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Studies on Reactive Sputtering Processes of Oxide Thin Films

Research Project

Project/Area Number 11680488
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field プラズマ理工学
Research InstitutionNagasaki University

Principal Investigator

MATSUDA Yoshinobu  Nagasaki Univ. Dept. Electrical and Electronic Engineering, Assoc. Prof., 工学部, 助教授 (60199817)

Project Period (FY) 1999 – 2001
Project Status Completed (Fiscal Year 2001)
Budget Amount *help
¥1,600,000 (Direct Cost: ¥1,600,000)
Fiscal Year 2001: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 2000: ¥800,000 (Direct Cost: ¥800,000)
KeywordsReactive Sputtering / Oxide Thin Films / Magnesium Oxide / Inductively Coupled Plasma / Hysteresis / Mode Transition / Magnetron / Secondary Electron Emission Coefficient / 金属モード / 酸化物モード / 透明導電膜 / ITO
Research Abstract

In the fiscal year 2001, we have succeeded in producing the high density ICP, and investigated the fundamental discharge properties under several operation conditions such as the sole PM operation, the sole ICP operation, and the simultaneous operation of PM and ICP.
The use of functional oxide thin films such as MgO, TiO_2, ZnO, and A1_2O_3 has been rapidly increasing in industry because of superior electrical, optical, mechanical, and biological nature of these materials. Thus, the high-rate deposition of high-quality oxide thin films has been more demanded than ever. In the past, various techniques such as sputtering, electron-beam evaporation, ion plating, and sol-gel methods, have been used for the fabrication of oxide thin films. In general, the sputtering method has the distinct advantages of low temperature processing for polycrystalline materials, film uniformity over large areas, and scalabiliry; however, its industrial application has been limited due to its low deposition ra … More te. For example, the deposition rate for MgO in the sputter based method is at the most 0.5 nm/s. For the purpose of high-rate deposition of high-quality magnesium oxide thin films that have been used as the protection-layers of discharge electrodes in plasma display panels, we have proposed a new reactive sputtering process in which conventional planar magnetron (PM) is assisted -by the inductively coupled plasma (ICP).
Obtained results in the fiscal year 2001 are summarized as follows :
1) By-using an internal single-turn coil antenna, we have succeeded in producing high-density ICP.
2) Application of 13.56MHz RF power of several hundreds ofW generated an ideal ICP with a density of more than 10^<17>m^<-3>.
3) As a result of the optical emission measurements of the axial and radial spatial profiles with an image-intensified CCD camera and spectrometers, we have confirmed that an ideal ICP was produced between the target and substrate electrodes.
4) As a result of the comparison between the above-mentioned operation conditions, we have confirmed that the simultaneous operation of ICP and PM is effective for reionizing the sputtered metallic atoms. Less

Report

(4 results)
  • 2001 Annual Research Report   Final Research Report Summary
  • 2000 Annual Research Report
  • 1999 Annual Research Report
  • Research Products

    (41 results)

All Other

All Publications (41 results)

