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Distributions and properties of grain boundary thin film water in the earth's interior

Research Project

Project/Area Number 12304034
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Petrology/Mineralogy/Science of ore deposit
Research InstitutionTokyo Institute of Technology

Principal Investigator

NAKASHIMA Satoru  Tokyo Institute of Technology, Graduate School of Science and Engineering, Professor, 大学院・理工学研究科, 教授 (80237255)

Co-Investigator(Kenkyū-buntansha) KAWAMURA Katsuyuki  Tokyo Institute of Technology, Graduate School of Science and Engineering, Professor, 大学院・理工学研究科, 教授 (00126038)
NAKAMURA Michihiko  Tohoku University, Graduate School of Science, Associate Professor, 大学院・理学研究科, 助教授 (70260528)
丸山 茂徳  東京工業大学, 大学院・理工学研究科, 教授 (50111737)
Project Period (FY) 2000 – 2003
Project Status Completed (Fiscal Year 2003)
Budget Amount *help
¥47,820,000 (Direct Cost: ¥45,900,000、Indirect Cost: ¥1,920,000)
Fiscal Year 2003: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2002: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2001: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2000: ¥39,500,000 (Direct Cost: ¥39,500,000)
KeywordsNear Field Infrared Microspectrometer / Infrared microspectroscopy / Water in the crust and mantle / Volcanic glass / Grain boundary / thin film water Constrained "hard"water / 「かたい」水 / 変成岩中の水 / マントル物質 / 粒径 / 粒界の幅 / NaCl多結晶体 / 水溶液 / 減衰全反射赤外分光 / OH伸縮振動吸収帯 / NaCl / 炭酸 / 流体包有物
Research Abstract

In order to study the distributions and properties of water in the earth's interior, infrared microspectroscopic methods have been used to measure water in various crustal and mantle materials
1)Near-Field infrared Microspectroscopy
A new water characterization method has been developed by combining a near field microscopy spectroscopy. This and infrared Near-field infrared (NFIR) microspectroscopy can measure chemical states and contents of water down to about I wt% in submicron scale down to about 300nm. Mapping results by this NFIR method on microcrystalline quartz aggregates (agate) revealed constrained structures of water along grain boundaries with shorter hydrogen-bond distances.
2)Distribution of water in the crust and mantle materials
infrared microspectroscopy on various crustal and mantle rocks revealed the following distributions of water in the earth's interior.
a)Water in deep subducted metamorphic rock to the depth of about 200 km is distributed in defects in clinopyroxnes ar … More id garnets with average contents of 2000 ppm, evidencing the water transport to the mantle.
b)Water in mantle can be stored in defects of mantle minerals such as perovskites upto about 2000 ppm. This is corresponding to 5 times as much water as the present sea water can be stored in the mantle.
c)Water in magma and erupted materials can be measured by infared microspectroscpy by using molar absorption coefficients determined by our studies. In-situ dehydration behaviors of magma can be studied also by this technique.
d)Fluids in shear zones in metamorphic rocks have contrasted wetting properties due to their chemistries (NaCl vs. C02) and this difference in wetting properties is expected to be much larger at metamorphic conditions.
e)Water in low grade metamorphic rocks is found to be distributed mainly ingrain boundaries.
3)Synthetic grain boundary water and synthetic aqueous solutions
In order to study experimentally the structures and properties of water in grain boundaries, several synthetic thin film water have been measured by infrared microspectroscopy. Thin film water showed a OH stretching absorption peak shift from 3400 to around 3200cm-1 indicating shorter hydrogen-bonding distance close to ice. Water sandwitched in minerals appeared to be constrained from about 200nm. This structural modification is dependent on mineral species and crystallographic orientations.
Synthetic aqueous solutions were studied by Attenuated Total Reflection (ATR) infrared spectroscopy, and NaCl solutions showed more loose nature with longer H-bond, while carbonate solutions indicated more tight nature with shorter H-bond. These aqueous solutions become "looser"at higher temperatues.
We organized an international symposium on September 13, 2003 in Tokyo Institute of Technology to discuss these results with international experts from physics, chemistry and earth sciences. The results of the symposium is now edited as a proceeding book which will be published in July-August 2004 (Nakashima, S.Mercury. L.Fenter, P. and Spiers, C.J.(2004)"Physicochemistry of Water and Dynamics_of Materials and the Earth-Structures and behaviors of the thin film water-"Universal Academy Press. Tokyo,〜200p.) Less

