhancement : Fabrication of micro diamond arrays"Diamond and Related Material. 8. 1423-1426 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] H.Sugimura et al.: "Fabrication of micro diamond array and electrical characterization of individual diamond microcrystals by scanning probe microscopy"J. Vac. Sci. Technol. E. 15. 1919-1922 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] H.Sugimura et al.: "Electron field emission from nitorgen-doped amorphous carbon thin films prepared by arc ion plating"Proceeeings of Second International Conference on Processing Materials for Properties. 315-318 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] H.Sugimura et al.: "Field emission properties of amorphous carbon nitride thin films prepared by arc ion Plating"Surface and Coatings Technology. 142-144. 714-718 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] H.Sugimura et al.: "Electron Field Emission from Thin Films of Amorphous Carbon Nitride Synthesized by Arc Ion Plating"Thin Solid Films. (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Hiroyuki Sigimura, Yoshiki Sato, Kazuya Ushiyama, Osamu Takai, Yukihiro Sakamoto, Matsufumi Takaya and Nobuyiki Nakagiri: "Characterization of individual diamond crystals in micro diamond arrays using an AFM-based technique"Appl. Surf. Sci.. Vol. 144-145. 593-597 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Yukihiro Sakamoto, Matsufumi Takaya, Hiroyuki Sugimura, Osamu Takai and Nobuyuki Nakagiri: "Site-selective plasma CVD based on catalytic nucleation enhancement : Fabrication of micro diamor arrays"Diamond and Related Materials. Vol.8 No.8-9. 1423-1426 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Hiroyuki Sigimura, Yoshiki Sato, Kazuya Ushiyama, Osamu Takai, Yukihiro Sakamoto, Matsufumi Takaya and Nobuyiki Nakagiri: "Fabrication of micro diamond array and electrical characterization of individual diamond microcrystals by scanning probe microscopy"J. Vac. Sci. Technol. B. Vol. 17 No.5. 1919-1922 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Hiroyuki Sugimura, Yoshiki Sato, Nobuhiro Yajima and Osamu Takai: "Electron field emission from nitorgen-doped amorphous carbon thin films prepared by arc ion platin"Proceedings of Second International Conference on Processing Materials for Properties (The Minerals, Metals & Materials Society) San Francisco. Nov. 5-8. 315-318 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Hiroyuki Sugimura, Yoshiki Sato, Nobuhiro Tajima and Osamu Takai: "Field emission properties of amorphous carbon nitride thin films prepared by arc ion plating"Surface and Coating Technology. Vol. 142-144. 714-718 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Hiroyuki Sugimura, Yoshiki Sato, Yoshiaki Ando, Nobuhiro Tajima and Osamu Takai: "Electron Fiefi Emission from Thin Films of Amorphous Carbon Nitride Synthesized by Arc Ion Plating"Thin Solid Films. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] H. Sugimura et al.: "Elctron Field Emission from Thin Films of Amorphous CarbonNitride Synthesized by Arc Ion Plating"Thin Solid Films. (印刷中). (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] H. Sugimura et al.: "Field emission properties of amorphous carbon nitride thin films prepared by arc ion plating"Surface and Coatings Technolog. 142-144. 714-718 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] H. Sugimura et al.: "Electron field emission from nitorgen-doped amorphous carbon thin films prepared by arc ion plating"Proceedings of Second International Conference on Processing Materials for Properties. 315-318 (2000)

    • Related Report
      2001 Annual Research Report
  • [Publications] H. Sugimura et al.: "Fabrication of micro diamond array and electrical characterization of individual diamond microcrvstals by scanning probe microscopy"J. Vac. Sci. Technol. B. 17. 1919-1922 (1999)

    • Related Report
      2001 Annual Research Report
  • [Publications] Y. Sakamoto et al.: "Site-selective plasma CVD based on catalytic nucleation enhancemer Fabrication of micro diamond arrays"Diamond and Related Material. 8. 1423-1426 (1999)

    • Related Report
      2001 Annual Research Report
  • [Publications] H. Sugimura et al.: "Characterization of individual diamond crystals in micro diamond amusing an AFM-based technique"Appl. Surf. Sci.. 144-145. 593-597 (1999)

    • Related Report
      2001 Annual Research Report
  • [Publications] H.Sugimura 他: "Field emission properties of amorphous carbon nitride thin films prepared by arc ion plating"Surface and Coating Technology.. (印刷中). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] H.Sugimura 他: "Characterization of individual diamond crystals in micro diamond arrays using an AFM-based technique"Appl. Surf. Sci.. 144-145. 593-597 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Y.Sakamoto 他: "Site-selective plasma CVD based on catalytic nucleation enhancement: Fabrication of micro diamond arrays"Diamond and Related Materials. 8(8-9). 1423-1426 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H.Sugimura 他: "Fabrication of micro diamond array and electrical characterization of individual diamond microcrystals by scanning probe microscopy"J. Vac. Sci. Technol. B. 17(5). 1919-1922 (1999)

    • Related Report
      1999 Annual Research Report

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Published: 1999-04-01   Modified: 2016-04-21  

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