| Project/Area Number |
11793008
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| Research Category |
Grant-in-Aid for University and Society Collaboration
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| Allocation Type | Single-year Grants |
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| Research Field |
有機工業化学
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| Research Institution | Osaka Prefecture University |
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Principal Investigator |
TAKATA Toshikazu Osaka Prefecture University, Graduate School of Engineering, Professor, 工学研究科, 教授 (40179445)
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| Co-Investigator(Kenkyū-buntansha) |
YAMADA Nobuo Daiso Co., Ltd. Corporate Business Development Department Manager, 総合開発部, 次長
KIHARA Nobuhiro Osaka Prefecture University, Graduate School of Engineering, Associate Professor, 工学研究科, 助教授 (30214852)
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| Project Period (FY) |
1999 – 2001
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| Project Status |
Completed (Fiscal Year 2001)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,900,000)
Fiscal Year 2001: ¥3,900,000 (Direct Cost: ¥3,900,000)
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| Keywords | Sodium / Sulfur / Oligosulfide / Silane Coupling Agent / Energy-Saving Tire / Monosulfide / Calsium Sulfide / Control of Sulfur Chain Length / 低燃費タイヤ / カルシウムスルフィド / 金属ナトリウム / 単体硫黄 / ナトリウムポリスルフィド / 省エネルギータイヤ / 固体 固体反応 / 無水物 / 一電子移動 / 省エネタイヤ / 製造プロセス / ジメトキシエタン |
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| Research Abstract |
Using specific ether solvents, successful control of the direct reaction of sodium metal with elemental sulfur was attained. Especially, use of dimethoxyethane gave the best result. In this system, anhydrous sodium oligosulfide in which composition was corresponded to the feed ratio was obtained. Further, the reaction of the oligosulfide with 3-(triethoxysilyl)propyl chloride afforded corresponding silane coupling agent having oligosulfide structure quantitatively. To reveal the distribution of sulfur chain of oligosulfide, the oligosulfide was reacted with alkylation agent such as methyl iodide, butyl bromide, and benzyl chloride as the model reaction. The resulting dialkyloligosulfides were isolated to determine the structure and the distribution of sulfur chains by various spectroscopic analyses. The relationship between the sulfur chain distribution and the physical properties of the rubber was discussed. Further, in comparison of the silane coupling agent obtained in this study with that commercially available, the former is superior to the latter as the additive for the tire thread because thermal crosslinking was suppressed.
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