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Crystal structure and solid state physics of earth's interiors under high pressure and high temperature

Research Project

Project/Area Number 11694076
Research Category

Grant-in-Aid for Scientific Research (B).

Allocation TypeSingle-year Grants
Section一般
Research Field Petrology/Mineralogy/Science of ore deposit
Research InstitutionOsaka University

Principal Investigator

YAMANAKA Takamitsu  Graduate School of Science, Osaka Univ. Professor, 大学院・理学研究科, 教授 (30011729)

Co-Investigator(Kenkyū-buntansha) NAGAI Takaya  Graduate School of Science, Osaka Univ. Research Associate, 大学院・理学研究科, 助手 (20243131)
OHTAKA Osamu  Graduate School of Science, Osaka Univ. Associate Professor, 大学院・理学研究科, 助教授 (40213748)
YOSHIASA Akira  Graduate School of Science, Osaka Univ. Associate Professor, 大学院・理学研究科, 助教授 (00191536)
SHIMOMURA Osamu  Graduate School of Science, Osaka Univ., 放射光, 部長
YAGI Takehiko  University of Tokyo Professor, 物性研究所, 教授 (20126189)
Project Period (FY) 1999 – 2000
Project Status Completed (Fiscal Year 2000)
Budget Amount *help
¥5,300,000 (Direct Cost: ¥5,300,000)
Fiscal Year 2000: ¥2,600,000 (Direct Cost: ¥2,600,000)
Fiscal Year 1999: ¥2,700,000 (Direct Cost: ¥2,700,000)
Keywordsmantle substances / electron conductivity under high pressure / electron conductivity of olivine / electron conductivity of wustite / EXAFS at high temperature and pressure / Compression with diamond anvil / multi anvil high-pressure aparatus / syncrotron diffraction experiment
Research Abstract

In order to understand dynamics of mantle or earth's shell, such as subduction of slab, mechanism of deep earthquake and mantle convection, in situ investigations of material sciences of constituent substances under high pressure and temperature are significant subject. Present experimental proposal is the collaboration works between French and Japanese geophysicists with mutual relations. By making use of the facilities in ESRF in Francc and SPring-8 and Photon Factory, phase transitions of oxides and silicates was studied under compression or stress field. Studies of solid state physics of electric conductivity, conductivity, elastic coefficient and thermal expansion coefficient were made using diamond anvil or multianvil high-pressure apparatus. The following experiments were executed :
Electric conductivity measurement of olivine (Mg1-x, Fex)2SiO4 under high pressure and high temperature was carried out by using multianvil high-pressure apparatus. Thc measurement was conducted at te … More mperature up to 1000 and pressure up to 6GPa. Geothermal change with depth can be estimated from the experimental results
The electric conductivity measurement of Fe2SiO4 indicate a large gap of the conductivity at the olivine-spinel transition at about 6GPa. It is clarified that the carrier of the conduction is attributed to the Fe^<2+>⇔Fe^<3+> electron hopping rather than hole.
ÅiCRÅjBy using diamond anvil high-pressure cell, electric conductivity of wustite (Mg1-x, Fex)O, one of major lower mantle substance, was measured measurement as functions of pressure and temperature together with Fe composition (x=0.1, 0.3, 0.5). This experiment was carried out at Inst. Physque du Globe, ) Paris University. Activation energy of electric conductivity was elucidated. With increasing Fe content in the solid solution the conductivity is elevated. The d-electron configuration of Fe ion in the bonding electron raises the conductivity.
ÅiCSÅjCollaboration work with Prof.J.P.Poirier (Inst.Physque du Globe) is the investigation of the melting curve of iron metal, earth core material at extremely high temperature over 2000℃ under high pressure.The experiment was made with the multianvil apparatus and synchrotron radiation at SPring-8. For this experiment The present Grant-in-Aid supported the travel fee of Dr.Andrault. Dr.Ohtaka of Osaka University and Dr.Shimomura of SPring-8 stuff were supporting members.
All experimental results have been reported at several International Conference or workshop and they were published in the science journals. Less

