Preparation and Carbonization of Ultra-Oriented Poly(acrylonitrile) Fibers: Effect of Stereoregularity
| Project/Area Number |
11650934
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
高分子構造・物性(含繊維)
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| Research Institution | Tokyo University of Science |
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Principal Investigator |
TETSUO Kanamoto Science University of Tokyo, Dept. of Appl. Chem.Professor, 理学部, 教授 (30084320)
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| Project Period (FY) |
1999 – 2000
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| Project Status |
Completed (Fiscal Year 2001)
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| Budget Amount *help |
¥3,800,000 (Direct Cost: ¥3,800,000)
Fiscal Year 2000: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 1999: ¥3,000,000 (Direct Cost: ¥3,000,000)
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| Keywords | poly(acrylonitrile) / sterepregularity / superdrawn fibers / Phase structure / conformation / stress / strain curves / tensile properties / 延伸繊維 / アタクティク / イソタクティック / 超延伸 / 繊維構造 / 引張特性 / コンフォーメーション変化 |
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| Research Abstract |
Uniaxial drawing of isotaotic and atactivc poly(acrylonitrile)(iso-PAN and at-PAN) were studied. Dried gel films were initially drawn by solid-state coextrusion (first-stage draw) to an extrusion draw ratio of 16, followed by a further tensile draw at 100-200℃(second-stage draw). The temperature for optimum second-stage draw of iso-PAN, 130-140℃, was significantly lower than that (160-180℃) of at-PAN, reflecting their crystal softening temperatures 〓00vs. 150℃). The maximum achieved total draw ratios were comparable for these PANs. Although, the maximum tensile modulus, as well as modulus at a given DR, was slightly higher for iso-PAN than for at-PAN (28.5 vs. 23.0 GPa), the maximum tensile strength was comparable for each PAN, at 0.90 GPa. The shapes of stress/strain curves for fibers were significantly different between iso- and at-PAN reflecting their different chain conformations: a predominantly 3/1 helical con formation for iso-PAN and planar zigzag and helical sequences for at-PAN.
SAXS of at-PAN fibers prepared by solid-state coextrusion of a nascent PAN formed under controlled conditions has been examined. Although solution-spun PAN fibers and their drawn products generally show no X-ray long-period scattering, the nascent PAN and the fibers prepared from it exhibited a clear SAXS maximum, depending on the extrusion temperature(T_<ext>) and draw ratio (EDR). These observations reveal that the absence or presence of an X-ray long-period scattering for PAN fibers depends on the initial morphology and the drawing variables.
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Report
(3 results)
Research Products
(20 results)
