• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Thermodynamic Investigation of Electron Correlation Effects in Organic Salts

Research Project

Project/Area Number 11640362
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 固体物性Ⅱ(磁性・金属・低温)
Research InstitutionOsaka University (2000-2001)
Okazaki National Research Institutes (1999)

Principal Investigator

NAKAZAWA Yasuhiro  Osaka University, Graduate school of Science, Research Associate, 大学院・理学研究科, 助手 (60222163)

Project Period (FY) 1999 – 2000
Project Status Completed (Fiscal Year 2001)
Budget Amount *help
¥3,100,000 (Direct Cost: ¥3,100,000)
Fiscal Year 2000: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 1999: ¥2,500,000 (Direct Cost: ¥2,500,000)
KeywordsElectron Correlation / Mott Transition / Charge Order / Heat Capacity / 電子相関効果 / 低温電子比熱
Research Abstract

This project is proposed to establish a systematic understanding of the various type of insulation mechanism due to electron correlation effects, which appears in organic 2 : 1salts consisting of BEDT-TTF and DCNQI molecules. Throughout the project, we tried to see the nature of the ground state and low-energy excitations from it by means of the thermodynamic measurements.
In the fiscal year 1999, we focussed on studying the peculiar properties around the Mott boundary in the phase diagram of κ-(BEDT-TTF)_2X system. Using the chemical pressure effect produed by partial deuteration in BEDT-TTF molecules, we have got the information on the variation of γ-term across the Mott boundary for the first time. The γvalue decrease monotonously with approaching the insulating phase and no Brinkmann-Rice type enhancement was observed. The psuedo-gap picture established in high-Tc oxide seems to be favored in this system.
Next year, we have dealt with the non-dimeric quasi-one-dimensional system (DI-DCNQI)_2Ag in terms of charge-ordering due to the long-range Coulomb interaction, V. Although we could not find any thermal anomaly around the charge-order transition, the existence of large one-dimensional spin excitations which is sensitively suppressed by external magnetic fields has been observed. The possibility of field induced spin-gap is suggested in this system.

Report

(3 results)
  • 2001 Final Research Report Summary
  • 2000 Annual Research Report
  • 1999 Annual Research Report
  • Research Products

    (24 results)

All Other

All Publications (24 results)

