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Synthesis of New Aprotic Polar Polymers

Research Project

Project/Area Number 11450357
Research Category

Grant-in-Aid for Scientific Research (B).

Allocation TypeSingle-year Grants
Section一般
Research Field 高分子合成
Research InstitutionKYOTO UNIVERSITY

Principal Investigator

CHUJO Yoshiki  Graduate School of Engineering, KYOTO UNIVERSITY Professor, 工学研究科, 教授 (70144128)

Co-Investigator(Kenkyū-buntansha) NAKA Kensuke  Graduate School of Engineering, KYOTO UNIVERSITY Associate Professor, 工学研究科, 助教授 (70227718)
Project Period (FY) 1999 – 2000
Project Status Completed (Fiscal Year 2000)
Budget Amount *help
¥13,400,000 (Direct Cost: ¥13,400,000)
Fiscal Year 2000: ¥4,300,000 (Direct Cost: ¥4,300,000)
Fiscal Year 1999: ¥9,100,000 (Direct Cost: ¥9,100,000)
KeywordsAprotic Polar Polymers / Aprotic Polar Solvents / DMAC / DMSD / HMPA / Amphiphilicity / Miscibility / Polymer Reaction
Research Abstract

N, N-Dimethylacetamide (DMAc), dimethyl sulfoxide (DMSO), and hexamethyl-phosphoric triamide (HMPA) are unique and useful aprotic polar solvents in organic synthesis. In this research project, the polymer homologues of these polar solvents were synthesized.
First, the polymer homologue of DMSO was prepared. Aliphatic polysulfoxides were successfully synthesized from the corresponding aliphatic polysulfides by the oxidation using hydrogen peroxide. The polysulfoxides obtained were used as oxidizing reagents in Swern oxidation. A real polymer homologue of DMSO, poly-(ethylene sulfoxide) was prepared by selective oxidation of poly (ethylene sulfide).
The poly (HMPA) was synthesized by the polymer reaction of linear poly (ethyleneimine) with bis (dimethylamino) phosphoryl chloride in the presence of DBU.The poly (HMPA) obtained showed good miscibility with commodity polymers such as polystyrene. The poly (HMPA) was also prepared by ring-opening polymerization of bis (dimethylamino) phosphorylpropylenimine.
As an example of poly (DMAc), poly (N, N-dimethylcarbamoylmethylene) having amide groups on all main chain carbons was successfully prepared by the polymer reaction of poly (fumaric acid).

Report

(3 results)
  • 2000 Annual Research Report   Final Research Report Summary
  • 1999 Annual Research Report
  • Research Products

    (24 results)

All Other

All Publications (24 results)