Report

(5 results)
  • 2003 Annual Research Report   Final Research Report Summary
  • 2002 Annual Research Report
  • 2001 Annual Research Report
  • 2000 Annual Research Report
  • Research Products

    (48 results)

All Other

All Publications (48 results)

  • [Publications] 廣野哲朗, 中嶋 悟: "画像処理・解析を用いた堆積岩中の間隙構造の可視化とその定量的評価"地質学雑誌. 106. 165-168 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 廣野哲朗, 林 為人, 中嶋 悟, 高橋 学: "原子間力顕微鏡を用いた地質媒体中の微小間隙の認定とその定量的評価"応用地質. 42. 23-29 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 廣野哲朗, 高橋 学, 中嶋 悟, 池原 研: "X線CT装置を用いた移流像その場観測透水試験法の開発"応用地質. 42. 294-299 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 中嶋 悟, 伊藤由紀, 塩田 大: "シリカ-水-有機物相互作用"岩石鉱物科学. 31. 58-62 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] MURAKAMI, M., HIROSE, K., YURIMOTO, H., NAKASHIMA, S., TAKAFUJI, N: "Water in Earth's lower mantle"Science. 295. 1885-1887 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] ITO, Y., NAKASHIMA, S.: "Water distribution in low-grade siliceous metamorphic rocks by micro-FTIR and its relation to grain size : A case from the Kanto Mountain region, Japan"Chemical Geology. 189. 1-18 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 廣野哲朗, 横山 正, 高橋 学, 中嶋 悟, 山本由弦, 林 為人: "マイクロフォーカスX線CT装置を用いた堆積物・岩石の内部構造の非破壊観察"地質学雑誌. 108(9). 606-609 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 中嶋 悟: "水の物性と地球ダイナミクス-地球内部のかたい水と地震の発生?-"日本初理学会誌. 57. 746-753 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] KATAYAMA, I., NAKASHIMA, S: "Hydroxyl in clinopyroxene from the deep subducted crust : Evidence for H_2O transport into the mantle."American Mineralogist. 88. 229-234 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] MASUDA, K., HARAMAKI, T., NAKASHIMA, S., HABERT, B, MARTINEZ, I., KASHIWARA, S.: "Structural change of water with solutes and temperature up to 100 C in aqueous solutions as revealed by ATR-IR spectroscopy"Applied Spectroscopy. 57(3). 274-281 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Okumura, S., Nakamura, M., Nakashima, S.: "Determination of molar absorptivity of IR fundamental OH stretching vibration in rhyolitic glasses."American Mineralogist. 88. 1657-1662 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Katayama, I., Hirose, K., Yurimoto, H, Nakashima, S.: "Water solubility in majoritic garnet in subducting oceanic crust."Geophysical Research Letters. 30(22). 2155;SDE 5-1-2155;SDE 5-4 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Famin, V., Nakashima, S., Jolivet, L., Phillipot, P.: "Mobility of metamorphic fluids inferred from infrared microspectroscopy on natural fluid-inclusions : the example of Tinos Island, Greece."Contributions to Mineralogy and Petrology. 146. 736-749 (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Okumura, S., Nakashima, S.: "Water diffusivity in rhyolitic glasses as determined by in-situ IR spectroscopy."Physics and Chemistry of Minerals. 31. 183-189 (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Nakashima, S, Mercury, L., Fenter, P., Spiers, C.J.: "Physicochemistry of Water and Dynamics of Materials and the Earth - Structures and behaviors of the thin film water -"Universal Academy Press, Tokyo(2004年7月頃出版予定). 200 (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Hirono, T., Nakashima, S.: "Image visualization and quantitative analysis of void structure in sedimentary rock using image processing"Jour. Geol. Soc. Japan. 106(in Japanese). 