  • [Publications] Madoka Muta: "Two-Dimentional Spatial Profiles of Plasma Parameters in DC Reactive Magnetron Sputtering of ITO"Thin Solid Films. Vol.341 No.1-2. 221-224 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Yoshinobu Matsuda: "Two-Dimensional Spatial Distributions of Sputtered Particles Produced in a Planar Magnetron Discharge of Indium-Thin-Oxide Target"Thin Solid Films. Vol.345 No.1. 167-171 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Koji Otomo: "Quantitative Analysis of Hysteresis Characteristics in Reactive Sputtering"Proceedings of the 17^<th> Symposium on Plasma Processing, January 26-28 2000, Nagasaki. 177-180 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 松田良信: "反応性スパッタリングによるMgO薄膜作成プロセスの実験的・理論的検討"電子情報通信学会技術研究報告. Vol.100 No.132. 33-38 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Yoshinobu Matsuda: "Quantitative Analysis of Reactive Sputtering Process for MgO Deposition"Proc.Of the Seventh International Display Workshops (IDW2000), Kobe, PDP4-1. 667-670 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Kei Tashiro: "Dynamic Change in Residual Oxygen Pressure during Reactive Sputtering Process of MgO"Proceedings of Plasma Science Symposium 2001/the 18^<th> Symposium on Plasma Processing, January 24-26 2001, Kyoto. 603-604 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Yoshinobu Matsuda: "Relation between Residual Oxygen Pressure and Film Crystallization in Reactive Sputtering of Mg Target"Proc.of the 25th Int.Conf.on Phenomena in Ionized Gases, July 17-22 2001, Nagoya. Vol.2. 127-128 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Yoshinobu Matsuda: "Quantitative Modeling of Reactive Sputtering Process for MgO Thin Film Deposition"Thin Solid Films. Vol.390. 59-63 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Yoshinobu Matsuda: "Application of Laser and Optical Diagnostics to The Study of Reactive Sputtering Process"Proc.of the 10th Symposium on Laser-Aided Plasma Diagnostics, September 24-28 2001, Fukuoka. 237-241 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Yoshinobu Matsuda: "New Reactive Sputtering Model Considering the Effect of the Electron Emission Coefficiency for MgO Deposition"IEICE Trans.Electron.. Vol.E84-C No.11. 1667-1672 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 松田良信: "MgO高速成膜用誘導放電支援反応性スパッタリング法の開発"電子情報通信学会技術報告. Vol.101 No.600. 127-132 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M. Muta, S. Ohgushi, Y. Matsuda, and H. Fujiyama: "Two-Dimentinal Spatial Profiles of Plasma Parameters in DC Reactive Magnetron Sputtering of ITO"Thin Solid Films. Vol.341,No.1-2. 221-224 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Matsuda, M. Muta and H. Fujiyama: "Two-dimensional spatial distributions of sputtered particles produced in a planar magnetron discharge of indium-tin-oxide target"Thin Solid Films. Vol.345,No.1. 167-171 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K. Otomo, Y. Matsuda, and H. Fujiyama: "Quantitative Analysis of Hysteresis Characteristics in Reactive Sputtering"Proceedings of the 17^<th> Symposium on Plasma Processing, January 26-28 2000, Nagasaki. 177-180 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Matsuda, K. Otomo, and H. Fujiyama: "Experimental and Theoretical Studies of Reactive Sputtering Process for MgO Film Deposition"IEICE Technical Report. Vol.100,No.132. 33, EID2000-38, 7 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Matsuda, K. Tashiro, K. Otomo and H. Fujiyama: "Global Quantitative Analysis of Reactive Sputtering Process for MgO Deposition"Proceedings of the 7th International Display Workshops (IDW2000), Nov.29-Dec.1, 2000, Kobe. (invited). 667-670 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K. Yashiro, Y. Matsuda, and H. Fujiyama: "Dynamic Change in Residual Oxygen Pressure during Reactive Sputtering Process of MgO"Proc. of Plasma Science Symposium 2001/the 18^<th> Symposium on Plasma Processing, January 24-26 2001, Kyoto. 603-604 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y> Matsuda, K. Tashiro, Y. Koyama and H. Fujiyama: "Relation between Residual Oxygen Pressure and Film Crystallization in Reactive Sputtering of Mg Traget"Proc. of teh 25th Int. Conf. on Phenomena in ionized Gases, July 17-22 Nagoya. Vol.2, 18a54. 127-128 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Matsuda, K. Otomo and H. Fujiyama: "Quantitative modeling of reactive sputtering process for MgO thin film deposition"Thin Solid Films. Vol.390. 59-63 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Matsuda and H. Fujiyama: "Application of Laser and Optical Diagnostics to The Study of Reactive Sputtering Process"Proc. of the 10th Symposium on Laser-Aided Plasma Diagnostics, September 24-28 Fukuoka. 237-241 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Matsuda, K. Tashiro, K. Otomo, and H. Fujiyama: "New Reactive Sputtering Model Considering the Effect of the Electron Emission Coefficiency for MgO Deposition"IEICE Trans. Electron.. Vol.E84-C,No.11. 1667-16t72 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Matsuda, K. Tasjhiro, and H. Fujiyama: "Development of Reactive Sputtering Method Assisted by Inductively Coupled Discharege for High-Rate Deposition of Magnesium Oxide"IEICE Technical Report. Vol.101,No.600. 127,EID2001-132,EID2001 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Madoka Muta: "Two-Dimentional Spatial Profiles of Plasma Parameters in DC Reactive Magnetron Sputtering of ITO"Thin Solid Films. Vol.341 No.1-2. 221-224 (1999)

