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一方向凝固偏晶・共晶合金の協調成長および偏析挙動に及ぼす重力の影響

Research Project

Project/Area Number 11750641
Research Category

Grant-in-Aid for Encouragement of Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Metal making engineering
Research InstitutionHiroshima University

Principal Investigator

吉田 誠  広島大学, 工学部, 助手 (80277847)

Project Period (FY) 1999 – 2000
Project Status Completed (Fiscal Year 2000)
Budget Amount *help
¥2,200,000 (Direct Cost: ¥2,200,000)
Fiscal Year 2000: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 1999: ¥1,500,000 (Direct Cost: ¥1,500,000)
Keywords凝固 / 共晶 / 比重差 / 重力 / 協調成長 / monotectic / eutectic / solidification / gravity
Research Abstract

共晶合金の協調成長(カップルドグロース)に対する、晶出相間の比重差および対流の影響を、おのおの別個に評価、検討した。
装置は、当該研究のために新たに開発した「有機物用縦型帯域溶融結晶成長装置」および「その場観察装置」を用いた。
対流は、協調成長における溶質再分配の質量流束よりも1000倍以上大きい質量流束を有することが分かった。晶出相間に比重差がない場合は、対流は、晶出相の間隔を短くする傾向が確認された。
晶出相間に比重差がある場合は、重力方向と反重力方向の一方向凝固組織に、差が生ずることが確認された。特に、irregular faceted/nonfaceted共晶系に分類され、なおかつ晶出相間に比重差がある場合は、凝固組織は成長方向の影響を受ける。
その理由は、irregular faceted/nonfaceted共晶系ではセクロ界面が平滑ではないため、regular系におけるlateral diffusionのみなく、成長方向の溶質拡散、すなわちvertical diffusionが必要となる。結果として、液相の平均比中よりも比重の大きい溶質成分は、反重力方向への拡散が困難となり、逆に比重の小さい溶質成分は、重力方向への拡散が困難となるためと考えられる。

Report

(2 results)
  • 2000 Annual Research Report
  • 1999 Annual Research Report
  • Research Products

    (9 results)

All Other

All Publications (9 results)

  • [Publications] Makoto,YOSHIDA: "Influence of gravity on the microstructure of directionally solidified Ag-Si eutectic alloy"Mater.Trans.JIM. 40. 27-33 (1999)

    • Related Report
      2000 Annual Research Report
  • [Publications] Makoto,YOSHIDA: "Gravitational Effect on the Microstructure of Unidirectionally Solidified Monotectic and Eutectic Alloys"Mater.Sci.Forum. 329. 259-264 (1999)

    • Related Report
      2000 Annual Research Report
  • [Publications] Makoto,YOSHIDA: "Gravitational Effect on the Microstructure of Unidirectionally Solidified Cu-Pb Monotectic Alloy"Proc.4th Pacific Rim International Conf.on Modeling of Casting and Solidification Processes. 331-339 (1999)

    • Related Report
      2000 Annual Research Report
  • [Publications] Makoto,YOSHIDA: "Influence of Gravity on the Monotectic and Eutectic Growth"Proc.2nd Int.Conf.on Processing Materials for Properties (PMP2000). 2. 1017-1022 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Makoto,YOSHIDA: "Influence of Growth Direction on the Microstructure of Unidirectionally Solidified Cu-Pb Monotectic Alloy Using Zone-melt Technique"J.Cryst.Growth. 222. 806-815 (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] 吉田 誠: "一方向凝固したAl-In偏晶合金の凝固組織に及ぼす重力の影響"日本金属学会誌. Vol.62. 85-91 (1998)

    • Related Report
      1999 Annual Research Report
  • [Publications] I.Aoi: "Influence of Gravity on the Microstructure of Directionally Solidified Ag-Si Eutectic Alloy"Mater.Trans.,JIM. Vol.40. 27-33 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] I.Aoi: "Gravitational Effect on the Microstructure of Unidirectionally Solidified Monotectic and Eutectic Alloys"Mater.Sci.Forum. Vols.329-330.

    • Related Report
      1999 Annual Research Report
  • [Publications] I.Aoi: "Gravitational Effect on the Microstructure of Unidirectionally Solidified Cu-Pb Monotectic Alloys"Proc.4th Pacific Rim International Conf. on Modeling of Casting and Solidfication Processes,.

    • Related Report
      1999 Annual Research Report

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Published: 1999-04-01   Modified: 2016-04-21  

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