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HELICAL CONJUGATED POLYMER SYNTHESIZED WITH A CHIRAL NEMATIC REACTION FIELD AND ITS PROPERTIES

Research Project

Project/Area Number 11650919
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 高分子構造・物性(含繊維)
Research InstitutionUNIVERSITY OF TSUKUBA

Principal Investigator

PIAO Guangzhe  University of Tsukuba, Institute of Materials Science, Research Associate, 物質工学系, 助手 (20302391)

Co-Investigator(Kenkyū-buntansha) AKAGI Kazuo  University of Tsukuba, Institute of Materials Science, Professoru, 物質工学系, 教授 (20150964)
後藤 博正  筑波大学, 物質工学系, 助手 (40292528)
Project Period (FY) 1999 – 2000
Project Status Completed (Fiscal Year 2000)
Budget Amount *help
¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 2000: ¥1,200,000 (Direct Cost: ¥1,200,000)
KeywordsPolyacetylene / Helical structure / Chiral nematic liquid crystal / Molecular solenoid / Conjugated polymer / Conducting polymer / Chiral dopant / Asymmetric and anisotropic reaction field / ヘリカルポリアセチレン / 不斉異方性反応場
Research Abstract

We have synthesized for the first time helical polyacetylene with left-and right-handed screw structures under chiral nematic reaction field. The screw direction of the (R)-and (S)-chiral nematic LCs is identified by miscibility test with a well-known right-handed chiral nematic LC, 3-chlorocholest-5-ene. The results demonstrate that they possessed left-handed and right-handed helical structures, respectively. By virtue of its helical structure, the chiral nematic LC is expected to serve as a medium which provides a asymmetric and anisotropic reaction filed for acetylene polymerization and the polyacetylene synthesized under (R)-or (S)-chiral nematic LCs to be chiral, based on a predominant left-handed or right-handed helical sense. It shows that the polyacetylene films synthesized under (R)-or (S)-chiral nematic LCs form helical fibrillar morphologies with left-handed and right-handed directions. respectively. The screw directions of the fibrils coincide with those of the chiral nematic LCs used as solvent. Namely, the twisted directions of the polyacetylene fibril are identical with the corresponding those of the chiral nematic LCs. In circular dichroism (CD) spectra, positive or negative Cotton effect is observed in the region of π→π^* transition of polyacetylene chain, in spite of no existence of chiroptical substituent in side chains. It is evident that the main chain itself is also helically screwed, too. The results mean that these helical chains are bundled through van der Waals interaction to form helical fibrils. It is worthy of remark that the present polyacetylene films showed high electrical conductivities of 1.5×10^3 S/cm after an iodine doping as well as high trans content of 80-90%. Such a helical polyacetylene with high electrical conductivity could serve as a "molecular solenoid" composed of electrically conducting molecular wire.

Report

(3 results)
  • 2000 Annual Research Report   Final Research Report Summary
  • 1999 Annual Research Report
  • Research Products

    (24 results)

All Other

All Publications (24 results)

