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The structure control of metal fine particle with micelle structure and the development of ferromagnet

Research Project

Project/Area Number 11490003
Research Category

Grant-in-Aid for Scientific Research (B).

Allocation TypeSingle-year Grants
Section一般
Research Field 広領域
Research InstitutionUtsunomiya University

Principal Investigator

INO Shozo  Fuculty of Engineering, Utsunomiya University Professor, 工学部, 教授 (70005867)

Co-Investigator(Kenkyū-buntansha) MINAMI Nobumasa  Fuculty of Edcation, Utsunomiya University Assistant, 教育学部, 助手 (80292572)
EGAWA Thikasi  Fuculty of Engineering, Utsunomiya University Associate Professor, 工学部, 助教授 (30151963)
ISHII Kiyoshi  Fuculty of Engineering, Utsunomiya University Associate Professor, 工学部, 助教授 (30134258)
TAKAMI Tomohide  Thohoku Univ. Reseach Institute for Scientific Measurements, Assistant, 科学計測研究所, 助手 (40272455)
Project Period (FY) 1999 – 2000
Project Status Completed (Fiscal Year 2000)
Budget Amount *help
¥14,200,000 (Direct Cost: ¥14,200,000)
Fiscal Year 2000: ¥5,000,000 (Direct Cost: ¥5,000,000)
Fiscal Year 1999: ¥9,200,000 (Direct Cost: ¥9,200,000)
Keywordsmetal fine particle / organic molecule / micelle structure / metal thin film / thin film fine structure / ferromagnetic film / X-ray spectroscopy / 金属微粒子 / 強磁性薄膜
Research Abstract

We have constructed an ultra-high vacuum apparatus in which we can acheave "in situ observation" of the structures, compositions, bonding states and magnetization processes in the growing process of MTP (Multiply Twnnned Particle) ultrafine particle. Besides, we have developed a new double crystal X-ray spectrometer combined with RHEED (Reflection High Energy Electron Diffraction). Using the apparatus, we measured the charactristic X-ray FeK α which were emitted from Fe thin film on Si (111) and a high resolution of 〜6.0 eV was achieved.
Using these apparatus, we studied the structures and the corresponding magnetization processes in the growth processes of Fe, Nd and Fe-Nd alloy. According to the RHEED analysis, we discovered that the structure of grown Nd film is not the bulk ABAC type hcp structure but fcc.
We made "MTP nano micelle" by dissolving the evaporated Au/NaCl multi layer film in the thiol (β-mercaptopropionic acid) solution. We found that the optimum concentration of thiol … More was 〜1.0×10^<-3> mol/l. We observed hexagonal net works of the MTP micelle in the electron micrographs taken from the micelles made with optimum concentration of thiol. The observed gap beween the particles were 〜12Å which corresponds to the twice of the length of the thiole molecules.
We have developed a new method to make the granuler magnetic material by mixing the different metal vapors after the condensation of fine particles in the sputtering process in the rare gas. Applying the method, we made Fe granuler magnetic material of Fe/Ag system and studied the magnetic natures and found that the magnetic force works between the particles and the magnetic property can be controlled.
The fcc structure is formed when Fe thin film is grown on the Rh (001) surfece. We studied the structures in details in the growth process by LEED.The result was that the Fe film take fcc structure up to 3 monolayers and the lattice spacing of the 4th layer decreased quickly to transform to the bcc original structure. Less

Report

(3 results)
  • 2000 Annual Research Report   Final Research Report Summary
  • 1999 Annual Research Report
  • Research Products

    (36 results)

All Other

All Publications (36 results)

