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A NOVEL COLORING TECHNIQUE WITH NO PIGMENTS - AN APPLICATION TO PHOTOCATALYTIC MATERIALS (TITANIUM DIOXIDE) -

Research Project

Project/Area Number 11650365
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 電子デバイス・機器工学
Research InstitutionKumamoto National College of Technology

Principal Investigator

IWAKI Ryuichi  KUMAMOTO NATIONAL COLLEG OF TECHNOLOGY DEPT. OF ELECTRONICS ENGINEERING PROFESSOR, 電子工学科, 教授 (50044699)

Co-Investigator(Kenkyū-buntansha) IWAKI Ryuichi  KUMAMOTO NATIONAL COLLEG OF TECHNOLOGY , DEPT. OF ELECTRONICS ENGINEERING PROFESSOR, 電子工学科, 教授 (30044720)
ITOH Hideo  NATIONAL INSTITUTE OF AIST. CYBER ASSIST RESEARCH CENTER, READER, サイバーアシスト研究センター, デバイスチームリーダー
MATSUDA Toyonori  KUMAMOTO NATIONAL COLLEG OF TECHNOLOGY , DEPT. OF INFORMATION & COMMUNICATION ENGINEERING, 情報通信工学科, 教授 (00157322)
NISHIYAMA Eiji  KUMAMOTO NATIONAL COLLEG OF TECHNOLOGY DEPT. OF ELECTRONICS ENGINEERING ASSOCIATE PROFESSOR, 電子工学科, 助教授 (00237752)
Project Period (FY) 1999 – 2000
Project Status Completed (Fiscal Year 2001)
Budget Amount *help
¥3,800,000 (Direct Cost: ¥3,800,000)
Fiscal Year 2000: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 1999: ¥2,700,000 (Direct Cost: ¥2,700,000)
Keywordsstructural color / Photo catalytic effect / Multilayer reflector / Periodic structures / Diffraction / Microfabrication / CIE colorimetric system / Morpho butterfly / 光触媒 / ドライエッチング
Research Abstract

We propose a novel technique that colors photo catalytic materials such as titanium dioxide (Ti02). Since the photolytic effect due to photo, catalysis extends not only to contaminants but also to paint itself, the coloring of photo catalysis materials cannot be maintained over the long term. It is therefore necessary to establish techniques for coloring photo catalysis materials with the desired color. The proposed coloring technique is based on the structural color of the wing scales of Morpho butterflies.
The color, which is a brilliant blue color with high gloss, is generated by optical interference in microscopic structures of the wing scales. In the term of project, we have carried on the following studies.
(1) From a computer simulation based on the electromagnetic theory, it is shown that the structural color of the wing scales of Morpho butterflies is associated with multilayer structures (lamella) and periodic structures (ridge) formed in the scales : A series of lamellae is ap … More proximately regarded as a multilayer dielectric reflector that is made up of several layers of material having alternating high and low refractive index ; The periodic structure reduces the bandwidth of the principal peak of the reflectance curve of the multiplayer reflector and decreases the subsidiary oscillations of the curve.
(2) Referring to the generation mechanism of structural color obtained by the computer simulation we have proposed the microscopic structure that colors the photo catalytic materials Ti02 with blue.
The structural-color device having ridges and lamellae is fabricated by the following process : Ti02 / Si02 dielectric multilayer film with Ti film on the top is formed on a substrate by a sputtering or an evaporation technique, ridge pattern is made by electron beam lithography, and the multilayer is etched by SF6> CHF3, and buffered HF.
(3) It is demonstrate from the colorimetry based on the CIE color system that the ridge-lamellar structure generates a brilliant blue color with high gloss as well as the wing scales. Less

Report

(3 results)
  • 2001 Final Research Report Summary
  • 2000 Annual Research Report
  • 1999 Annual Research Report
  • Research Products

    (31 results)

All Other

All Publications (31 results)

