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Cosmochemical Study of Halogens Based on Halogen-derived Noble Gas Isotopes

Research Project

Project/Area Number 11640487
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 地球化学
Research InstitutionThe University of Tokyo

Principal Investigator

NAGAO Keisuke  University of Tokyo, Graduate School of Science, Professor, 大学院・理学系研究科, 教授 (40131619)

Co-Investigator(Kenkyū-buntansha) NAKAMURA Yayoi  University of Tokyo, Earthquake Research Institute, Research Assistant, 地震研究所, 助手 (90282730)
NAKAMURA Tomoki  Kyushu University, Faculty of Science, Associate Professor, 大学院・理学研究院, 助教授 (20260721)
Project Period (FY) 1999 – 2000
Project Status Completed (Fiscal Year 2001)
Budget Amount *help
¥3,500,000 (Direct Cost: ¥3,500,000)
Fiscal Year 2000: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 1999: ¥2,300,000 (Direct Cost: ¥2,300,000)
Keywordsnoble gas isotopes / meteorites / Allende carbonaceous chondrite / secondary neutron / halogen / neutron capture / laser microprobe analysis / CAI / 希ガス / 隕石中のハロゲン元素 / レーザープローブ / コンドルール
Research Abstract

We have observed very high concentrations of Cl, Br and I in Yamato-74191 and in CAIs of Allende(CV3) chondrite. Because halogens are generally thought to have behaved as volatile elements when solid condensates were produced in solar nebula, mechanism to produce the observed high concentrations of halogens in CAIs is difficult to understand. This is due to a lack of knowledge about the cosmochemical behavior of halogens. Laser microprobe noble gas analysis was applied to Allende meteorite traversing the CAI and matrix with a space resolution of about 150μm. The high concentrations of ^<129>Xe show good correlation with the chlorine concentrations determined with EPMA analysis. ^<80>Kr/^<84>Kr and ^<128>Xe/^<132>Xe ratios are also high in the measured portions with high ^<129>Xe/^<132>Xe ratios. The ^<80>Kr and ^<128>Xe can be produced by neutron capture on ^<79>Br and ^<127>I, respectively, in space.
The present results show that halogens have penetrated into the CAIs from outside through the disordered boundary of CAI, when aqueous alteration produced sodalite inside the CAIs. Since we could not find halogen-derived noble gases in surrounding matrix materials, the halogen-rich materials in CAIs must have been produced in the solar nebular, and not in parent body after embedded in matrices. The high concentrations of ^<129>Xe in sodalite-rich materials indicate that the aqueous alteration must occur at the very early stage of solar system when abundant ^<129>I was still alive.

Report

(3 results)
  • 2001 Final Research Report Summary
  • 2000 Annual Research Report
  • 1999 Annual Research Report
  • Research Products

    (10 results)

All Other

All Publications (10 results)

  • [Publications] Okazaki R.: "Cosmic-ray exposure ages of enstatite chondrites"Antarctic Meteorite Research. 13. 153-169 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Osawa T.: "Noble gas measurement in individual mierometeoriles using laser gas-extraction system"Antarctic Meteorite Research. 13. 322-341 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Terada K.: "General characterization of Antarctic micrometeorites collected by the 39th Japanese Antoretic Research Expedition : Consertium studies of JARE AMHs(III)"Antarctic Meteorite Research. 14. 89-107 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Okazaki R.: "Noble-gas-rich chondrites in an enstatite meteorite"Nature. 412. 795-798 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Takaoka N.: "Noble gases in Kobe carbonaceons chandrite"Geochemical Journal. (in press). (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Okazaki, R.: "Cosmic-ray exposure ages of enstatite chondrites."Antarctic Meteorite Res.. 13. 153-169 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Osawa, T.: "Noble gas measurement in individual micrometeorites using laser gas-extraction system"Antarctic Meteorite Res.. 13. 322-341 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Terada, K.: "General characterization of Antarctic micrometeorites collected by the 39th Japanese Antarctic Research Expedition: Consortium studies of JARE AMMs (III)"Antarctic Meteorite Res.. 14. 89-107 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Okazaki, R.: "Noble-gas-rich chondrules in an enstatite meteorite"Nature. 412. 795-798 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Takaoka, N.: "Noble gases in Kobe carbonaceous chondrite"Geochem. J. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary

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Published: 1999-04-01   Modified: 2016-04-21  

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