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Dynamic Studies of Self-organizing Polymeric Materials

Research Project

Project/Area Number 11695049
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 高分子構造・物性(含繊維)
Research InstitutionKyoto Institute of Technology

Principal Investigator

KUNUGI Shigeru  Kyoto Institute of Technology, Faculty of Textile Science, Professor, 繊維学部, 教授 (70111929)

Co-Investigator(Kenkyū-buntansha) KIMURA Yoshiharu  Kyoto Institute of Technology, Faculty of Textile Science, Professor, 繊維学部, 教授 (10132276)
SAKURAI Shinichi  Kyoto Institute of Technology, Faculty of Textile Science, Ass. Prof., 繊維学部, 助教授 (90215682)
ITAYA Akira  Kyoto Institute of Technology, Faculty of Textile Science, Professor, 繊維学部, 教授 (80035071)
TSUTSUMI Naoto  Kyoto Institute of Technology, Faculty of Textile Science, Professor, 繊維学部, 教授 (50172036)
MIYATA Takaaki  Kyoto Institute of Technology, Faculty of Textile Science, Professor, 繊維学部, 教授 (50188827)
柴山 充弘  東京大学, 物性研究所, 教授 (00175390)
Project Period (FY) 1999 – 2001
Project Status Completed (Fiscal Year 2001)
Budget Amount *help
¥4,500,000 (Direct Cost: ¥4,500,000)
Fiscal Year 2001: ¥1,500,000 (Direct Cost: ¥1,500,000)
Fiscal Year 2000: ¥1,400,000 (Direct Cost: ¥1,400,000)
Fiscal Year 1999: ¥1,600,000 (Direct Cost: ¥1,600,000)
KeywordsSelf-organixation / Polymer Materials / Dymanics / Polymer Gels / Polymer Films / Block-copolymerization / Polymer Blends / Photofuctinality
Research Abstract

This study has initiated by collaboration with the researchers in the related fields in the department of chemistry and materials science of Polytechnic University, N Y, USA, in order to elucidate the dynamic aspects of self-organizing and self-structuring polymeric materials, in which multi-phase and hierarchic structures are the characteristics. The total plan has been grouped in to the following five categories :
1. Slow dynamics of structural formation in polymer-blend organizing materials.
2. Development of new block copolymers and their organization and functionalization.
3.Analysis of organizing superstructures by use of dynamic light scattering method.
4. Structurization of synthetic-biological complex systems and reaction analysis.
5. Development of new photo-functional organizing materials.
6. Molecular design of self-organizing materials.
The attained results from each category were :
1. Optical observation of organizing process during the phase-separation of thermoresponsive phase-separating polymericmaterials.
2. Development of A-B-A type block copolymer having amphiphilic properties by using terechelic reactive oligomers.
3. Structural analysis of block- and blend-based organizing materials.
4. Unified understanding for structural formations in proteins and synthetic polymers.
5.Development of new self-organizing polymeric materials in which structural formation is induced by light stimulation.
6. Design and development of novel biodegradable polyester-based self-organizing materials.
These works have been carried out with a tight exchange of research information and discussion between two Institutes and Joint-symposium was organized every year to present the details of newly attained results and to exchange productive discussion upon every result.

Report

(4 results)
  • 2001 Annual Research Report   Final Research Report Summary
  • 2000 Annual Research Report
  • 1999 Annual Research Report

Research Products

(30 results)

All Other

All Publications (30 results)

