| Budget Amount *help |
¥14,300,000 (Direct Cost: ¥14,300,000)
Fiscal Year 2001: ¥2,600,000 (Direct Cost: ¥2,600,000)
Fiscal Year 2000: ¥2,600,000 (Direct Cost: ¥2,600,000)
Fiscal Year 1999: ¥9,100,000 (Direct Cost: ¥9,100,000)
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| Research Abstract |
In this research, various structural Dendoriticc polymers which had been able to become the matrix polymer first of all in the future were synthesized. They are aroma family Poriamidodendorimar, the hyper branch polymer, the aroma family polyimide hyper branch polymer, and Porishirokisanhaiparbrantiporimar, etc. The acrylyl group was introduced into the end of this especially easy aroma family polyimide hyper branch polymer to synthesize, the copolymerization of those single polymerizations or the acrylate ester coexistence was done, and it succeeded in making of the complex which assumed the Dendoriticc polymer to be Kazunari amount. The complex's which had obtained it giving a tough film cpmpared with original Dendoriticcporiamid became clear. Next, the hyper branch polyamide silica complex was made by an anhydrous Zolugel reaction of Tetoraetokishishiran which used the formic acid under the hyper branch polyamide existence as a solvent and reactive Tamezai. It was possible to do, an
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d surprisingly, it became, and Sout succeeded in making a transparent film in the appearance of organic polymer and inorganic silica in this faction. This material is sure to be going to say the tough glass, and come not to crack easily because of the usual glass if it sees from the glass side. Moreover, the usage as the adhesive of the glass is thought because a uniform solution at the former stage of the Zolugel reaction. To introduce silicon into the hyper branch polymer side, the hyper branch polymer of the Porishirokisan frame was synthesized. When the amino group was introduced into the end radical of the obtained hyper branch polymer, it made having the character of one molecule micelle as it became meltable and a main chain took the coloring matter of hydrophobe into the hydrochloric acid water though it was Porishirokisan of hydrophobe clear. Moreover, radical Cyril was generated by an optical irradiation when the end was Fenilshiril radical, and constructing the hyper branch polymer happened. Less
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