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Micro gas analytical system by means of radial electrophoresis pump

Research Project

Project/Area Number 11640611
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 分離・精製・検出法
Research InstitutionKumamoto University

Principal Investigator

TODA Kei  Kumamoto University, Faculty of Science, Associate professor, 理学部, 助教授 (90264275)

Project Period (FY) 1999 – 2001
Project Status Completed (Fiscal Year 2001)
Budget Amount *help
¥3,500,000 (Direct Cost: ¥3,500,000)
Fiscal Year 2001: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 2000: ¥1,500,000 (Direct Cost: ¥1,500,000)
Fiscal Year 1999: ¥1,500,000 (Direct Cost: ¥1,500,000)
KeywordsELECTROPHORESIS PUMP / GAS ANALYSIS / DROPLET MICRORING ELECTRODE / HYDROGEN SULFIDE / 二酸化硫黄 / 電気浸透流 / μTAS / 亜硫酸ガス
Research Abstract

In this research, a simple liquid flow method, which could be used in the field, was developed and it was applied to monitoring of atmospheric pollutants. First, a new concept of flowing method "radial electrophoresis pump" was designed and investigated. In this method, gas absorbing solution is flowed electrophoretically with only several volts of voltage. In the beginning of the test it seemed that it worked, but actually the liquid was moved by bubbles generated by the electrodecomposition of water. Then, other methods were tested ; the absorbing solution could be flowed through 10-cm micro channel in a glass chip and same length silicone tubing with several tens of volts. Next, gravity method and compressing method were also tested and they worked well especially compressing with a small compressor and pressure sensor. These flow methods were applied to some kinds of gas analysis. One is a droplet ring electrode fabricated on a chip of micro capillary This device showed very fast response compared to the conventional chronoamperometry The compressing method was applied to a high sensitive H_2S determination system that was composed of tubular gas diffusion scrubber and solid state photo devices. Very low level of H_2S even back ground level could be measured continuously in this method, because stable liquid flow without pulsation was obtained. This system could be operated by battery and could be used for several days in outside field without AC power source. The results obtained with the system showed a good correlation with a conventional tape meter, and further, the time and concentration resolutions were much better in this system.

Report

(4 results)
  • 2001 Annual Research Report   Final Research Report Summary
  • 2000 Annual Research Report
  • 1999 Annual Research Report
  • Research Products

    (15 results)

All Other

All Publications (15 results)

  • [Publications] 戸田 敬: "亜硫酸ガスの高感度マイクロ検出器"硫酸と工業. 52. 1-6 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K.Toda: "A wall-jet ring disk electrode fabricated within a thin-layered micromachined cell"Journal of Electroanalytical Chemistry. 479. 57-63 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 戸田 敬: "液的マイクロリング電極による電気化学的ガス計測方法の検討"分析化学. 49. 989-995 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K.Toda: "Fluorometric field instrument for continuous measurement of atmospheric hydrogen sulfide"Analytical Chemistry. 73. 5716-5724 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K.Toda: "Measurement of atmospheric hydrogen sulfide by continuous flow fluorometry"Analytical Sciences. 18(in press). (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K. Toda, H. Inoue, S. Ohira and I. Sanemasa: "High sensitive micro detector for measurement of sulfur dicxide"Ryusan to Kogyo. 52. 1-6 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K. Toda, S. Oguni, Y. Takamatsu and I. Sanemasa: "A wall-jet ring disk electrode fabricated within a thin-layered micromachined cell"Journal of Electroanalytical Chemistry. 479. 57-63 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K. Toda, M. Kitazaki and I. Sanemasa: "Amperometric gas detection using a micro-ring electrode coupled with a gas-absorbing droplet"Bunseki Kagaku. 49. 989-995 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K. Toda, P.K. Dasgupta, J. Li, G.A. Tarver and G.M. Zarus: "Fluorometric field instrument for continuous measurement of atmospheric hydrogen sulfide"Analytical Chemistry. 73. 5716-5724 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K. Toda, P.K. Dasgupta, J. Li, G.A. Taver, G.M. Zarus, S. Ohira and E.L. Loree: "Measurement of atmospheric hydrogen aulfide hy continuous flow Fluorometry"Analytical Sciences. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K.Toda: "Fluorometric field instrument for continuous measurement of atmospheric hydrogen sulfide"Analytical Chemistry. 73. 5716-5724 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] K.Toda: "Measurement of atmospheric hydrogen sulfide by continuous flow fluorometry"Analytical Sciences. 18(in press). (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] 戸田敬: "液滴マイクロリング電極による電気化学的ガス計測方法の検討"分析化学. 49(12). 989-995 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 戸田敬、井上博史、大平慎一、實政勲: "亜硫酸ガスの高感度マイクロ検出器"硫酸と工業. 52(16). 1-6 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] K.Toda,S.Oguni,Y.Takamatsu,I.Sanemasa: "A wall-jet ring disk electrode fabricated within a thin-layered micromachined cell"J.Electroanal.Chem.. 479(1). 57-63 (1999)

    • Related Report
      1999 Annual Research Report

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Published: 1999-04-01   Modified: 2016-04-21  

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