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Synthetic Studies on Semiochemicals Related to the Pest Control

Research Project

Project/Area Number 11660101
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Bioproduction chemistry/Bioorganic chemistry
Research InstitutionTohoku University (2000)
Ibaraki University (1999)

Principal Investigator

KUWAHARA Shigefumi  Division of Life Science, Graduate School of Agricultural Science, Tohoku University, Associate Professor, 大学院・農学研究科, 助教授 (30170145)

Project Period (FY) 1999 – 2000
Project Status Completed (Fiscal Year 2000)
Budget Amount *help
¥2,900,000 (Direct Cost: ¥2,900,000)
Fiscal Year 2000: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 1999: ¥1,800,000 (Direct Cost: ¥1,800,000)
Keywordsstink bug / sesquiterpene / pheromone / cockroach / periplanone / spodoptera exigua / volicitin / leaf miner moth / Tynacantha marginata / sesquiterpene / Diels-Alder reaction / periplanone-D / periplanone-C / volicitin / 5,9-dimethylpentadecane / Perileucoptera coffeella / Spodoptera exigua / Periplaneta fuliginosa / Pheromone / Elicitor
Research Abstract

Synthesis of both the racemate and optically active forms of a novel sesquiterpene (9-isopropyl-4, 6-dimethyltricyclo [4.4.0.0^<5, 9>] dec-3-en-2-one) isolated from the pheromone gland of a Brazilian predatory stink bug, Tynacantha marginata Dallas, was achieved via a intramolecular double Michael cycloaddition and intramolecular Diels-Alder reaction, respectively. This synthetic work enabled us to determine the absolute configuration of the putative pheromone in addition to the confirmation of the proposed structure. Other semiochemicals such as the sex pheromones of Periplaneta fuliginosa and Perileucoptera coffeella, and an elicitor (named volicitin) contained in the regurgitant of Spodoptera exigua were also synthesized in optically active forms. The synthesis of the sex pheromone of Periplaneta fuliginosa led to the correction of prviously reported physical and spectroscopic data of this pheromone called periplanone-D.

Report

(3 results)
  • 2000 Annual Research Report   Final Research Report Summary
  • 1999 Annual Research Report
  • Research Products

    (19 results)

All Other

All Publications (19 results)

  • [Publications] Shigefumi Kuwahara: "Preparation of (-)-periplanone D and its physical and spectroscopic properties"Bioscience, Biotechnology, and Biochemistry. 64. 600-602 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Ting Liang: "Simple Synthesis of 5,9-dimethylated long-chain alkanes, the sex pheromones of leaf miner moths"Bioscience, Biotechnology, and Biochemistry. 64. 2474-2477 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Shigefumi Kuwahara: "Synthesis of all four possible stereoisomers of 5,9-dimethylpentadecane, the major sex pheromone component of the coffee leafminer moth"Bioscience, Biotechnology, and Biochemistry. 64. 2723-2726 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Shigefumi Kuwahara: "Synthesis of a novel sesquiterpene isolated from the pheromone gland of a stink bug, Tynacantha marginata Dallas"Tetrahedron. 56. 8111-8117 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Shigefumi Kuwahara: "Synthesis of both enantiomers of a novel sesquiterpene isolated from the pheromone gland of a stink bug, Tynacantha marginata"Synthesis. 1930-1935 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 桑原重文: "昆虫の生産する生態相関物質の合成研究"日本農薬学会誌. 25. 451-455 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Kuwahara, I.Nagashima, W.S.Leal, J.Ishikawa, and O.Kodama: "Preparation of (-)-periplanone D and its physical and spectroscopic properties."Bioscience, Biotechnology, and Biochemistry. 64. 600-602 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Liang, S.Kuwahara, M.Hasegawa, and O.Kodama: "Facile synthesis of 5, 9-dimethylated long-chain alkanes, the sex pheromone of leaf miner moths"Bioscience, Biotechnology, and Biochemistry. 64. 2474-2477 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Kuwahara, T.Liang, W.S.Leal, J.Ishikawa, and O.Kodama: "Synthesis of all four possible stereoisomers of 5, 9-dimethylpentadecane, the major sex pheromone component of the coffee leaf miner moth, Perileucoptera coffeella"Bioscience, Biotechnology, and Biochemistry. 64. 2723-2726 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Kuwahara, S.Hamade, W.S.Leal, J.Ishikawa, and O.Kodama: "Synthesis of a novel sesquiterpene isolated from the pheromone gland of a stink bug, Tynacantha marginata"Tetrahedron. 56. 8111-8117 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Kuwahara, J.Ishikawa, W.S.Leal, S.Hamade, and O.Kodama: "Synthesis of Both Enantiomers of a Novel Sesquiterpene Isolated from the Pheromone Gland of a Stink Bug, Tynacantha marginata Dallas."Synthesis. 1930-1935 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Kuwahara: "Synthesis of some insect semiochemicals."Journal of Pesticide Science. 25. 451-455 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Kuwahara,I.Nagashima,W.S.Leal,J.Ishikawa,O.Kodama: "Preparation of (-)-periplanone D and its physical and spectroscopic properties"Bioscience,Biotechnology,and Biochemistry. 64・3. 600-602 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Liang,S.Kuwahara,M.Hasegawa,O.Kodama: "Facile Synthesis of 5,9-dimethylated long-chain alkanes, the sex pheromones of leaf minor moths"Bioscience,Biotechnology,and Biochemistry. 64・11. 2474-2477 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] S.Kuwahara,T.Liang,W.S.Leal,J.Ishikawa,O.Kodama: "Synthesis of all four possible stereoisomers of 5,9-dimethyl-pentadecane, the sex pheromone component of the coffee leaf miner moth"Bioscience,Biotechnology,and Biochemistry. 64・12. 2723-2726 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] S.Kuwahara,S.Hamade,W.S.Leal,J.Ishikawa,O.Kodama: "Synthesis of a novel sesquiterpene isolated from the pheromone gland of a stink bug, Tynacantha marginata"Tetrahedron. 56・41. 8111-8117 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] S.Kuwahara,J.Ishikawa,W.S.Leal,S.Hamade,O.Kodama: "Synthesis of both enantiomers of a novel sesquiterpene Isolated from the pheromone gland of a stink bug, Tynacantha marginata Dallas"Synthesis. 13. 1930-1935 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 桑原重文: "昆虫の生産する生態相関物質の合成研究"日本農薬学会誌. 25・4. 451-455 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shigefumi Kuwahara et.al.: "Preparation of (-)-periplanone D and its physical and spectroscopic properties"Bioscience,Biotechnology,and Biochemistry. 64(3). 600-602 (2000)

    • Related Report
      1999 Annual Research Report

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Published: 1999-04-01   Modified: 2016-04-21  

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