  • [Publications] 山中俊朗,井野正三: "Electron Standing Waves at a Surface during Reflection High Energy Electron Diffraction and Application on to Structure Analysis"International J.Modern Phys.. B14. 2171-2222 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 山中俊朗,井野正三: "Surface Electron Standing Waves and Adatom Hights on S1(111)-√<3>×√<3>-(Ga, In, Sn) Surface"Physical Review. B61. R5074-R5077 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 石井清,天野春日,濱欠裕貴: "Hollow Cathod Sputtering Cluster Source for Low Energy Deposition-Deposition of Fe Small Clusters-"J.Vacuum Science and Technol.. A17. 310-313 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 濱欠裕貴,石井清: "Preparation of Fe/Ag Granular Films by Low Energy Cluster Deposition"IEEE Transactions and Magnetics. 35. 3457-3459 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 江川千佳司: "Adsorption and Reaction of Ethylene and Hydrogen on Rh(100)Surface"Surface Science. 454-456. 222-226 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 江川千佳司,岩井秀和,大木昌一: "Ethylene Hydrogenation on fcc Co and Fe Thin Films Grown on Ni(100)"Surface Science. 454-456. 347-351 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 石井清: "Recent Research Development in Vacuum Science & Technology"Transworld Research Network. 12 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Yamanaka and S.Ino: "Electron Standing Waves at a Surface during Reflection High Energy Electron Diffraction and Apprication on to Structure Analysis"Int.J.Modern Phys.. B14. 2171-2222 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Yamanaka and S.Ino: "Anomalous X-ray Yields under Surface Waves Resonance during Reflection High Energy Electron Diffraction and Adatom Site Determination"Phys.Rev.Letters. 84. 4389-4392 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Yamanaka and S.Ino: "Surface Electron Standing Waves and Adatom Hights on Si (111)-√3×√3-(Ga, In, Sn) Surfaces"Phys.Rev.. B61 (Rapid Connuni.). R5074-R5077 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Yamanaka, N.Shimomura and S.Ino: "High-Resolution Observation of the Growth Motion of Elements on Surfaces and at Interfaces"Appl.Phys.Letters. 77. 3983-3985 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Yamanaka and S.Ino: "An Apparatus for Beam-Rocking Reflection High Energy Electron Diffraction and Total Reflection Angle X-ray Spectroscopy"Rev.Scientific Instr.. 72. 1477-1481 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Ishii, K.Amano and H.Hamakake: "Hollow Cathode Sputtering Cluster Source for Low Energy Deposition, -Deposition of Fe Small Clusters-"J.Vacuum.Sci.Technol.. A 17. 310-313 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Ishii, T.Naka and T.Ohba: "Structure and Magnetic Properties of Hexagonal-Close-Packed Co Films Deposited by Low Energy Sputtering"IEEE Trans. on Magn.. 35. 3019-3021 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Hamakake and K.Ishii: "Preparation of Fe/Ag Granular Films by Low Energy Cluster Deposition"IEEE Transactions on Magnetics. 35. 3457-3459 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Ishii: "A Versatile Cluster Source Utilizing Hollow Cathode Sputtering : Cluster Deposition for Producing some Nanostructured Thin Films"Recent Res.Devel.Vac.Sci. and Tech.. 1. 165-175 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] C.Egawa: "Adsorption and Reaction of Ethylene and Hydrogen on Rh (100) Surface"Surf.Sci.. 454-456. 222-226 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] C.Egawa, H.Iwai and S.Oki: "Ethylene Hydrogenation on fcc Co and Fe Thin Films Grown on Ni (100)"Surf.Sci.. 454-456. 347-351 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] C.Egawa, S.Endo, H.Iwai and S.Oki: "Ethylene Hydrogenation on Pt Thin Films on Ni (100) Surface"Surf.Sci.. 474. 14-20 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] C.Egawa, H.Iwai and S.Oki: "Ethylene Hydrogenation on fcc Ultra Thin Fe Films on a Rh (100) Surface-Effect of Co-Adsorbed CO and Growth Temperature-"Studies in Surf.Sci.and Catal.. 132. 673-676 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] C.Egawa, H.Iwai and S.Oki: "Ethylene Hydrogenation on fcc Co Thin Films on Ni (100) Surface"Studies in Surf.Sci. and Catal.. 132. 745-748 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Takami, K.Suzuki, I.Kusunoki, I.Sakaguchi, M.Nishitani-Gamo and T.Ando: "RHEED and AFM Studies of Homoepitaxial Diamond Thin Film on C (001) Substrate Produced by Microwave Plasma CVD"Diamond Relat.Mater.. 8. 701-704 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Takami, K.Suzuki, I.Kusunoki, I.Sakaguchi, M.Nishitani-Gamo, and T.Ando: "Diamond Thin Film Grown Homoepitaxially on Diamond (001) Substrate by Microwave Plasma CVD Method Studied by Reflection High Energy Electron Diffraction and Atomic Force Microscopy"Surf.Sci.. 440. 103-115 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 高見知秀,井野正三: "多重双晶粒子表面に有機分子が吸着した集合体-多重双晶粒子ミセル-"表面科学. 20. 220-227 (1999)

    • Related Report
      2000 Annual Research Report
  • [Publications] 佐藤崇文,河村真,析笠邦明,南伸昌,織田晃祐,井野正三: "反射高速電子回折と組合わせた精密X線分光装置の試作"真空. (印刷中). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] K.Ishii,K.Amano and H.Hamakaka: "Hollow cathode sputteing cluster source for low energy deposition : Deposition of Fe small clusters"Journal Vac.Sci.Technol.. A17. 310-313 (1999)

    • Related Report
      2000 Annual Research Report
  • [Publications] 石井清,濱欠裕貴: "ガスフロースパッタ法とグロニュラー〓性体の合成"日本応用〓気学会誌. 24. 1343-1348 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] C.Egawa,H.Iwai and S.oki: "Ethylene hydrogenation on fcc Co and Fe thin films grown on Ni(100) Surface"Surface Science. 454/456. 347-351 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] C.Eqawa,H.Iwai and S.Oki: "Ethylene hydrogenation on fcc ultia thin Fe films on a Rh(100) swiface"Studies Swface Suerue and catalysis. (印刷中). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] K.Ishii: "Recent research development in vacuam stience & techmalogy"Trano woild Roseaich Network. 165-177 (1999)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Yamanaka and S.Ino: "Surface electron standing waves and adatom heights on Si(III)-√<3>×√<3>-(Ga,In,Sn)surfaces"Physical Review. B61. R5074-R5077 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Yamanaka and S.Ino: "Anomalous X-ray yield under surface wave resonance during reflection high energy electron diffraction and…"Physical Review Letters. (印刷中). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] H.Hamakake, M.Inada, M.Wakairo and K.Ishii: "Effects of substrate temperature on the structure of Fe/Ag granular Films prepared by cluster Deposition"Proc. 2nd Magneto-Electronics Inter. Symposium. 2. 419-422 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] K.Ishii, T.Naka and T.Ohba: "Structure and magnetic properties of hexagonal-close-nacked Co films deposited by low energy sputtering"IEEE Trans. on Magn.. 33. 3457-3459 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] C.Egawa, H.Iwai and S.Oki: "Ethylene hydrognation on fcc Co and Fe thin films grown…"Surface Science. (印刷中). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Takami, K.Suzuki…: "RHEED and AFM studies of homoepitaxial diamond thin film on C(001) substrate produced by microwave plasma"Diamond Related Matters. 8. 701-704 (1999)

    • Related Report
      1999 Annual Research Report

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Published: 1999-04-01   Modified: 2016-04-21  

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