| Project/Area Number |
11555187
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| Research Category |
Grant-in-Aid for Scientific Research (B).
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| Allocation Type | Single-year Grants |
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| Section | 展開研究 |
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| Research Field |
Material processing/treatments
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| Research Institution | OKAYAMA UNIVERSITY |
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Principal Investigator |
YOSHIO Tetuo OKAYAMA UNIVERSITY, Faculty of Environmental Science and Technology, Professor, 環境理工学部, 教授 (70032943)
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| Co-Investigator(Kenkyū-buntansha) |
TOMII Youich Faculty of Energy Science, Graduate School, Kyoto University, Associate Professor, 大学院・エネルギー科学研究科, 助教授 (90026245)
TAKADA Jun OKAYAMA UNIVERSITY, The Graduate School of Natural Science and Technology, Professor, 大学院・自然科学研究科, 教授 (60093259)
NAGAE Masahiro OKAYAMA UNIVERSITY, Faculty of Environmental Science and Technology, Research Fellow of the Japan Society for the Promotion of Science, 環境理工学部, 日本学術振興会特別研究員 (60304341)
KATO Yasuhiro Engineering Department, Sunric Co., Ltd, General Manager, 技術部・部長
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| Project Period (FY) |
1999 – 2000
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| Project Status |
Completed (Fiscal Year 2000)
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| Budget Amount *help |
¥13,700,000 (Direct Cost: ¥13,700,000)
Fiscal Year 2000: ¥5,800,000 (Direct Cost: ¥5,800,000)
Fiscal Year 1999: ¥7,900,000 (Direct Cost: ¥7,900,000)
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| Keywords | Internal Nitriding / Molybdenum Alloy / Molybdenum Nitrides / Precipitation Strengthening / Corrosion Resistance / Boiling Sulfuric Acid / 析出強化 |
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| Research Abstract |
For pure Mo and Mo-0.5 mass% alloy nitrided at 1073K to 1373K in NH_3 gas, the microstructural observations of molybdenum nitride layer were carried out through an optical and a transmission electron microscope and X-ray diffraction analysis. Corrosion behavior of the nitrided specimens was also examined. A surface nitriding layer consisted mainly of two Mo nitrides : an outer one of γ-Mo_2N and an inner one of β-Mo_2N.A great number of{011}<011>-type micro-twins were observed in the β-Mo_2N layer whereas the microstructure of the γ-Mo_2N layer is almost free from lattice defects. The nitrided specimens exhibited excellent corrosion resistance even in 75wt% sulfuric acid solution at the boiling temperature of 460.8K compared with unnitrided specimens. Its corrosion rate decreased with decreasing nitriding time because of the suppression of cracking by decreasing thickness of the surface nitriding layer. The corrosion rate of the specimen nitrided at 1123K for 24h was less than 0.001mm/y in boiling 75% sulfuric acid. In a nitrided Mo-0.5Ti alloy an internal nitriding layer with remarkably high hardness of Hv〜800 was formed beneath the surface nitriding layer. The high hardness is considered to be ascribed from fine dispersion of extremely small titanium nitride particles in the Mo matrix. The hardness in the internal nitriding layer gradually decreased as the distance from the interface increased.
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