165-168 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Hirono, T., Lin, W., Nakashima, S., Takahashi, M.: "Identification and quantitative analysis of micro-pore in geomaterials using atomic force microscope."Jour. Japan Soc. Eng. Geol.. 42. 23-29 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Murakami, M., Hirose, K., Yurimoto, H., Nakashima, S., Takafuji, N.: "Water in Earth's lower mantle."Science. 295. 1885-1887 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Ito, Y., Nakashima, S.: "Water distribution in low-grade siliceous metamorphic rocks by micro-FTIR and its relation to grain size: A case from the Kanto Mountain region, Japan"chemical Geology. 189. 1-18 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Hirono, T., Yokoyama, T., Takahashi, M., Nakashima, S., Yamamoto, Y, Lin, W.: "Nondestructiove observation of internal structure in sediments and rocks using microfocus. X-ray CT system."Jour Geol. Soc. Japan. 108. 606-609 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Katayama, I., Nakashima, S.: "Hydroxyl in clinopyroxene from the deep subducted crus t: Evidence for H_20 transport into the mantle."American Mineralogist. 88. 229-234 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Masuda, K.Haramaki, T., Nakashima, S., Habert, B, Martinez, I., Kashiwabara, S.: "Structural change of water with solutes and temperature up to 100 C in aqueous solutions as revealed by ATR-IR spectroscopy."Applied Spectroscopy. 57(3). 274-281 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Hirono, T., Takahashi, M., Nakashima, S.: "In-situ visualization of fluid 'flow image within deformed rock by X-ray CT."Engineering Geology. 2162. 1-10 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Hirono, T., Takahashi, M., Nakashima, S.: "Direct imaging of fluid flow in geomaterials by X-ray CT."Geological Society of London Special Publication SP215:"Applications of X-Ray Computed Tomography in the Geosciences". 215. 107-115 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Okumura, S., Nakamura, M., Nakashima, S.: "Determination of molar absorptivity of IR fundamental OH stretching vibration in rhyolitic glasses."American Mineralogist. 88. 1657-1662 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Katayama, I., Hirose, K.Yurimoto, H, Nakashima, S.: "Water solubility in majortic garnet in subducting oceanic crust."Geophysical Research Letters. 30(22). 2155;SDE5-1-2155;SDE5-4 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Famin, V., Nakashima, S., Jolivet, L., Phillipot, P.: "Mobility of metamorphic fluids inferred from infrared microspectroscopy on natural fluid-inclusions: the example pfTinos Island, Greece."contributions to Mineralogy and Petrology. 146. 736-749 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Okumura, S., Nakashima, S.: "Water diffusivity in rhyolitic glasses as determined by in-situ IR spectroscopy."Physics and chemistry of Minerals. 31. 183-189 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Nakashima, S, Mercury, L., Fenter, P., Spiers, C.J.: "Physicochemistry of Water and Dynamics of Materials and the Earth-Structures and behaviors of the thin film water"Universal Academy Press, Tokyo(in press). 200 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] KATAYAMA, I., NAKASHIMA, S.: "Hydroxyl in clinopyroxene from the deep subducted crust : Evidence for H_2O transport into the mantle"American Mineralogist. 88. 229-234 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] MASUDA, K., HARAMAKI, T., NAKASHIMA, S., HABERT, B., MARTINEZ, I., KASHIWARA, S.: "Structural change of water with solutes and temperature up to 100 C in aqueous solutions as revealed by ATR-IR spectroscopy"Applied Spectroscopy. 