Report

(3 results)
  • 2000 Annual Research Report   Final Research Report Summary
  • 1999 Annual Research Report
  • Research Products

    (67 results)

All Other

All Publications (67 results)

  • [Publications] T.Yamanaka,R.C.Lievermann and C.T.Prewitt: "Thermal expansion of aluminous perovskite ScAlO3"J.Mineral.Pettol.Sci.. 95. 182-192 (2000)

    • Description
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    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Yamanaka,T.Fukuda,T.Hattori and H.Sumiya T.: "New diamond-anvil cell for single-crystal analysis"Rev.Sci.Instrum. 42. 1458-1462 (2000)

    • Description
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    • Related Report
      2000 Final Research Report Summary
  • [Publications] A.Yoshiasa,G.Yagyu T.Ito,T.Yamanaka,and T.Nagai: "Crystal Structure of the high pressure phase (II) in CuGeO3"Zeit.Anorg.Allg.Chem.. 626. 42-49 (2000)

    • Description
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    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Nagai,T.Hattori and T.Yamanaka: "Compression mechanism of brucite : An investigation by structural refinement under pressure"Amer.Miner.. 85. 760-764 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Yamanaka and T.Tsuchiya: "Lattice Instabilities examined by X-ray diffractometry and molecular dynamics"Physics meats Mineralogy ed.H.Aoki,Y.Syono and R.J.Hemley.. 225-241 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Yamanaka,R.Kurashima and J.Mimaki: "X-ray diffraction study of bond character of rutile SiO2, GeO2 and SnO2"Zeit.Krist.. 215. 424-428 (2000)

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    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Tsuchiya, T.Yamanaka and M.Matsui: "Molecular dynamics study of the crystal and phase relation of the GeO_2 polymorphs"Phys.Chem.Mineral.. 25. 94-100 (1998)

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      2000 Final Research Report Summary
  • [Publications] T.Nagai, O.Ohtaka, A.Yoshiasa, T.Yamanaka and O.Shimomura: "Pressure-induced structural modifications of metagermanates at room temperature : In situ XRD and EXAFS studies, Properties of Earth and Planetary Materials at High Pressure and temperature."Geophysical monograph. (1998) Vol.101, AGU,Washington, D.C.. 385-391

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      2000 Final Research Report Summary
  • [Publications] H.Chihara, C.Uyeda, A.Tsuchiyama and T.Yamanaka: "The magnetic ordering of graphite and experimental application to grain ailgnment."Publ.Astron.Soc.Japan. 50. 149-154 (1998)

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      2000 Final Research Report Summary
  • [Publications] A.Yoshiasa, T.Nagai and T.Yamanaka: "Effective pair potentials of NaCl- and CsCl- type KBr determined by X-ray absorption fine structure under pressure."Jpn.J.Appl.Phys.. 37. 728-729 (1998)

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      2000 Final Research Report Summary
  • [Publications] T.Nagai, T.Hattori, T.Tsuchi and T.Yamanaka: "A.New observation of FeGeO_3-perovskite."NIRIM Int.nat.Symp.on AdvanceMeter. (ISAM'98). 241-244 (1998)

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      2000 Final Research Report Summary
  • [Publications] H.Chihara, C.Uyeda, A.Tsuchiyama and T.Yamanaka: "The magnetic ordering of graphite and experimental application to grain alinment."Publ.Astron.Soc.Japan.. 50. 149-154 (1998)

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      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] A.Yoshiasa, T.Nagai and T.Yamanaka: "Effective pair potentials of NaCl- and CsCl- type KBr determined by X-ray absorption fine structure under pressure."Jpn.J.Appl.Phys.. 37. 728-729 (1998)