  • [Publications] H.Itoh: "Structural-color Configuration using Dielectric Multilayer Film and Dry Etching Technique"Proc. International Topical Workshop on CPT2000 Technical Digest held in Tokyo, Japan. 87-88 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] R.Iwaki: "Electronic Circuit Model of Color Sensitive Retinal Cell Network"IEEE Int. Workshop BMCV 2000, LNCS1811. 482-491 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] E.Nishiyama: "Numerical Analysis of Structural Coloration of Wing-Scales of Morpho butterflies"Proc. First Japanese-Australian Joint Seminar held in Adeloaide, Australia. (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 西山: "構造色の測色について"熊本電波工業高等専門学校研究紀要. 27号. 15-28 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Matsuda: "Numerical Analysis of Structural Coloration of Wing-Scales of Morpho butterflies"JSAEM. 11. 231-238 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 杉谷: "誘電体薄板を積層した微細周期構造の反射スペクトル特性"OPTICS JAPAN '99講演論文集. 339-340 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 伊藤: "構造性発色デバイスのためのTiO2/SiO2多層膜のドライエッチング"OPTICS JAPAN '99講演論文集. 155-156 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 大津: "構造性発色による分光特性"第14回熊本県産学官技術交流化会講演論文集 14521. (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 鈴木: "構造性発色構造を目指してドライエッチングされたTiO2/SiO2多層膜の光学特性"春季第47回応用物理学会全国大会. (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 松田: "構造性発色とその工学的応用"第120回熊本県知能システム技術研究会(RIST)フォーラム. (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 松田: "蝶燐粉の構造と光学特性"日本光学会第27回冬季講習会「フォトニック結晶と極微周期の光学」テキスト. 113-122 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] H. Itoh, T. Matsuda: "Photocatalytic Colored Member and Method of Manufacturing the Same"Application to the US Patent Office for a patent, Filing No. 09/749, 876, Filing date 29/12/2000.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] H. Itoh, T. Matsuda: "Photocatalytic Colored Member and Method of Manufacturing the Same"Application to Japan Patent Office for a patent, Filing No. 2000-135405, Filing date 9/5/2000 (in Japanese)..

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] H. Itoh, Suzuki, E. Nishiyama, T. Matsuda, and Nemoto: "Structural-color Configuration using Dielectric Multilayer Film and Dry Etching technique"Proc. International Topical Workshop on CPT 2000 Technical Digest held in Tokyo, Japan. 87-88 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] R. Iwaki and M. Shimoda: "Electronic. Circuit Model of Color Sensitive Retinal Cell Network"IEEE Int. Workshop BMCV 2000, LNCS, 1811. 482-491 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] E. Nishiyama, T. Matsuda, H. Itoh, and M. Shimoda: "Numerical Analysis of Structural Coloration of Wing-Scales of Morpho butterflies"Proc. First Japanese-Australian Joint Seminar held in Adelaide, Australia. 6-2 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] E. Nishiyama, T. Matsuda, M. Shimoda, R. Iwaki, and H. Itoh: "On a colorimetry of structural coloration (in Japanese)"Research Reports of Kumamoto National College of Technology. Vol.27. 15-28 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Matsuda, H. Itoh, E. Nishiyama, and M. Shimoda: "Numerical Analysis of Structural Coloration of Wing-Scales of Morpho butterflies"JSAEM in Applied Electromagnetics and Mechnics. Vol.11. 231-238 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K. Sugitani, T. Matsuda, H. Itoh, E. Nishiyama and M. Shimoda: "Repection spectrum characteristics of periodic structures stacked dielectric-plates (in Japanese)"Extended abstracts of OPTICS JAPAN '99. 339-340 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] H. Itoh, A. Suzuki, E. Nishiyama, T. Matsuda, and T. Nemoto: "Dry etching process of dielectric thin films for structural-color devies (in Japanese)"Extended abstracts of OPTICS JAPAN '99. 155-156 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 松田: "蝶厘燐粉の光学特性とその構造,"光学会第27回冬季講習会予稿集. 122-133

    • Related Report
      2000 Annual Research Report
  • [Publications] R.Iwaki and M.Shimoda: "Electronic Circuit Model of Color Sensitive Retinal Cell Network"Proc.BMCV 2000, LNCS 1811. 482-491

    • Related Report
      2000 Annual Research Report
  • [Publications] 西山,松田,下田,岩木,伊藤: "構造色の測色について"熊本電波高専紀要. 27号. 15-28

    • Related Report
      2000 Annual Research Report
  • [Publications] H.Ito and T.Matsuda: "Photocatalytic Colored Member and Method of Manufacturing the Same"米国特許出願OSMM&N DOCKET 201419US0X.

    • Related Report
      2000 Annual Research Report
  • [Publications] 伊藤,松田: "光触媒発色材料とその製造方法"特許出願 特許出願番号 特願2000-135405.

    • Related Report
      2000 Annual Research Report
  • [Publications] 杉谷,松田,伊藤,西山,下田: "誘電体薄板を積層した微細周期構造の反射スペクトル特性"OPTICS JAPAN '99 講演会論文集. 339-340 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 伊藤,鈴木,西山,松田,根本: "構造性発色デバイスのためのTiO2/SiO2の多層膜ドライエッチング"OPTICS JAPAN '99 講演会論文集. 155-156 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 伊藤,鈴木,西山,松田,根本: 87-88 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] 西山,松田,伊藤,下田: 6-2 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] 大津,松田,西山,伊藤: "構造性発色による分光特性"第14回熊本県産学官技術交流会講演論文集. 14521 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] 鈴木,伊藤,西山,松田,根本: "構造性発色構造を目指してドライエッチングされたTiO2/SiO2多層膜の光学特性"第47回応用物理学関係連合講演会. (発表予定). (2000)

    • Related Report
      1999 Annual Research Report

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Published: 1999-04-01   Modified: 2016-04-21  

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