57(3). 274-281 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Okumura, S., Nakamura, M., Nakashima, S.: "Determination of molar absorptivity of IR fundamental OH stretching vibration in rhyolitic glasses"American Mineralogist. 88. 1657-1662 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Katayama, I., Hirose, K., Yurimoto, H., Nakashima.S.: "Water solubility in majoritic garnet in subducting oceanic crust"Geophysical Research Letters. 30(22). 2155;SDE 5-1-2155;SDE 5-4 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Famin, V., Nakashima, S., Jolivet, L., Phillipot, P.: "Mobility of metamorphic fluids inferred from infrared microspectroscopy on natural fluid-inclusions : the example of Tinos Island, Greece"Contributions to Mineralogy and Petrology. 146. 736-749 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Nakashima, S., Mercury, L., Fenter, P., Spiers, C.J.: "Physicochemistry of Water and Dynamics of Materials and the Earth - Structures and behaviors of the thin film water -"Universal Academy Press, Tokyo(2004年7月頃出版予定). 200 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] MURAKAMI, M., HIROSE, K., YURIMOTO, H., NAKASHIMA, S., TAKAFUJI, N: "Water in Earth's lower mantle"Science. 295. 1885-1887 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] ITO, Y., NAKASHIMA, S.: "Water distribution in low-grade siliceous metamorphic rocks by micro-FTIR and its relation to grain size: A case from the Kanto Mountain region, Japan"Chemical Geology. 189. 1-18 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 廣野哲朗, 横山 正, 高橋 学, 中嶋 悟, 山本由弦, 林 為人: "マイクロフォーカスX線CT装置を用いた堆積物・岩石の内部構造の非破壊観察"地質学雑誌. 108(9). 606-609 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] KATAYAMA, I., NAKASHIMA, S: "Hydroxyl in clinopyroxene from the deep subducted crust : Evidence for H_2O transport into the mantle"American Mineralogist. 88. 229-234 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] MASUDA, K., HARAMAKI, T., NAKASHIMA, S., HABERT, B, MARTINEZ, I., KASHIWARA, S.: "Structural change of water with solutes and temperature up to 100 C in aqueous solutions as revealed by ATR-IR spectroscopy"Applied Spectroscopy. 57(3). 274-281 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 中嶋 悟: "水の物性と地球ダイナミクス-地球内部のかたい水と地震の発生?-"日本物理学会誌. 57. 746-753 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 廣野哲朗, 林 為人, 中嶋 悟, 高橋 学: "原子間力顕微鏡を用いた地質媒体中の微小間隙の認定とその定量的評価"応用地質. 42. 23-29 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 廣野哲朗, 高橋 学, 中嶋 悟, 池原 研: "X線CT装置を用いた移流像その場観測透水試験法の開発"応用地質. 42. 294-299 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 中嶋 悟, 伊藤由紀, 塩田 大: "シリカ-水-有機物相互作用"岩石鉱物科学. 31. 58-62 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 中嶋悟,伊藤由紀,鈴木覚: "地殻における粒界薄膜水の分布と物性-地殻深部の水はかたい!?-"月刊地球. 22・7. 470-476 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] KATO,K.,AMONO,O.and NAKASHIMA,S.: "Infrared Microscopy Analysis of High Temperature Dehydration Behavior of Clay Minerals."12th Pacific Basin Nuclear Conference Technical Sessions Proceedings. Vol.2. 745-750 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 広野哲朗,中嶋悟: "画像処理・解析を用いた堆積岩中の間隙構造の可視化とその定量的評価"地質学雑誌. 106. 165-168 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 中村美千彦: "多結晶石英集合体での間隙の発達と粒子成長"月刊地球. 22・7. 482-486 (2000)

    • Related Report
      2000 Annual Research Report

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Published: 2000-04-01   Modified: 2016-04-21  

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