  • [Publications] TSUTSUMI N.: "Diffraction measurement for grating formed in optically poled polymeric materials"Jpn. J. Appl. Phys.. 40. 2264-2268 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] URAKAWA O.: "A Dielectric Study on the Local Dynamics of Miscible Polymer Blends : Poly-2-chlorostyrene/Poly(vinyl methyl ether)Blend"Polymer. 42. 765-773 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] FUJIWARA T.: "Self-organization of Diblock and Triblock Copolymers of Poly(L-Lactide)and Poly(Oxy-ethylene)into Nanostructured Bands and their Network System. Proposition of a Doubly Twisted Chain Conformation of Poly(L-Lactide)"Macromolecule. 34(12). 4043-4050 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] SAKURAI S.: "Preferential Orientation of Lamellar Microdomains Induced by Uniaxial Stretching of Cross-Linked Polystyrene-block-Polybutadiene-block-polystyrene Triblock Copolymer"Macromolecules. 34. 3672-3678 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] TSUBOI Y.: "Pulsed laser deposition of silk protein : Effect of photosensitized-ablation on the secondary structure in thin deposited films"J. Appl. Phys.. 89. 7917-7923 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] KUNUGI S.: "Effects of Pressure on the Behavior of(Hydroxypropyl)cellulose in Aqueous Solution"Colloid Polym. Sci. 279. 1139-1143 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] KUNUGI S., YOSHIDA D., KIMINAMI H.: "Effects of Pressure on the fehavior of (Hydroxypropyl)cellulose in Aqueous Solution"Colloid Polym. Sci.. 279. 1139-1143 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] TSUBOI Y., IKEJIRI T., SHIGA S., YAMADA K., ITAYA A: "an transform the secondary structure of silk protein"Appl. phys. A.. 73(5). 637-640 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] SAKURAI S., AIDA S., OKAMOTO S., ONO T., IMAIZUMI K., NOMURA S.: "Preferential Orientation of Lamellar Microdomains Induced by Uniaxial Stretching of Cross-Linked Polystyrene-block-Polybutadiene-block-polystyrene Triblock Copolymer"Macromolecules. 34. 3672-3678 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] FUJIWARA T., MIYAMOTO M., KIMURA Y., IWATA T., DOI Y.: "self-organization of Diblock and Triblock Copolymers of Poly(L-actide) and Poly(Oxyethylene) into Nanostructured Bands and their Network System. Proposition of a Doubly Twisted Chain Conformation of Poly(L-Lactide)"Macromolecules. 34(12). 4043-4050 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] URAKAWA O., FUSE Y., HORI H., TRAN-CONG-MIYATA Q.,YANO O: "A Dielectric Study on the Local Dynamics of Miscible Polymer Blends : Poly-2-chlorostyrene/Poly(vinyl methyl ether) Blend"Polymer. 42. 765-773 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] TSUTSUMI N., YAMAMOTO J. SAKAI W.: "Diffraction measurement for grating formed in optically poled polymeric materials"Jpn. J. Appl. Phys.. 40. 2264-2268 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] TSUTSUMI N: "Diffaction measurement for gating formed in optically poled polymeric materials"Jpn.J.Appl.Phys.. 40. 2264-2268 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] URAKAWA.O: "A Dielectric Study on the Local Dynamics of Miscible Polymer Blends. Poly-2-chlorostyrene/Poly(vinyl methyl ether)Blend"Polymer. 42. 765-773 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] FUJIWARA T: "Self-organization of Diblock and Triblock Copolymers of Poly(L-Lactide) and Poly(Oxy-ethylene) into Nanostructured Bands and their Network System. Proposition of a Doubly Twisted Chain Conformation of Poly(L-Lactide)"Macromolecule. 34(12). 4043-4050 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] SAKURAI S: "Preferential Orientation of Lamellar Microdomains Induced by Uniaxial Stretching of Cross-Linked Polystyrene-block-polybutadiene-block-polystyrene Triblock Copolymer"Macromolecules. 34. 3672-3678 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] TSUBOI Y: "Pulsed laser deposition of silk protein : Effect of photosensitized-ablation on the secondary structure in thin deposited films"J.Appl.Phys. 89. 7917-7923 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] KUNUGI S: "Effects of Pressure on the Behavior of (Hydroxypropyl) cellulose in Aqueous Solution"Colloid Polym. Sci.. 279. 1139-1143 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] T.Tamura: "Effects of Temperature and Pressure on the Aggregation Properties of an Engineered Elastin Model Polypeptide in Aqueous Solution"Biomacromolecules. 1(4). 552-555 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] S.Komamine: "Photoinduced electron transfer between C60 and carbazole dimer compounds in a polar solvent"J.Photochem.Photobiol.A : Chemistry. 135. 111-117 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] S.Takata: "Heat-Induced Gelation of β-Lactoglobulin. 1. Time-Resolved Dynamic light Scattering"Macromolecules. 33(15). 5470-5475 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] K.Sakurai: "Preferential orientation of crystallites spatially confined in lamellar microdomains of polyethylene-block-[atactic poly (propylene)]"Macromolecular Rapid Communication. 21. 1140-1143 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Fujiwara: "Tailoring of Block Copolymers Based on the Stoichiometric Control of the End-Funnctionality of Telechelic Oligomers and the Utilization of Large-Scale Fractionation by Phase Fluctuation Chromatography : A Synthetic Strategy for the Preparation of End-Functionalized Poly (L-lactide)-block-poly (oxyethylene)"Journal of Polymer Science : Part A : Polymer Chemistry. 38. 2405-2414 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Fujiwara: "Crystallization-Induced Morphological Changes of a Poly (L-lactide) / Poly (oxyethylene) Diblock Copolymer from Sphere to Band via Disk : A Novel Macromolecular Self-Organization Process from Core-Shell Nanoparticles on Surface."Macromolecules. 33(8). 2782-2785 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] S.Kunugi 他: "Thermodynamic studies on coil-globule transitions of poly(N-vinylisobutyramide-co-vinylamine) (pNVIBA-co-VAm) in aqueous solutions"Langmuir. 16(4). 2040-2042 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Sumiyoshi 他: "Vacuum-deposited films of mesogen of 4-n-pentyl-4"-cyano-terphenyl: Their electron spectra and molecular aggregation structures"Thin Solid Films. 未定(in press). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] M.Takeda 他: "Critical dynamics of cross-linked polymer chains near gelation threshold"Macromolecules. 33(in press). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Y.Imamura 他: "Polarized light-induced photoisomerization in glassy poly(methyl methacrylat) and local relaxation processes of the polymer matrix"J. Polym. Sci., Polym. Phys.. 38(in press). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Fujiwara 他: "Separation of a dibrock-triblock copolymer mixture by phase fluctuation chromatography"Macromolecules. 33(in press). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] J.K.Kim 他: "Lattice disordering and domain dissolution transitions in polystyrene-block-poly(ethylene-co-but-l-ene)-block-polystyrene triblock copolymer having asymmetric composition"Macromolecules. 32(20). 6707-6717 (1999)

    • Related Report
      1999 Annual Research Report

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Published: 1999-03-31   Modified: 2016-04-21  

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