    • Related Report
      2001 Annual Research Report
  • [Publications] Yoshinobu Matsuda: "Two-Dimensional Spatial Distributions of Sputtered Particles Produced in a Planar Magnetron Discharge of Indium-Thin-Oxide Target"Thin Solid Films. Vol.345 No.1. 167-171 (1999)

    • Related Report
      2001 Annual Research Report
  • [Publications] Koji Otomo: "Quantitative Analysis of Hysteresis Characteristics in Reactive Sputtering"Proceedings of the 17^<th> Symposium on Plasma Processing, January 26-28 2000, Nagasaki. 177-180 (2000)

    • Related Report
      2001 Annual Research Report
  • [Publications] 松田良信: "反応性スパッタリングによるMgO薄膜作成プロセスの実験的・理論的検討"電子情報通信学会技術研究報告. Vol.100 No.132. 33-38 (2000)

    • Related Report
      2001 Annual Research Report
  • [Publications] Yoshinobu Matsuda: "Quantitative Analysis of Reactive Sputtering Process for MgO Deposition"proc.Of the Seventh International Display Workshops (IDW2000), Kobe, PDP4-1. 667-670 (2000)

    • Related Report
      2001 Annual Research Report
  • [Publications] Kei Tashiro: "Dynamic Change in Residual Oxygen Pressure during Reactive Sputtering Process of MgO"Proceedings of Plasma Science Symposium 2001/the 18^<th> Symposium on Plasma Processing, January 24-26 2001, Kyoto. 603-604 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Yoshinobu Matsuda: "Relation between Residual Oxygen Pressure and Film Crystallization in Reactive Sputtering of Mg Target"Proc.of the 25th Int.Conf.on Phenomena in Ionized Gases, July 17-22 2001, Nagoya. Vol.2. 127-128 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Yoshinobu Matsuda: "Quantitative Modeling of Reactive Sputtering Process for MgO Thin Film Deposition"Thin Solid Films. Vol.390. 59-63 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Yoshinobu Matsuda: "Application of Laser and Optical Diagnostics to The Study of Reactive Sputtering Process"Proc.of the 10th Symposium on Laser-Aided Plasma Diagnostics, September 24-28 2001, Fukuoka. 237-241 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Yoshinobu Matsuda: "New Reactive Sputtering Model Considering the Effect of the Electron Emission Coefficiency for MgO Deposition"IEICE Trans.Electron.. Vol.E84-C No.11. 1667-1672 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 松田良信: "MgO高速成膜用誘導放電支援反応性スパッタリング法の開発"電子情報通信学会技術報告. Vol.101 No.600. 127-132 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] Madoka Muta: "Two-Dimentional Spatial Profiles of Plasma Parameters in DC Reactive Magnetron Sputtering of ITO"Thin Solid Films. Vol.341 No.1-2. 221-224 (1999)

    • Related Report
      2000 Annual Research Report
  • [Publications] Yoshinobu Matsuda: "Two-Dimensional Spatial Distributions of Sputtered Particles Produced in a Planar Magnetron Discharge of Indium-Thin-Oxide Target"Thin Solid Films. Vol.345 No.1. 167-171 (1999)

    • Related Report
      2000 Annual Research Report
  • [Publications] Koji Otomo: "Quantitative Analysis of Hysteresis Characteristics in Reactive Sputtering"Proceedings of the 17^<th> Symposium on Plasma Processing. 177-180 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 松田良信: "反応性スパッタリングによるMgO薄膜作成プロセスの実験的・理論的検討"電子情報通信学会技術研究報告. Vol.100 No.132. 33-38 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Yoshinobu Matsuda: "Quantitative Analysis of Reactive Sputtering Process for MgO Deposition"Proc.Of the Seventh International Display Workshops (IDW2000), Kobe, PDP4-1. 667-670 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Yoshinobu Matsuda: "Quantitative Modeling of Reactive Sputtering Process for MgO Thin Film Deposition"Thin Solid Films. (to be published in Summer of 2001). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] Yoshinobu Matsuda: "Two-dimensional spatial distributions of sputtered particles produced in a planar magnetron discharge of indium-tin-oxide target"Thin Solid Films. Vol.345. 167-171 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Koji Otomo: "Quantitative Analysis of Hysteresis Characteristics in Reactive Sputtering"Proceedings of The 17th Symposium on Plasma Processing. 177-180 (2000)

    • Related Report
      1999 Annual Research Report

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Published: 2000-04-01   Modified: 2016-04-21  

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