| Project/Area Number |
11680507
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
エネルギー学一般
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| Research Institution | Keio University |
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Principal Investigator |
KISHI Tomiya Keio University, Faculty of Science and Technology, Department of Applied Chemistry, Professor, 理工学部, 教授 (50051412)
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| Co-Investigator(Kenkyū-buntansha) |
KATAYAMA Yasushi Keio University, Faculty of Science and Technology, Department of Applied Chemistry, Instructor, 理工学部, 助手 (50286639)
MIURA Takashi Keio University, Faculty of Science and Technology, Department of Applied Chemistry, Professor, 理工学部, 教授 (50051917)
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| Project Period (FY) |
1999 – 2000
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| Project Status |
Completed (Fiscal Year 2000)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,900,000)
Fiscal Year 2000: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 1999: ¥2,700,000 (Direct Cost: ¥2,700,000)
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| Keywords | Graphite intercalation compounds / lithium secondary battery / tantalum chloride / transient metal chlorides / 塩化鉄 / 酸化クロム / 遷移金属酸化物 |
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| Research Abstract |
Graphite intercalation compounds (GIC) of some transition metal chlorides have rigid layered structures and high electronic conductivity. In this study, electrochemical insertion of lithium into the GICs of some transition metal chlorides was investigated in order to apply the GICs to the cathode materials for lithium secondary batteries.
The electrochemical lithiation behavior of a 1 st stage GIC of tantalum pentachloride, C_<20>TaCl_5, was investigated in 1 M LiClO_4/propylene carbonate electrolyte. The degradation of the stage number from 1 st to higher stages was confirmed at the beginning of the discharge, indicating that the deintercalation of tantalum species from the host material occurred. The pentavalent tantalum species, which is in the host material or in the electrolyte, were considered to be reduced to the lower oxidation states. On the other hand, the charge was impossible.
These results showed that the GICs of tantalum chloride are not suit able for cathode materials for lithium secondary batteries. However, it was suggested that lithium can be inserted into the higher stage GICs containing the transition metals which can take various valence states without destruction of the layered structures.
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