SEPARATE MEASUREMENT OF PARTICULATE AND DISSOLVED POLYCYCLIC AROMATIC HYDROCARBONS IN ENVIRONMENTAL WATER AND THEIR MUTAGENICITY ASSAY
| Project/Area Number |
11680538
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Environmental dynamic analysis
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| Research Institution | OKAYAMA UNIVERSITY OF SCIENCE |
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Principal Investigator |
NOGAMI Yusaku OKAYAMA UNIV.OF SCIENCE, SCIENCES, PROFESSOR, 理学部, 教授 (00172768)
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| Co-Investigator(Kenkyū-buntansha) |
KIRA Shohei OKAYAMA UNIV.MEDICAL SCHOOL, MEDICAL, PROFESSOR, 医学部, 教授 (50033212)
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| Project Period (FY) |
1999 – 2000
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| Project Status |
Completed (Fiscal Year 2000)
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| Budget Amount *help |
¥1,800,000 (Direct Cost: ¥1,800,000)
Fiscal Year 2000: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 1999: ¥900,000 (Direct Cost: ¥900,000)
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| Keywords | WATER ENVIRONMENT / POLYCYCLIC AROMATIC HYDROCARBONS / BENZO(A)PYRENE / SUSPENDED SOLID / SEPARATE MEASUREMENT / 懸濁態ベンツピレン / 溶存態ベンツピレン / 変異原性 |
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| Research Abstract |
The state of polycyclic aromatic hydrocarbons (PAHs) in the nature is one of the important issues from the viewpoints of environmental chemistry. When PAHs are transported into environmental water from atmosphere, they adsorb quickly to the suspended solids (SS) because of their hydrophobic property. In this study, we investigated the state of PAHs in natural water obtained from three rivers and Lake Kojima in Okayama Prefecture, Japan. First, SS was separated by glass fiber filter in accordance with the JIS K0102. Subsequently, the amounts of PAHs in SS and in filtrate were measured separately.
The average concentrations of SS in the rivers were 1-2 mg/L, and benzo[a]pyrene in SS (p-BaP) were 1-4 ng/L.The mass ratios of p-BaP to total benzo[a]pyrene (t-BaP = p-BaP+d-BaP) were ca. 60%.
On the other hand, the average concentrations of SS at three different points in L.Kojima were 20-30 mg/L.However, the t-BaP concentrations in water of the lake were the same as those of the rivers. It was also clarified that the ratios of p-BaP to t-BaP of the lake were >90%. Other PAHs, fluoranthene and perylene seem to be adsorbed to SS, too.
The mutagenicity assay of extracts from SS and filtrate was performed according to the preincubation technique of Yahagi et al.. However, no positive ewsult was observed from 300 mL equivalent sample.
The results obtained in this study show that the PAHs amounts in the rivers and the lake are ppt level, and SS adsorbs the most of these chemicals. Therefore, the amounts of PAHs in SS and in filtrate have to be measured simultaneously to evaluate the problems such as endocrine disruption.
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Report
(3 results)
Research Products
(11 results)
