• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Charge Ordering and Electronic Properties of Molecular Solids and Transition Metal Oxides

Research Project

Project/Area Number 11640338
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 固体物性Ⅱ(磁性・金属・低温)
Research InstitutionThe University of Tokyo

Principal Investigator

FUKUYAMA Hidetshohi  Institute for Solid State Physics, Professor, 物性研究所, 教授 (10004441)

Project Period (FY) 1999 – 2002
Project Status Completed (Fiscal Year 2002)
Budget Amount *help
¥3,600,000 (Direct Cost: ¥3,600,000)
Fiscal Year 2002: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 2001: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 2000: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 1999: ¥800,000 (Direct Cost: ¥800,000)
Keywordsorganic conductors / quarter-filled bands / electronic properties / localized spins / magnetite / metal-insulator transition / Verwey / Verwey転移 / 磁気秩序 / 超交換相互作用 / マグネタイイト / Vervey転移 / 低次元有機導体 / 分子間クーロン相互作用 / ハートリーフォック近似 / モット絶縁体 / 電荷秩序状態 / ハイゼンベルグスピン模型 / スピンギャップ
Research Abstract

Theoretical studies on the charge ordering and associated electronic properties in quarter-filled bands are developed. Especially organic conductors with localized magnetic ions, i.e. π・d systems, and magnetites, the typical magnetic systems, are pursued in details.
The formers are of interest in view of the fact that biological molecules with functionality have often localized spins, while the latter attracts general interest since the understanding is far from complete in spite of the first proposal by Verwey half a century ago.
In the π・d systems, the spatial pattern of the magnetism of localized spins is directly coupled with that of the charge disproportionation of the π electrons leading to a unique feature of metal-insulator transition.
On the other hand, the charge ordering scenario for the metal-insulator transition in magnetites has recently been challenged by the careful NMR measurement. In this research project, a new and completely different mechanism for the metal ・ insulator transition in magnetites has been proposed based on the orbital ordering and accompanying Peierls transition of spinless fermions moving along the one-dimensional direction. This proposal has stimulated renewed efforts in the experimental activities.

Report

(5 results)
  • 2002 Annual Research Report   Final Research Report Summary
  • 2001 Annual Research Report
  • 2000 Annual Research Report
  • 1999 Annual Research Report
  • Research Products

    (31 results)

All Other

All Publications (31 results)

  • [Publications] H.Fukuyama: "Orbital Magnetism in Confirmed Two-Dimensional System"J.Low Temperature Physics. 126・3/4. 1067-1080 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T.Sasaki: "Electrical Conductance under Periodic Magnetic Field"J.Physical Society of Japan. 71・4. 1108-1117 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H.Seo: "Aspects of the Verwey Transition in Magnetite"Physical Review B. 65・8. 085107(1)-085107(7) (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H.Seo: "Orbital Ordering and Bond Dimerization in Magnetite Fe_3O_4"Physica B. 312. 691-693 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] C.Hotta: "Possible Ferromagnetism in Divalent Boride Systems"Physical Review B. 65・18. 184421(1)-184421(5) (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] C.Hotta: "Ferromagnetism in CaB_6"J.of Physics and Chemical Solids. 63・6-8. 1505-1509 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H. Fukuyama, T. Sasaki, K. Yokoyama and Y Ishikawa: "Orbital Magnetism in Confirmed Two-Dimensional System"J. Low Temperature Physics. 126-3/4. 1067-1080 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Sasaki and H Fukuyama: "Electrical Conductance under Periodic Magnetic Field"J. Phys Soc. Jpn.. 71 #4. 1108-1117 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H Seo, M. Ogata and H. Fukuyama: "Aspects of the Verwey Transition in Magnetite,"Phys Rev B. 085107. 1-7 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H. Seo, M. Ogata and H Fukuyam: "Orbital Ordering and Bond Dimerization in Magnetite Fe_3O_4"Physica B. 312. 691-693 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] C. Hotta and H Fukuyama: "Possible Ferromagnetism in Divalent Boride Systems"Phys Rev B. 184421. 1-5 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] C, Hotta and H. Fukuyama: "Ferromagnetism in CaB_6"J.Phys Chem Sol.. 63# 6-8. 1505-1509 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H.Fukuyama: "Orbital Magnetism in Confirmed Two-Dimensional System"J. Low Temperature Physics. 126・3/4. 1067-1080 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Sasaki: "Electrical Conductance under Periodic Magnetic Field"J. Physical Society of Japan. 71・4. 1108-1117 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] H.Seo: "Aspects of the Verwey Transition in Magnetite"Physical Review B. 65・8. 085107(1)-085107(7) (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] C.Hotta: "Possible Ferromagnetism in Divalent Boride Systems"Physical Review B. 65・18. 184421(1)-184421(5) (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] M.Saito: "A Theoretical Study on Orbital Magnetism of Mesoscopic Ring Systems"Physica E (Proc. of LT23). (in press). (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] C.Hotta: "Classification of the Ground States of Two・Dimensional Quarter-Filled Organic Conductors with Strong Dimerization"J. Phys. Soc. Jpn.. 70・2. 321-324 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] T.Matsuo: "Application of Berezinskii's Diagram Method to Bond Disordered System with the Dimerization and the Staggered Field"J. Phys. Soc. Jpn.. 70・9. 2633-2644 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] H.Fukuyama: "Orbital Magnetism in Confined Two-Dimensional Systems"J. Low Temp. Phys. 126・3/4. 1067-1080 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] T.Sasaki: "Electrical Conductance under Periodic Magnetic Field"J. Phys. Soc. Jpn.. 71・4(in press). (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] C.Hotta: "Possibility of Ferromagnetism in Divalent Boride-Systems"Phys. Rev. B. (to be published). (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] H.Seo: "Charge Ordering in Charge Transfer Organic Compounds"Physica B. 284-288. 1539-1540 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] H.Fukuyama: "Interplay between Structure and Electronic Properties in Organic Conductors"Physica B. 280. 462-466 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] C.Hotta: "Effects of Localized Spins in Quasi-Two Dimensional Organic Conductors"J.Phys.Soc.Jpn.. 69・8. 2577-2596 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] H.Fukuyama: "Interplay between Lattice Structure and Electronic Properties in Organic Conductors"J.Phys.Soc.Jpn.Suppl.B. 69. 144-148 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] H.Yamase: "Possible Quasi-One-Dimensional Fermi Surface in LSCO : Phenomenological Study"Physica B. 284-288. 1375-1376 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] H Seo: "Charge Ordering and Spin Gap in NaV_2O_5"J. Phys. Chem. Solids. 60. 1095-1097 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] M. Saito: "A Theoretical Study of Magnetic Excitations in Disordered Spin-Peierls Systems"J. Phys. Chem. Solids. 60. 1113-1115 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] M. Saito: "Effects of Disorder on Magnetic Excitation in Spin-Peierls Systems"Physica B. (in press).

    • Related Report
      1999 Annual Research Report
  • [Publications] H. Fukuyama: "Interplay between Structure and Electronic Properties in Organic Conductor"Physica B. (in press).

    • Related Report
      1999 Annual Research Report

URL: 

Published: 1999-04-01   Modified: 2020-05-15  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi