| Project/Area Number |
11640511
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Physical chemistry
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| Research Institution | KAGOSHIMA UNIVERSITY |
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Principal Investigator |
KURAWAKI Junichi Faculty of Science, KAGOSHIMA UNIVERSITY, Associate Professor, 理学部, 助教授 (10170078)
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| Co-Investigator(Kenkyū-buntansha) |
HIGO Morihide Faculty of Engineering, KAGOSHIMA UNIVERSITY, Associate Professor, 工学部, 助教授 (10128077)
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| Project Period (FY) |
1999 – 2000
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| Project Status |
Completed (Fiscal Year 2000)
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| Budget Amount *help |
¥3,600,000 (Direct Cost: ¥3,600,000)
Fiscal Year 2000: ¥1,400,000 (Direct Cost: ¥1,400,000)
Fiscal Year 1999: ¥2,200,000 (Direct Cost: ¥2,200,000)
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| Keywords | Atomically Smooth / Metal Thin Films / FT-IR Spectra / Photosynthetic Dyes / Adsorbed State / Electron transfer / Fluorescence Study / Aluminum Films / 蛍光分光法 / 赤外反射スペクトル / 角度分布 / 吸着配向 / 光化学反応 |
|---|
| Research Abstract |
An infrared reflection absorption spectroscopy (FT-IRAS) offers a powerful technique for obtaining wide range vibrational spectra of molecules adsorbed on a metal surface. For the purpose of investigating surface geometry and metal surface reactions of the adsorbed molecules on metal films, we prepared atomically smooth aluminum (Al) films and measured IRAS spectra of some aromatic carboxylic acids such as benzoic acid, 1- and 2-naphthoic acids, and 2- and 9- anthracenecarboxylic acids adsorbed on the Al films. The spectral results are discussed in relation to the effect of roughness of the Al film surfaces on the IRAS spectral pattern and its intensity.
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