  • [Publications] T.Oyama,Y.Ohkubo,K.Naka,Y.Chujo: "Synthesis of Poly (HMPA) by Ring-Opening Polymerization"Polymer Journal. 31・6. 506-509 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Oyama,K.Naka,Y.Chujo: "Polymer Homolog of DMSO : Synthesis of Poly-(ethylene suldoxide) by selective Oxidation"Macromolecules. 32・16. 5240-5242 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Oyama,T.Fukui,K.Naka,Y.Chujo: "Synthesis of Poly (N,N-dimethylcarbamoylmethylene) as a Polymer Homolog of DMAC."Polymer Bulletin. 43・2/3. 183-190 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Oyama,Y.Chujo: "Synthesis of Highly Optically Active Polysulfoxides by Asymmetric Oxidation."Macromolecules. 32・23. 7732-7736 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Naka,E.Horii,Y.Chujo: "Synthesis and Optical Properties of Soluble Isoxazole-Containing Poly (p-phenylene)."Polymer Journal. 32・1. 73-74 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Imai,K.Adachi,K.Naka,Y.Chujo: "Photochromic Organic - Inorganic Polymer Hybrids from Spiropyran-Modified Poly DMAC."Polymer Bulletin. 44・1. 9-15 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Toshiyuki Oyama, Yasushi Ohkubo, Kensuke Naka, Yoshiki Chujo: "Novel Aprotic Polar Polymers 5. Synthesis of Poly (HMPA) by Ring-Opening Polymerization."Polym.J.. 31. 506 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Toshiyuki Oyama, Kensuke Naka, Yoshiki Chujo: "Polymer Homolog of DMSO.Synthesis of Poly (ethylene sulfoxide) by Selective Oxidation of Poly (ethylene sulfide)."Macromolecules. 32. 5240 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Toshiyuki Oyama, Tatsuki Fukui, Kensuke Naka, Yoshiki Chujo: "Synthesis of Poly (N, N-dimethylcarbamoylmethylene) as a Polymer Homolog of N, N-Dimethylacetamide."Polym.Bull.. 43. 183 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Toshiyuki Oyama, Yoshiki Chujo: "Synthesis of Highly Optically Active Polysulfoxides by Asymmetric Oxidation of Polysulfides."Macromolecules. 32. 7732 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Kensuke Naka, Etsuo Horii, Yoshiki Chujo: "Synthesis and Optical Properties of Soluble lsoxazole-Containing Poly (p-phenylene)-Related Polymer."Polym.J.. 32. 73 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Kyung-Min Kim, Yusuke Imai, Kensuke Naka, Yoshiki Chujo: "Synthesis and Characterization of New Side-Chain Liquid Crystalline Polyoxazolines."Polym.J.. 32. 657 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Oyama,Y.Ohkubo,K.Naka,Y.Chujo.: "Synthesis of Poly(HMPA) by Ring - Opening Polymerigation."Polymer Journal. 31・6. 506-509 (1999)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Oyama,K.Naka,Y.Chujo: "Polymer Homolog of DMSO : Synthesis of Polylethylene sulforidel by Selective Oxidation"Macromolecules. 32・16. 5240-5242 (1999)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Oyama,T.Fukui,K.Naka,Y.Chujo: "Synthesis of Poly(N,N - dimethylcarbamoylmethylene) as a Polymer Homolog of DMAc."Polymer Bulletin. 43・2/3. 183-190 (1999)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Oyama,Y.Chujo: "Synthesis of Highly Optically Active Poly - sulfoxides by Assymmetric Oxidation."Macromolecules. 32・23. 7732-7736 (1999)

    • Related Report
      2000 Annual Research Report
  • [Publications] K.Naka,E.Horii,Y.Chujo: "Synthesis and Optical Properties of Soluble Isoxazole - Containing Poly (p - phenylene)."Polymer Journal. 32・1. 73-74 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Y.Imai,K.Adachi,K.Naka,Y.Chujo: "Photochromic Organic - Inorganic Polymer Hybrids from Spiropyran - Modified PolyDMAc."Polymer Bulletin. 44・1. 9-15 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Oyama,Y.Ohkubo,K.Naka,Y.Chujo: "Synthesis of Poly (HMPA) by Ring-Opening Polymerigation"Polymer Journal. 31・6. 506-509 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Oyama,K.Naka,Y.Chujo: "Polymer Homolog of DMSO: Synthesis of Polylethy line sulfoxide) by Selective Oxidation"Macromolecules. 32・16. 5240-5242 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Oyama,T.Fukui,K.Naka,Y.Chujo: "Synthesis of Poly (N, N-dimethylcarbomoylmethylene) as a Polymer Homolog of DMAC"Polymer Bulletin. 43・2/3. 183-190 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Oyama,Y.Chujo: "Syrothesis of Highly Optically, Active Polysultoxides by Asymmetric Oxidation"Macromolecules. 32・23. 7732-7736 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] K.Naka,E.Horii,Y.Chujo: "Synthesis and Optical Properties of Soluble Isoxazole-Containing Poly (p-phenylene)"Polymer Journal. 32・1. 73-74 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Y.Imai,K.Adachi,K.Naka,Y.Chujo: "Photochromic Organic-Inorganic Polymer Hybrids from Spiropyron-Modified Poly (DMAc)"Polymer Bulletin. 44・1. 9-15 (2000)

    • Related Report
      1999 Annual Research Report

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Published: 1999-04-01   Modified: 2016-04-21  

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