  • [Publications] K.Akagi,G.Piao,S.Kaneko,K.Sakamaki,H.Shirakawa and R.Kyotani: "Helical polyacetylene synthesized with a chiral nematic reaction field"Science. 282・5394. 1683-1686 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Akagi,G.Piao,S.Kaneko,I.Higuchi,H.Shirakawa and R.Kyotani: "Helical polyacetylene synthesized under chiral nematic liquid crystals"Synthetic Metals. 102・(1-3). 1406-1409 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] G.Piao,S.Kaneko,I.Higuchi,K.Akagi,H.Shirakawa,M.Kyotani: "Synthesis and properties of helical polyacetylene"Synthetic Metals. 101・(1-3). 94-94 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] G.Piao,K.Akagi,H.Shirakawa: "Chiroptical titanium complexes as catalytically active chiral dopants available for asymmetric acetylene polymerization"Synthetic Metals. 101・(1-3). 92-93 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Akagi,I.Higuchi,G.Piao,H.Shirakawa,M.Kyotani: "Helical polyacetylene synthesized under asymmetric reaction field constructed with chiral nematic liquid crystals"Mol.Cryst.Liq.Crys.. 332. 463-470 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] G.Piao,N.Kawamura,K.Akagi,H.Shirakawa,M.Kyotani: "Advanced conjugated polymer-Helical polyacetylene"Polym.Adv.Technol.. 11・(8-12). 826-829 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Akagi, G.Piao, S.Kaneko, K.Sakamaki, H.Shirakawa and R.Kyotani: "Helical polyacetylene synthesized with a chiral nematic reaction field"Science. 282-5394. 1683-1686 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Akagi, G.Piao, S.Kaneko, I.Higuchi, H.Shirakawa and R.Kyotani: "Helical polyacetylene synthesized under chiral nematic liquid crystals"Synthetic Metals. 102-(1-3). 1406-1409 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] G.Piao, S.Kaneko, I.Higuchi, K.Akagi, H.Shirakawa, M.Kyotani: "Synthesis and properties of helical polyacetylene"Synthetic Metals. 101-(1-3). 94-94 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] G.Piao, K.Akagi, H.Shirakawa: "Chiroptical titanium complexes as catalytically active chiral dopants available for asymmetric acetylene polymerization"Synthetic Metals. 101-(1-3). 92-93 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Akagi, I.Higuchi, G.Piao, H.Shirakawa, M.Kyotani: "Helical polyacetylene synthesized under asymmetric reaction field constructed with chiral nematic liquid crystals"Mol.Cryst.Liq.Crys.. 332. 463-470 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] G.Piao, N.Kawamura, K.Akagi, H.Shirakawa, M.Kyotani: "Advanced conjugated polymer-Helical polyacetylene"Polym.Adv.Technol.. 11-(8-12). 826-829 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Akagi,G.Piao,S.Kaneko,K.Sakamaki,H.Shirakawa and R.Kyotani: "Helical polyacetylene synthesized with a chiral nematic reaction field"Science. 282・5394. 1683-1686 (1998)

    • Related Report
      2000 Annual Research Report
  • [Publications] K.Akagi,G.Piao,S.Kaneko,I.Higuchi,H.Shirakawa and R.Kyotani: "Helical polyacetylene synthesized under chiral nematic liquid crystals"Synthetic Metals. 102・(1-3). 1406-1409 (1999)

    • Related Report
      2000 Annual Research Report
  • [Publications] G.Piao,S.Kaneko,I.Higuchi,K.Akagi,H.Shirakawa,M.Kyotani: "Synthesis and properties of helical polyacetylene"Synthetic Metals. 101・(1-3). 94-94 (1999)

    • Related Report
      2000 Annual Research Report
  • [Publications] G.Piao,K.Akagi,H.Shirakawa: "Chiroptical titanium complexes as catalytically active chiral dopants available for asymmetric acetylene polymerization"Synthetic Metals. 101・(1-3). 92-93 (1999)

    • Related Report
      2000 Annual Research Report
  • [Publications] K.Akagi,I.Higuchi,G.Piao,H.Shirakawa,M.Kyotani: "Helical polyacetylene synthesized under asymmetric reaction field constructed with chiral nematic liquid crystals"Mol.Cryst.Liq.Crys.. 332. 463-470 (1999)

    • Related Report
      2000 Annual Research Report
  • [Publications] G.Piao,N.Kawamura,K.Akagi,H.Shirakawa,M.Kyotani: "Advanced conjugated polymer-Helical polyacetylene"Polym.Adv.Technol.. 11・(8-12). 826-829 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] G.Piao (朴光哲): "Synthesis and properties of helical polyacetylene"Synthetic Metals. 101・(1-3). 94-94 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] G.Piao (朴光哲): "Chiroptical titanium complexes as catalytically active chiral dopants available for asymmetric acetylene polymerization"Synthetic Metals. 101・(1-3). 92-93 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] K.Akagi (赤木和夫): "Helical polyacetylene synthesized undeer chiral nematic liquid crystals"Synthetic Metals. 102・(1-3). 1406-1409 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] K.Akagi (赤木和夫): "Helical polyacetylene synthesized under asymmetric reaction field constructed with chiral nematic liquid crystals"Molecular Crystals and Liquid Crystals. 332. 463-470 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] G.Piao (朴光哲): "Advanced conjugated polymer-Helical polyacetylene"Polymers for Advanced Technologies,to be accepted..

    • Related Report
      1999 Annual Research Report
  • [Publications] H.Shirakawa (白川英樹): "Synthesis of vertically aligned polyacetylene thin films in homeotropic liquid crystalline solvents"Synthetic Metals,to be accepted..

    • Related Report
      1999 Annual Research Report

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Published: 2000-04-01   Modified: 2016-04-21  

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