| Project/Area Number |
11555266
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 展開研究 |
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| Research Field |
資源開発工学
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| Research Institution | Tohoku University |
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Principal Investigator |
TOHJI Kazuyuki Tohoku University, Graduate school of engineering, Professor, 大学院・工学研究科, 教授 (10175474)
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| Co-Investigator(Kenkyū-buntansha) |
TAKAHASHI Hideyuki Tohoku University, Institute for Materials Research, Research Associate, 金属材料研究所, 助手 (90312652)
SHINODA Kozo Tohoku University, Graduate school of engineering, Research Associate, 大学院・工学研究科, 助手 (10311549)
BALACHANDRAN Jeyadevan Tohoku University, Graduate school of engineering, Associate Professor, 大学院・工学研究科, 助教授 (80261593)
KASUYA Atsuo Tohoku University, Center for Interdisciplinary Research, Professor, 学際科学研究センター, 教授 (10005986)
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| Project Period (FY) |
1999 – 2001
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| Project Status |
Completed (Fiscal Year 2001)
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| Budget Amount *help |
¥13,800,000 (Direct Cost: ¥13,800,000)
Fiscal Year 2001: ¥2,800,000 (Direct Cost: ¥2,800,000)
Fiscal Year 2000: ¥4,300,000 (Direct Cost: ¥4,300,000)
Fiscal Year 1999: ¥6,700,000 (Direct Cost: ¥6,700,000)
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| Keywords | solar energy / photocatalyst / stratified / hydrogen generation reaction / environment conservation / ストラティファイド光触媒 / ZnS光触媒 / CdS光触媒 / 水素発生 / 太陽光 / 光エネルギー / ZnS / 環境 / ZnO / クラスター / エネルギー |
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| Research Abstract |
The purposes of this research project are the synthesis of photocatalyst can convert from the solar-energy to the chemical energy and the environment conservation through the redox reactions of sulfur compounds in aqueous solutions. We had succeeded to synthesize the photocatalysts of metal sulfide semiconductors with high-efficiency of hydrogen generation. The photocatalysts were synthesized from metal oxides or hydroxides as starting material. Our photocatalysts synthesized by a novel wet-reaction process have the "stratified" structure composed by nano-crystals.
In this project, we had researched the relationship between the stratified structure and the photocatalytic activity of the energy conversion. It was found that the stratified-semiconductors formed capsule with a thin layer by ultra fine particles and maintained a potential gradient within this layer, from the results of the morphology observation by transmission electron microscope and the analysis of elemental distribution in the semiconductor particle by energy dispersive x-ray spectroscopy. We can consider that the effective separation of the photoexcited electron and the hole was due to the potential gradient created by the stratified structure. We also researched the studies to establish the reaction system using sea water and sulfur compounds. As a result, we succeeded recovering of various metal ions as sulfides and found the possibilities of removing of harmful heavy metal ions and recovering of useful noble metal ions from sea water.
We applied the synthesis process of stratified material to various compound semiconductor materials considered they can use visible region of sunlight. As the results of experiments, we found the stratified-CdS was obtained. These stratified-CdS particles can generate about 7 litters/hour to 1 m^2 of sunlight irradiation.
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