  • [Publications] Y.Nakazawa: "Thermodynamic Investigation of the Electron is stat of Devterated к-(BEDT-TTF)_2Cu[N(CN)_2]Br"Physical Review B. 60. 4263-4267 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y.Nakazawa: "Thermodynamics of BEDT-TTF based Dimeric Salts,"Synthetic Metals. 103. 1903-1904 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] A.Sato: "Magnetic Properties of λ-BETS_2(Fe_xGa_<1-x>)Cl_4 Exhibiting Superconductor-to-Insulator Transition (BETS=bis(ethylenedithiotetraselenafulvalene : 0.35<x<0.5)"Physical Review B. 61. 111-114 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y.Nakazawa: "Electronic Specific Heat at the Boundary Region of Mott Trunsition in Two-Dimensional Electronic System of к-(BEDT-TTF)_2Cu[N(CN)_2]Br"Physical Review B. 61. R16295-R16298 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y.Nakazawa: "Electronic Specific Heat of BEDT-TTF Based Organic Conductors"Physica B. 281-282. 899-900 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y.Nakazawa: "Thermodynamic Studies of Electron Conrelation Effecte on Organic Salts Based on BEDT-TTF and DCNQI Molecales"J. Phys. Chem. of Solids. 62. 385-388 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Nakazawa et al: "Thermodynamic Investigation of the Electronic States of Deuterated κ(BEDT-TTF)_2Cu[N(CN)_2]Br"Phys. Rev.. B60. 4263-4267 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Nakazawa et al and K. Kanoda: "Thermodynamics of BEDT-TTF based Dimeric Salts"Synthetic Metals Proc. of ICSM Conference'98, Montpellier, France. 103. 1903-1904 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] H.Taniguchi et al: "Metal-Insulator Transition in Partially Deuterated κ-(BEDT-TTF)_2Cu[N(CN)_2]Br"Syathetic Metals. 103. 2250 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] A. Sato et al: "Magnetic Properties of λ-BETS_2(Fe_xGa_(1-x)Cl_4 Exhibiting Superconductor-to-Insulator Transition (BETS=bis(ethlenedithiotetraselenafulvalene ; 0.35<x<0.5)"Phys. Rev.. B61. 111-114 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Nakazawa et al: "Electronic Specific Heat at the Boundary region of Mott Transition in Two-Dimensional Electronic System of κ-(BEDT-TTF)_2Cu[N(CN)_2]Br"Phys. Rev.. B61. R16295-16298 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Nakazawa et al: "Electronic Specific Heat of BEDT-TTF Based Organic Conductors"Physica B. 281&282. 899-900 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] H Fujiwara et al: "A Novel Antiferromagnetic Organic Superconductor, κ-(BETS)_2FeBr_4[ Where BETS=bis(ethylenedithio)tetraselenafulvalene]"J. Am. Chem. Soc.. 123. 306-314 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Nakazawa et al: "Thermodynamic Studies of Electron Correlation Effects on Organic Salts Based on BEDT-TTF and DCNQI Molecules"J. Phys. Chem. of Solids. 62. 385-388 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] H. Kobayashi et al: "Antiferromagnetism and Superconductivity of BETS conductors with Fe^<3+> ions"Synthetic Metals. 120. 663-666 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y.Nakazawa,H.Taniguchi,A.Kawamoto and K.Kanoda: "Electronic Specific Heat of BEDFTTF Based Organic Conducors"Physica B. 281・282. 899-900 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Y.Nakazawa,H.Taniguchi,A.Kawamoto,K.Miyagawa,K.Hiraki,and K Kanoda: "Thermodynamic Studies of Electron Correlation Effects on Organic Salts Based on BEDFTTF and DCNQI Molecules"J.Physics and Chemistry of Solids. 62. 385-388 (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] Y.Nakazawa,H.Taniguchi,A.Kawamoto and K.Kanoda: "Electronic Specific Heat at the Boundary Region of Mott Transition in Two-Dimensional Electronic System of k-(BEDFTTF)_2Cu[N(CN)_2]Br"Physical Review B. 61. R16295-16298 (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] H.Fujiwara,E.Fujiwara,Y.Nakazawa,B.Zh.Narymbetov,K.Kato,H.Kobayashi,A.Kobayashi,M.Tokumoto,P.Cassoux: "A Novel Antiferromagnetic Organic Superconductor, k-BETS_2FeBr_4"J.American Chemical Soolety. 123. 306-314 (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] Y. Nakazawa and K. Kanoda: "Thermodynamic Investigation of the Electronic States of Denterated K-(BEDT-TTF)_2 Cu[N(CN)_2]Br"Physical Review B. 60. 4263-4267 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Y. Hosokoshi, Y. Nakazawa, K. Inoue, K. Takizawa, H, Nakano, M. Takahashi, and T. Goto: "Magnetic Properties of Low-Dimensional Quantum Spin Systems Mode of Stable Organic Biradicals PNNNO, F_2PNNNO and PIMNO"Physical Review B. 60. 12924-12932 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] A. Sato, E. Ojima, H. Akutsu, Y. Nakazawa, H. Kobayashi, H.Tanaka, A. Kobayashi, P. Cassoux: "Magnetic Properties of λ-(BETS)_2(Fe_XGa_<1-X>)Cl_4 Exhibiting Superconductor-to-Insulator Transition"Physical Review B. 61. 111-114 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] I. Shirotani, H. kadoya, C. Sekine, S. Todo, T. Yagi, Y. Nakazawa and K. Kanoda: "Superconductivity of Niobium Phosphorous Sulphide, NbPS, Prepared at High Pressure"J. Physics : Condensed Matter. 11. 6231-6237 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Y. Nakazawa, H. Taniguchi, A. Kawamoto and K. Kanoda: "Electronic Specific Heat of BEDT-TTF Bosed Organic Conductors"Physica B. (in press). (2000)

    • Related Report
      1999 Annual Research Report

URL: 

Published: 1999-04-01   Modified: 2020-05-15  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi