| Project/Area Number |
11694156
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
電子デバイス・機器工学
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| Research Institution | Osaka University |
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Principal Investigator |
YOSHINO Katsumi Osaka University Graduate School of Engineering Professor, 大学院・工学研究科, 教授 (70029205)
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| Co-Investigator(Kenkyū-buntansha) |
FUJII Akihiko Osaka University Graduate School of Engineering Research Associate, 大学院・工学研究科, 助手 (80304020)
OZAKI Masanori Osaka University Graduate School of Engineering Associate Professor, 大学院・工学研究科, 助教授 (50204186)
大森 裕 大阪大学, 先端科学技術共同研究センター, 教授 (50223970)
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| Project Period (FY) |
1999 – 2001
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| Project Status |
Completed (Fiscal Year 2001)
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| Budget Amount *help |
¥8,700,000 (Direct Cost: ¥8,700,000)
Fiscal Year 2001: ¥2,800,000 (Direct Cost: ¥2,800,000)
Fiscal Year 2000: ¥2,800,000 (Direct Cost: ¥2,800,000)
Fiscal Year 1999: ¥3,100,000 (Direct Cost: ¥3,100,000)
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| Keywords | π-conjugated polymer / conducting polymer / exciton / polaron pair / laser / excited electronic states / photonic band / opal |
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| Research Abstract |
Various types of n-conjugated polymers have been designed and synthesized to realized a novel solid laser with a high performance and their electronic and optical characteristics have been investigated. The electronic and optical properties such as a photo-excited electronic state in polyacetylene derivatives having various substituents have been investigated by a UV-visible absorption and luminescence measurements and a life time measurement of the luminescence. The relationship between electronic state and molecular structure in π-conjugated polymers with hetero main chain structures including Si atom has been investigated, and it is found that the effective π-conjugation length can be controlled by the introduction of Si atom. Fabrication techniques for solid lasers such as a spin coating and self-assembly methods have been improved and light emission characteristics have been investigated. Based on a nonlinear photoconductivity upon a high intensity excitation in the π-conjugated polymers, an excitation process for the photoconduction has been revealed by means of a pump and probe technique using a femto second high intensity laser. It is found that a polaron pair plays an important role in a photo-excitation process in π-conjugated polymers. The inverse opal of π-conjugated polymer has been fabricated. Poly(3-alkylthiophene) is infiltrated into nano-scale voids of SiO_2 synthetic opal in the melted state and subsequently SiO_2 spheres is removed by a chemical treatment, resulting in the conjugated polymer inverse opal. The reflection spectrum of the polymer inverse opal can be controlled by a thermal treatment and electrochemical doping, which is interpreted to be due to a refractive index change in poly(3-alkylthiophene) based on the change in electronic state upon the temperature change and electrochemical doping.
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