    • Description
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    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Nagai, T.Hattori, T.Tsuchi and T.Yamanaka: "A.New observation of FeGeO_3-perovskite."NIRIM Int.nat.Symp.on AdvanceMeter. (ISAM'98). 241-244 (1998)

    • Description
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    • Related Report
      2000 Final Research Report Summary
  • [Publications] O.Ohtaka, T.Nagai, T.Yamanaka, T.Yagi and O.Shimomura: "In situ Observation of ZrO_2 Phases at High Pressure and Temperature."Propeties of Earth and Planetary Materials at High Pressure and Temperature, edited by M.H.Manghnani and T.Yagi. AGU Geophysical Monograph. 101. 429-433 (1998)

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      2000 Final Research Report Summary
  • [Publications] T.Nagai, O.Ohtaka, A.Yoshiasa, T.Yamanaka, and O.Shimomura: "Pressure-induced structural modifications of metagermanates at room temperature : In situ XRD and EXAFS studies."Propeties of Earth and Planetary Materials at High Pressure and Temperature, edited by M.H.Manghnani and T.Yagi. AGU Geophysical Monograph. 101. 385-391 (1998)

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      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Yamanaka, K.Tobe, H.Shimazu, A.Nakatsuka, Y.Dobuchi, O.Ohtaka, T.Nagai and E.Ito: "Phase relations and physical properties of Fe_2SiO_4-Fe_3O_3 solid solution under pressure up to 12GPa."Propeties of Earth and Planetary Materials at High Pressure and Temperature, edited by M.H.Manghnani and T.Yagi. AGU Geophysical Monograph. 101. 451-459 (1998)

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      2000 Final Research Report Summary
  • [Publications] T.Nagai, S.Mori, O.Ohtaka and T.Yamanaka: "Nucieation and growth kinetics of the α-quartz-coesite transformations using both powder and single crystal samples. Propeties of Earth and Planetary"Materials at High Pressure and Temperature, edited by M.H.Manghnani and T.Yagi. AGU Geophysical Monograph. 101. 451-459 (1998)

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      2000 Final Research Report Summary
  • [Publications] Y.Matsumoto, O.Ohtaka, M.Kikuchi, N.Nagai, T.Yamanaka and O.Shimomura: "Pressure induced Structural Transition of Cdl2-type PbI2."Propeties of Earth and Planetary Materials at High Pressure and Temperature, edited by M.H.Manghnani and T.Yagi.AGU Geophysical Monograph. 101. 451-459 (1998)

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      2000 Final Research Report Summary
  • [Publications] T.Yamanaka and T.Nagai: "Phase transformations and lattice instability of earth interiors under high pressure and stress field."Propeties of Earth and Planetary Materials at High Pressure and Temperature, edited by M.H.Manghnani and T.Yagi. AGU Geophysical Monograph. 101. 451-459 (1998)

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      2000 Final Research Report Summary
  • [Publications] T.Nagai, T.Hattori, T.Tsuchiya and T.Yamanaka.: "First obserbation of FeGeO_3-Perovskite under highpressure"Solid State Comm.. Vol.107, No.5. 223-225 (1998)

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  • [Publications] S.Kawasaki, T.Aket, F.Okino, H.Touhara, T.Hattori, T.Nagai, and T.Yamanaka.: "Stability of C70Fxdrystalline under high pressure"Solid State Communications. Vol.10. 749-752 (1998)

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      2000 Final Research Report Summary
  • [Publications] T.Hattori, T.Matsuda, T.Tsuchiya, T.Nagai and T.Yamanaka: "Clinopyroxene-perovskite phase transition of FeGeO_3 under high pressure and room temperature."Phys.Chem.Minerals.. 26. 212-216 (1999)

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      2000 Final Research Report Summary
  • [Publications] A.Nakatsuka, A.Yoshiasa, T.Yamanaka, T.Katsura and E.Ito: "Symmetry change of majorite solid solution in the system Mg_3Al_2Si_3O_<12>-MgSiO_3"Am.Mineral.. 84. 1135-1143 (1999)

