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INVESTIGATION OF ELECTRONIC PROPERTY NEAR THE METAL TO NONMETAL TRANSITION FOR Pd OXIDES

Research Project

Project/Area Number 11640359
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 固体物性Ⅱ(磁性・金属・低温)
Research InstitutionSCIENCE UNVERSITY OF TOKYO

Principal Investigator

TSUDA Nobuo  SCIENCE UNIVERSITY OF TOKYO, FACULTY OF SCIENCE PROFESSOR, 理学部, 教授 (20155386)

Project Period (FY) 1999 – 2000
Project Status Completed (Fiscal Year 2000)
Budget Amount *help
¥1,900,000 (Direct Cost: ¥1,900,000)
Fiscal Year 2000: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1999: ¥1,400,000 (Direct Cost: ¥1,400,000)
KeywordsPd OXIDE / METAL TOINSULATOR TRANSITION / CONDUCTIVE OXIDE / KONDO EFFECT / MAGNETIC SUSCEPTIBILITY / ELECTRICAL RESISTIVITY / NEARLY ANTIFERROMAGNETIC METAL / 反強磁性的金属 / パラジウム酸化物 / 銅パラジウム酸化物 / 金属・絶縁体転移
Research Abstract

The logarithmic temperature dependence was found for Cu doped Ca_<1-x>Na_xPd_<3-y>Cu_yO_4 which is metallic (x > 0.3). This was analyzed by using the Hamann equation for the Kondo scattering, and TK was found to be about 8 K.
The magnetic susceptibility was measured for Ca_<1-x>Na_xPd_3O_4. The susceptibility slightly increased with decreasing temperature, and it was analyzed by using the Hasegawa-Moriya theory for nearly antiferromagnetic metal. The intraatomic Coulomb repulsion was 4.9 to 3.3 eV depending on the composition.
No superconductivity was found down to 2 K.

Report

(3 results)
  • 2000 Annual Research Report   Final Research Report Summary
  • 1999 Annual Research Report
  • Research Products

    (5 results)

All Other

All Publications (5 results)

  • [Publications] M.KANAZAWA: "Logarithmic Temperature Dependence of Resistivity for Ca_<0.7>Na_<0.3>Pd_3O_4 Dopend with Cu"J.Phys.Soc.Jpn.. 69・12. 4112-4113 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.YANO: "Magnetic Susceptibility of Ca_<1-x>Na_xPd_3O_4(発表予定)"J.Phys.Soc.Jpn.. (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] MASAMI KANAZAWA AND NOBUO TSUDA: "LOGARITHMIC TEMPERATURE DEPENDENCE OF RESISTIVITY FOR Ca_<0.7>Na_<0.3>Pd_3O_4 DOPED WITH Cu"J.Phys.Soc.Jpn.. Vol.69, No.12. 4112-4113 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] YUJI YANO, MASAMI KANAZAWA AND NOBUO TSUDA: "MAGNETIC SUSCEPTIBILITY OF Ca_<1-x>Na_xPd_3O_4"J.Phys.Soc.Jpn.. (TO BE PUBLISHED). (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.KANAZAWA: "Logarithmic Temperature Dependence of Resistivity for Ca_<0.7>Na_<0.3>Pd_3O_4 Doped with Cu"J.Phys.Soc.Jpn.. 69・12. 4112-4113 (2000)

    • Related Report
      2000 Annual Research Report

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Published: 1999-04-01   Modified: 2020-05-15  

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