| Project/Area Number |
11555213
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 展開研究 |
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| Research Field |
触媒・化学プロセス
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| Research Institution | Kyushu University |
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Principal Investigator |
KORAI Yozo Kyushu Univ. IAMS, associate Prof., 機能物質科学研究所, 助教授 (50122693)
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| Co-Investigator(Kenkyū-buntansha) |
KURODA Keiichi Kyushu Environmental Analyses, researcher, 分析化学部, 研究員
KAWABUCHI Yuji Petoca Co. Ltd., researcher, 新素材事業部研究部, 研究員
MOCHIDA Isao Kyushu Univ. IAMS, Prof., 機能物質科学研究所, 教授 (20037758)
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| Project Period (FY) |
1999 – 2002
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| Project Status |
Completed (Fiscal Year 2002)
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| Budget Amount *help |
¥8,300,000 (Direct Cost: ¥8,300,000)
Fiscal Year 2002: ¥2,700,000 (Direct Cost: ¥2,700,000)
Fiscal Year 2001: ¥2,800,000 (Direct Cost: ¥2,800,000)
Fiscal Year 2000: ¥2,800,000 (Direct Cost: ¥2,800,000)
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| Keywords | Activated carbon / Activated carbon fiber / surface area / Pore size distribution / oxygen functional group / nitrogen functional group / adsorbability / pore size / 硫黄酸化物 / 窒素酸化物 / ハロメタン / 排気ガス / 大気汚染物質 / キノリン / イソキノリン / ピッチ系活性炭素繊維 / 表面改質 / NaOH / 賦活 / 表面官能基 / CVD / ヘテロ原子 |
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| Research Abstract |
Pore size control of a series of active carbon fibers was attempted by CVD of benzene to clarify the influences of the pore distribution. Weight increase by CVD was found saturated at the certain level respective to the fiber, reflecting the their surface areas. However, the molecular sieving selectivity between CO_2 and CH_4 was induced only to the fibers of smaller surface area, while the fibers of larger surface areas lost the adsorption activity against both gases. Straight micropores developed from the surface are controlled at their slit size by carbon deposition onto the wall surface while benzene molecule can get into the pore. In contrast, the pore size of micropores developed on the wall of mesopore are difficult to be controlled since the carbon deposit continues until the whole wall of the mesopores is covered by the carbon to plug the micropores
Catalytic denydrochlorination of 1, 2-dichloroethane(1, 2-DEC) into vinyl chloride(VC) was carried out over pitch-based active carbon fiber s(ACF). Surface modification of the ACF by Chemical Vapor Deposition(CVD) of N-containing compounds showed higher catalytic activity and longer life time at very high ralectivity than thin as-received forms. X-ray photoelectron spectroscopy(XPS) suggested that pyridinic nitrogen found on the surface of the modified fibers catalyzes the selective dehydrochlorination reaction through its basicity, radical elimination appearing suppressed to provided longer life
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