    • Description
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      2000 Final Research Report Summary
  • [Publications] A.Nakatsuka, A.Yoshiasa, T.Yamanaka and E.Ito.: "Structure refinement of a birefringent Cr-bearing majorite Mg_3(Mg_<0.34>Si_<0.34>Al_<0.18>Cr_<0.14>)Si_3O_<12>"American Mineralogist. Volume 84. 199-202 (1999)

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      2000 Final Research Report Summary
  • [Publications] O.Ohtaka, M.Kikuchi, K.Nakajima, A.Yoshiasa and T.Yamanaka.: "EXAFS study of densified GeO_2 glasses"Jpn.J.Appl.Phys.. Vol.38 Supp ; .38-1. 164-167 (1999)

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      2000 Final Research Report Summary
  • [Publications] A.Nakatsuka., A.Yoshiasa. and T.Yamanaka.: "Cation distribution and crystal chemistry of Y_3Al_<5-x>Ga_xO_<12> (0≦x≦5) gamet solid solutions"Acta Cryst.. B55. 266-272 (1999)

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      2000 Final Research Report Summary
  • [Publications] A.Yoshiasa, T.Nagai, O.Ohtaka, O.Kamishima and O.Shimomura: "Pressure and temperature dependence of EXAFS Debye-Waller factors in diamond-type white-tin-type germanium"J.Synchrotron Rad.. 6. 43-49 (1999)

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      2000 Final Research Report Summary
  • [Publications] A.Yoshiasa and H.Maeda: "Anharmonic effective pair potentials of b- and a-AgI determined by I K-edge EXAFS"Solid State Ionics. 121. 175-182 (1999)

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      2000 Final Research Report Summary
  • [Publications] A.Yoshiasa, T.Tamura, O.Kamishima, K.Murai, K.Ogata and H.Mori: "Local structure and mean-square relative displacement in SiO2 and GeO2 polymorphs"J.Synchrotron Rad.. 6. 1051-1058 (1999)

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      2000 Final Research Report Summary
  • [Publications] T.Yamanaka, T.Fukuda, T.Hattori and H.Sumiya: "New diamond-anvil cell for single-crystal analysis"Rev.Sci.Inst.. 42. 1458-1462 (2000)

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      2000 Final Research Report Summary
  • [Publications] T.Yamanaka, R.C.Libermann and C.T.Prewitt: "Thermal expansion of alumnus perovskite ScAlO3"J.Mineral.Peterol.Sci.. 95. 182-192 (2000)

    • Description
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      2000 Final Research Report Summary
  • [Publications] T.Yamanaka, R.Kurashima and J.Mimaki: "X-ray diffraction study of bond character of rutile SiO2, GeO2 and SnO2"Zeit.Krist.. 215. 424-428 (2000)

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      2000 Final Research Report Summary
  • [Publications] J.Mimaki, T.Tsuchiya and T.Yamanaka: "The bond character of rutile type SiO2, GeO2 and SnO2 investigated by molecular orbital calculation"Zeit Krist.. 215. 419-423 (2000)

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  • [Publications] T.Hattori, T.Nagai, T.Yamanaka, S.Werne, and H.Schulz: "Single-crystal X-ray diffraction study of FeGeO3 high-P clinopyroxen (C2/c) up to 8.2 GPa"Amer.Mineral.. 85. 1485-1491 (2000)

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      2000 Final Research Report Summary
  • [Publications] T,Ito, A.Yoshiasa and T.Yamanaka.: "Site preference of cations and structure variation in MgAl2-xGaxO4 (0<x, 2) spinel solid solution."Zeit. Anorg. Allg. Chem.. 626. 42-49 (2000)

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      2000 Final Research Report Summary
  • [Publications] A.Yoshiasa, G.Yagyu T.Ito, T.Yamanaka, and T.Nagai: "Crystal Structure of the high pressure phase (II) in CuGeo3"Zeit.Anorg.Allg.Chem.. 626. 42-49 (2000)

