• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Microcapsules doped by metal elements

Research Project

Project/Area Number 11555170
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section展開研究
Research Field Composite materials/Physical properties
Research InstitutionGunma University

Principal Investigator

DOBASHI Toshiaki  Faculty of Engineering, Gunma University, Professor, 工学部, 教授 (30155626)

Co-Investigator(Kenkyū-buntansha) ICHIKAWA Kimio  Fuji Photo Film Co. Ltd., Fujinomiya Laboratory, Senior Scientist, 富士宮研究所, 主任研究員
YAGIHARA Shin  Tokai University, Faculty of Science, Professor, 理学部, 教授 (40191093)
Project Period (FY) 1999 – 2001
Project Status Completed (Fiscal Year 2001)
Budget Amount *help
¥12,800,000 (Direct Cost: ¥12,800,000)
Fiscal Year 2001: ¥3,200,000 (Direct Cost: ¥3,200,000)
Fiscal Year 2000: ¥7,000,000 (Direct Cost: ¥7,000,000)
Fiscal Year 1999: ¥2,600,000 (Direct Cost: ¥2,600,000)
Keywordsmicrocapsule / dielectric spectroscopy / ultrasonic method / Metal element / solid-type battery / β-ray therapy / 誘電分散 / 高分子 / 放射線治療
Research Abstract

The preparation method, structure, physicochemical properties and permeability were studied for microcapsules having poly(urea-urethane) wall membrane doped by metal elements and applied for solid battery and β-ray therapy.
1. Methodology to determine the microcapsule structure was established by means of single-particle light scattering and atomic force microscopy.
2. Theoretical studies on the permeability of the wall membrane was performed to assess the permeability of commercial dyes and pigments from the microcapsules.
3. Application of dielectric spectrometry for dispersed phase was attempted.
4. Combination of structure determination and ultrasonic measurements enabled us to estimate the compressibility of the wall membrane of microcapsules.
5. Mechanism of electric conductivity of microcapsules doped by Lithium compound was clarified.
6. Microcapsules containing Dy chelate compound were prepared and radioactivity from the microcapsules was estimated.

Report

(4 results)
  • 2001 Annual Research Report   Final Research Report Summary
  • 2000 Annual Research Report
  • 1999 Annual Research Report
  • Research Products

    (32 results)

All Other

All Publications (32 results)

  • [Publications] T.Dobashi: "Determination of the swelling ratio of poly(urea-urethane) microcapsules by sigle-particle light scattering"Langmuir. 17. 4525-4528 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 土橋敏明: "マイクロカプセルとレオロジー"日本バイオレオロジー学会誌. 15. 75-83 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S.Shimofure: "Preparation of microcapsules containing rare-earth metal elements"J. Microencap. 18. 13-17 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 八木原晋: "高分子と水の相互作用とダイナミクスー誘電緩和およびDSC測定"高分子. 49. 724-730 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S.Sudo: "Dielectric relaxation time and relaxation time distribution of alcohol-water mixtures"J. Phys. Chem.. (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] N.Shinyashiki: "Comparison of dielectric relaxations of water mixtures of poly(vinylpyrrolidone) and 1 -vinyl-2-pyrrolodinone"J. Phys. Chem.. 103. 4481-4484 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Dobashi: "Surface Characterization Method"Marcel Dekker. 412 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Dobashi: "Determination of the swelling ratio of poly (urea-urethane) microcapsules by single-particle light scattering"Langmuir. 17. 4525-4528 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Dobashi: "Microcapsules and Rheology"J. Jpn. Soc. Biorheol.. 15. 75-83 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S. Shimofure: "Preparation of microcapsules containing rare-earth metal elements"J. Microencap.. 18. 13-17 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S. Yagihara: "Interaction and dynamics of polymer and water - Dielectric relaxation and DSC measurement"Koubunshi.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S. Sudo: "Dielectric relaxation time and relaxation time distribution of alcohol-water mixtures"J. Phys. Chem.. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] N. Shinyashi: "Comparison of dielectric relaxations of water mixtures of poly(vinylpyrrolidone) and 1-vinyl-2-pyrrolidone"J. Phys. Chem.. 103. 4481-4484 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Dobashi: "Surface Characterization Method"Marcel Dekker (responsible for 20p). 412 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Dobashi: "Determination of the swelling ratio of poly(urea-urethane)microcapsules by single-particle light scattering"Langmuir. 17. 4525-4528 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 土橋敏明: "マイクロカプセルとレオロジー"日本バイオレオロジー学会誌. 15. 75-83 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] N.Miura: "Abnormal dielectric relaxation phenomena in mixture of polar liquid and conductive particles"J.Appl.Phys.. In press.

    • Related Report
      2001 Annual Research Report
  • [Publications] S.Sudo: "Dielectric relaxation time and relaxation time distribution of alcohol-water mixtures"J.Phys.Chem.. In press.

    • Related Report
      2001 Annual Research Report
  • [Publications] Y.Hayashi: "Ordering in aqueous polysaccharide solutions : I Dielectric relaxation in an aqueous solution of a triple-helical polysaccharide"Biopolymers. 63. 21-31 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 八木原晋: "誘電分光最近の動向"生物物理. 41. 240-243 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] S.Yagihara: "Microwave dielectric study on water structure and physical properties of aqueous systems using time domain reflectometry with flat-end cells"Subsurface Sensing Technologies and Applications. 2(1). 15-30 (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] 八木原晋: "高分子と水の相互作用とダイナミクス"高分子. 49. 724-729 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] S.Kouchi,T.Dobashi 他2名: "Volumetric phase transition of heat-set fish meat gel"Trans.MRS-J.. 25. 791-793 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Sato,T.Dobashi 他4名: "Effect of hydroxypropylmethylcellulose on Lower Critical Solution Temperature"Trans.MRS-J.. 25. 755-756 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Y.Hayashi,S.Yagihara 他3名: "Molecular dynamics of hinge-bending motion of IgG vanishing with the hydrolysis by papain"Biophys.J.. 79. 1023-1029 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] S.Yagihara: "Non-destructive testing in civil engineering"Application of the dielectric measurement for non-destructive test of mortar. 7 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Y.Toyama: "Erthrocyte aggregation enhanced by hydrostatic pressure"高圧力の科学と技術. 9. 142-145 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] R.Kita: "Simulation of Erythrocyte Aggregation under Gravity"Rept.Progr.Polym.Phys.Jpn. 42. 51-52 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] S.Shimofure: "Preparation of Microcapsules Containing Rare-Earth Metal Elements"Rept.Progr.Polym.Phys.Jpn. 42. 493-494 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] S.Shimofure: "Preparation of mirocapsules containing rare-earth metal elements"J.Microencapsulation. (印刷中). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] S.Shimofure: "Phase Equilibrium in Nonionic Surfactant with the Addition of Urea"Rept.Progr.Polym.Phys.Jpn. 42. 135-136 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Dobashi: ""Light Scattering Studies of Microcapsules in Suspension"in"Surface Characterization Methods:Principles,Techniques,and Applications""Marcel Dekker. 20 (1999)

    • Related Report
      1999 Annual Research Report

URL: 

Published: 1999-04-01   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi