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Study of preparation of ceramics fibers by using sol-gel processing (Ceramics fiber prepared from complex alkoxide solution through ferroelectric materials and its application for sensor materials)

Research Project

Project/Area Number 11555169
Research Category

Grant-in-Aid for Scientific Research (B).

Allocation TypeSingle-year Grants
Section展開研究
Research Field Inorganic materials/Physical properties
Research InstitutionFUKUI NATIONAL COLLEGE OF TECHNOLOGY

Principal Investigator

TOYODA Masahiro  FUKUI NATIONAL COLLEGE OF TECHNOLOGY, CHEMISTRY AND BIOLOGY ENGINEERING, ASSOCIATE PROFESSOR, 物質工学科, 助教授 (00290742)

Co-Investigator(Kenkyū-buntansha) ANDO Akira  MURATA MANUFACTURING CO.LTD., FUNCTIONAL MATERIALS RESEARCH AND DEVELOPMENT.SECTION-I, MANAGER, 村田製作所・材料開発部・開発1課, 課長
Project Period (FY) 1999 – 2000
Project Status Completed (Fiscal Year 2000)
Budget Amount *help
¥9,900,000 (Direct Cost: ¥9,900,000)
Fiscal Year 2000: ¥2,700,000 (Direct Cost: ¥2,700,000)
Fiscal Year 1999: ¥7,200,000 (Direct Cost: ¥7,200,000)
KeywordsSol-gel / (Sr, Ba)NbO_6 / Sensor / Ceramics fiber / Hydrolysis / Complex alkoxide / 一次元重合体 / 重縮合反応 / (Sr,Ba)NbO_3 / 誘電体
Research Abstract

The sol-gel processing was applied to the fabrication of SrBaNb_2O_6 ceramics fibers. Sr methoxide, Ba methoxide, Nb pentaethoxide and ethylene glycol monoethyl ether as starting materials were selected and then reflux with stirring to form complex alkoxide. The hydrolysis and polycondensation of its alkoxide gave polymerized products, and as a result the viscosity of the solution increased, its suggested that linear polymer products were obtained. The (Sr, Ba)NbO_6 Gel fibers were drawn from the viscous solution. Its get fibers were crystallized into tungsten bronze phase at 800℃. The heat-treated fibers were a few centimeters long and from 30 to 200μm long in diameter. The dielectric constant was 450 at 400 Hz.

Report

(3 results)
  • 2000 Annual Research Report   Final Research Report Summary
  • 1999 Annual Research Report
  • Research Products

    (9 results)

All Other

All Publications (9 results)

  • [Publications] M.Toyoda and K.Shirono: "Preparation and Characterization of (Sr_<0.48>Ba_<0.52>)Nb_2O_6 Ceramics Fibers Through Sol-Gel Processing."Ceramic Transaction, J.Am.Ceram.Soc.,. (accepted)..

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Toyoda,Y.Muhamm,: "Preparation and Characterization of (Ba,Ca) (Ti,Zr)O_3 Thin Films through Sol-Gel Processing"J.Sol-Gel Sci.Tech.,). 16,#1/2,. 7-12 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Toyoda,J.Watanabe and T.Matsumiya,: "Evolution of Structure of the precursor during Sol-Gel Processing of Zinc Oxide and Low Temperature Formation of Thin Films"J.Sol-Gel.Sci.Tech.,. 16,#1/2,. 93-102 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Toyoda and K.Shirono: "Preparati and Characterization of (Sr_<0.48> Ba_<0.52>)Nb_2O_6 Ceramics Fibers through Sol-Gel Processing"Ceramic Transition, J.Am.Ceram.Soc.. (accepted).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Toyoda, Y.Muhamm: "Preparation and Characterization of (Ba, Ca)(Ti, Zr) O_3 Thin Films through Sol-Gel Processing"J.Sol-Gel Sci.Tech.. 16, #1/2. 7-12 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Toyoda, J.Watanabe and T.Matsumiya: "Evolution of Structure of the Precursor during Sol-Gel Processing of Zinc Oxide and Low Temperature Formation of Thin Films"J.Sol-Gel.Sci.Tech.. 16, #1/2. 93-102 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Toyoda and K.Shirono: "Preparation and Characterization of(Sr_<0.48>Ba_<0.52>)Nb_2O_6 Ceramics Fibers Through Sol-Gel Processing."Ceramic Transaction, J.Am.Ceram.Soc.,. (accepted)..

    • Related Report
      2000 Annual Research Report
  • [Publications] M.Toyoda,Y.Muhamm,: "Preparation and Characterization of (Ba,Ca) (Ti,Zr) O_3 Thin Films through Sol-Gel Processing"J.Sol-Gel Sci.Tech.,. 16,#1/2,. 7-12 (1999)

    • Related Report
      2000 Annual Research Report
  • [Publications] M.Toyoda,J.Watanabe and T.Matsumiya,: "Evolution of Structure of the precursor during Sol-Gel Processing of Zinc Oxide and Low Temperature Formation of Thin Films"J.Sol-Gel.Sci.Tech.,. 16,#1/2,. 93-102 (1999)

    • Related Report
      2000 Annual Research Report

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Published: 1999-04-01   Modified: 2016-04-21  

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