    • Description
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      2000 Final Research Report Summary
  • [Publications] T.Nagai, T.Hattori and T.Yamanaka: "Compression mechanism of brucite : An investigation by structural refinerment under pressure"Amer.Miner.. 85. 760-764 (2000)

    • Description
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    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Tsuchiya T.Yamanaka and M.Matsui: "Molecular dynamical study of pressure-induced transformation of quartz-type GeO2"Phys.Chem.Mineral.. 149-155 (2000)

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      2000 Final Research Report Summary
  • [Publications] H.Fukui, O.Otaka, T.Nagai, T.Katsura, K.Funakashi and W.Utsumi: "Melting of nportlandite up to 6 GPa"Phys.Chem.Mineral. 27. 367-370 (2000)

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      2000 Final Research Report Summary
  • [Publications] A.Yoshiasa, M.Okube, O.Ohtaka, O.Kamishima, Y.Katayama: "Anharmonic Effective pair potentials of g- and a-CuBr at high pressure"J.Appl.Phys.. 39. 6747-6751 (2000)

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  • [Publications] A.Tani, C.Yamanaka, M.Ikeya, O.Ohtaka and K.Katsura: "ESR study of a new electron center in synthetic stishovite, a high-pressure polymorph of silica"Appl.Magn.Reson.. 18. 559-564 (2000)

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  • [Publications] A.Tani, C.Yamanaka, M.Ikeya, O.Ohtaka M.Takada and K.Katsura.: "Optically stimulated luminescence (OSL) study of synthetic stishovite"Radiation Meas.. 32. 473-477 (2000)

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      2000 Final Research Report Summary
  • [Publications] T.Yamanaka: "Pressure-induced profile change of energy dispersive diffraction using synchrotron radiation"Defect and Microstructure Analysis by Diffraction ed. R.L.Snyder, J.Fiala and H.J.Bunge. (1999)

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      2000 Final Research Report Summary
  • [Publications] T.Yamanaka and T.Tsuchiya: "Lattice Instabilities examined by X-ray diffractometry and molecular dynamics"Physics meats Mineralogy 225-241 2000 ed.H.Aoki, Y.Syono and R.J.Hemley.. 225-241 (2000)

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      2000 Final Research Report Summary
  • [Publications] T.Yamanaka, H.Shimazu and K.Ota: "Electric Conductivity of the Fe2Sio4-Fe3O4 Spinel Solid Solution"Phys.Chem.Mineral..

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      2000 Final Research Report Summary
  • [Publications] T.Yamanaka and M.Okita: "Magnetic Properties of the Fe2SiO4-Fe3O4 Spinel Solid Solution"Phys.Chem.Mineral..

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  • [Publications] T.Hattori, T.Tsuchiya, T.Nagai and T.Yamanaka: "Sequential high-presswure transformations of FeGeO3 high-Pclinopyroxene (C2/c) at temperatures up to 365℃"Amer. Mineral..

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      2000 Final Research Report Summary
  • [Publications] T.Tsuchi, K.Kawamura and T.Yamanaka: "Mechanism of pressure-induced transitions of rutile-type materials : Comparative study of SiO2 and MnF2"Phys.Rev.

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      2000 Final Research Report Summary
  • [Publications] O.Otaka H.Fukui, T.Kunisada, F.Fujisawa, K.Funakoshi, T.Irifune, K.Kuroda, T.Kikegawa: "Phasew relation and Volume chage of hafnia under high-pressure and high-temperature"

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      2000 Final Research Report Summary
  • [Publications] O.Ohtaka, A.Yoshiasa, H.Fukui, K.Murai, M.Okube, Y.Katayama, W.Utsumi, Y.Nishihata: "Structure changes of quartz-type crystalline and vitreous GeO2 under pressure"

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      2000 Final Research Report Summary
  • [Publications] H.Fukui, O.Ohtaka, T.Katsura T.Nagai, K.Funakoshi, W.Utsumi and T.Kikegawa: "Pressure relation of Ca(OH)2 under high-temperature and high-pressure conditions"

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      2000 Final Research Report Summary
  • [Publications] T.Yamanaka,R.C.Lievermann and C.T.Prewitt: "Thermal expansion of aluminous perovskite ScAlO3"J.Mineral.Petrol.Sci.. 95. 182-192 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Yamanaka,T.Fukuda,T.Hattori and H.SumiyaT.: "New diamond-anvil cell for single-crystal analysis"Rev.Sci.Instrum. 42. 1458-1462 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] A.Yoshiasa,G.Yagyu,T.Ito,T.Yamanaka,and T.Nagai: "Crystal Structure of the high pressure phase(II)in CuGeO3"Zeit.Anorg.Allg.Chem.. 626. 42-49 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Nagai,T.Hattori and T.Yamanaka: "Compression mechanism of brucite : An investigation by structural refinement under pressure"Amer.Miner.. 85. 760-764 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Yamanaka and T.Tsuchiya: "Lattice Instabilities examined by X-ray diffractometry and molecular dynamics"Physics meats Mineralogy ed.H.Aoki,Y.Syono and R.J.Hemley.. 225-241 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Yamanaka,R.Kurashima and J.Mimaki: "X-ray diffraction study of bond character of rutile SiO2, GeO2 and SnO2"Zeit.Krist.. 215. 424-428 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Hattori,T.Matsuda,T.Tsuchiya,T.Nagai and T.Yamanaka: "Clinopyroxene-perovskite phase transition of transition of FeGeO_3 under high pressure and room temperature."Phys.Chem.Minerals.. 26. 212-216 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] A.Nakatsuka,A.Yoshiasa,T.Yamanaka,T.Katsura and E.Ito: "Symmetry change of majorite Solid solution in the system Mg_3Al_2Si_3O_<12>-MgSiO_3"Am.Mineral.. 84. 1135-1143 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] A.Nakatsuka,A.Yoshiasa, and E.Ito: "Structure refinement of a birefringent Cr-bearing majorite Mg_3(Mg_<0.34>Si_<0.34>Al_<0.18>Cr_<0.14>)Si_3O_<12>"American Mineralogist,. 84. 199-202 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 山中 高光: "高圧・応力過程での相転移の動的観察"日本結晶学会誌. 41. 32-41 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] O.Ohtaka,M.Kikuchi,K.nakajima,A.Yoshiasa and T.Yamanaka.: "EXAFS study of densified GeO_2 glasses"Jpn.J.Appl.Phys.. 38. 164-167 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] A.Nakatsuka,A.Yoshiasa,T.Yamanaka,T.katsura.: "Cation distribution and crystal chemistry of Y_3Al_<5-x>Ga_xO_<12>(0≦x≦5)"Acta Cryst.. B55. 266-272 (1999)

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      1999 Annual Research Report
  • [Publications] A.Yoshiasa,T.Nagai,O.Ohtaka,O.Kamishima and O.Shimomura: "Pressure and temperature dependence of EXAFS Debye-waller factors in diamond type and white-tin type germanium"J.Synchrotron Radiation,. 6. 43-49 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Ito,A.Yoshiasa and T.Yamanaka: "Site preference of cations and structure variation in MgA12-xGaxO4(0<x,2) spinel solid solution"Zeit.Anorg.Allg.Chem.. 626. 42-49 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] A.Yoshiasa,G.Yagtu T.Ito,T.Yamanaka, and T.Nagai: "Crystal Structure of the high pressure phase (II) in CuGeO3"Zeit.Anorg.Allg.Chem.. 626. 36-41 (2000)

    • Related Report
      1999 Annual Research Report

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Published: 1999-04-01   Modified: 2021-09-02  

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