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Iron-silicate reactions under the condition of the core-mantle boundary

Research Project

Project/Area Number 12440120
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 固体地球物理学
Research InstitutionThe University of Tokyo

Principal Investigator

YAGI Takehiko  Institute for Solid State Physics, Professor, 物性研究所, 教授 (20126189)

Co-Investigator(Kenkyū-buntansha) MIYAJIMA Nobuyoshi  Institute for Solid State Physics, Research Associate, 物性研究所, 助手 (90345231)
ONO Shigeaki  Institute for Solid State Physics, Research Associate, 物性研究所, 助手 (20313116)
Project Period (FY) 2000 – 2002
Project Status Completed (Fiscal Year 2002)
Budget Amount *help
¥15,000,000 (Direct Cost: ¥15,000,000)
Fiscal Year 2002: ¥3,800,000 (Direct Cost: ¥3,800,000)
Fiscal Year 2001: ¥4,500,000 (Direct Cost: ¥4,500,000)
Fiscal Year 2000: ¥6,700,000 (Direct Cost: ¥6,700,000)
Keywordshigh pressure experiment / lower mantle / core / iron / transition-metal oxides / high pressure transition / コア-マントル境界 / ケイ酸塩 / 溶解鉄 / コアーマントル境界 / 溶融鉄
Research Abstract

Final target of the present project was to clarify the reaction of silicates and molten iron at the condition of the Earth's core-mantle boundary. For this purpose, various developments were made for the experimental techniques to make well controlled experiments under very high pressures and high temperatures. Using the facilities thus developed, experiments in four category were carried out. 1. Mineralogy in the lower mantle. 2. High pressure phase transformation of iron and transition metal oxides. 3. High pressure scale under very high pressures. 4. Reaction between iron and oxides under very high pressure.
Many results were obtained in category 1 and 2, while the results of 3. was obtained up to 35 GPa and further experiments are in progress. In 4, only preliminary results were obtained so far. However, experimental techniques for the preparation of the sample is well established and many results are expected to come out in near future.

Report

(4 results)
  • 2002 Annual Research Report   Final Research Report Summary
  • 2001 Annual Research Report
  • 2000 Annual Research Report
  • Research Products

    (69 results)

All Other

All Publications (69 results)

  • [Publications] T.Kondo: "Phase transitions of MnO to 137 GPa"J. Appl. Phys.. 87. 4153-4159 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] M.Hasegawa: "Stability and compression behaviour of icosahedral Zn-Mg-Y quasicrystal under high pressures up to 70 GPa"Philosophical Magazine A. 80. 1769-1778 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H.Hirai: "Methane Hydrate Behavior under High Pressure"J. Phys. Chem. B. 104. 1429-1433 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] M.Hasegawa: "Growth of nitride crystals in a supercritical nitrogen fluid under high pressures and high temperatures yield using diamond anvil cell and YAG laser heating"Journal of Crystal Growth. 217. 349-354 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] A.Kubo: "Compressibility of Mg_<0.9>Al_<0.2>Si_<0.9>O_3 perovskite"Proc. Japan. Acad.. 76B. 103-107 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] K.Oguri: "Post-Garnet Transition in a Natural Pyrope : a multi-anvil study based on in situ X-ray diffraction and transmission electron microscopy"Phys. Earth Planet Inter.. 122. 175-186 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 八木健彦: "高圧科学の展望と結晶学"日本結晶学会誌. 42. 272-276 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 清水宏晏: "Bassett教授退官記念シンポジウムとレーザー加熱DACワークショップ"高圧力の科学と技術. 10. 245-248 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 近藤忠: "ダイヤモンドアンビルセルとレーザー加熱法を用いた高温超高圧実験法"圧力技術. 38. 14-22 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T.Yagi: "Laser heated diamond anvil apparatus at the Photon Factory and SPring-8 : Problems and improvements"Rev. Sci. Instrum.. 72. 1293-1296 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] N.Miyajima: "Potential host phase of aluminum and potassium in the Earth's lower mantle"Am. Mineral.. 86. 740-746 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] K.Hirose: "In situ measurements of the phase transition boundary in Mg_3Al_2Si_3O_<12> : implications for the nature of the seismic discontinuities in the Earth's mantle"Earth Planet. Sci. Lett.. 184. 567-573 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T.Watanuki: "Construction of laser-heated diamond anvil cell system for in situ x-ray diffraction study at SPring-8"Rev. Sci. Instrum.. 72. 1289-1292 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H.Hirai: "High-pressure structures of methane hydrate observed up to 8 GPa at room temperature"J. Chem. Phys.. 115. 7066-7070 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H.Hirai: "Pressure-induced phase changes of argon hydrate and methane hydrate at room temperature"Proc. Jpn. Acad.. 78B. 39-44 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] M.Hasegawa: "Stability and compression behavior of approximants in Al-Pd-Os system under high pressures up to 70GPa"J. Alloys and Compounds. 342. 232-236 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] N.Takafuji: "Study on Al_2O_3 content and phase stability of aluminous-CaSiO_3 perovskite at high pressure and temperature"Phys. Chem. Minerals. 29. 532-537 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T.Yagi: "Behavior of Earth materials under deep mantle conditions"Proceedings of the International School of Physics "Enrico Fermi" Course CXLVII. 643-655 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T.Yagi: "Experimental overview of large-volume techniques"Proceedings of the International School of Physics "Enrico Fermi" Course CXLVII. 41-54 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H.Hirai: "Structural Changes of Argon Hydrate under High Pressure"J. Phys. Chem.. 106. 11089-11092 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 後藤弘匡: "焼結ダイヤモンドアンビルの表面粗さが圧力発生効率に及ぼす影響"高圧力の科学と技術. 12. 236-241 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 八木健彦: "下部マントル深部条件下における高温高圧X線回折実験"Photon Factory News. 20. 15-20 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T.Mukaide: "High pressure and high temperature phase transformations in LiNbO_3"J. Appl. Phys.. 93. 3852-3858 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T.Yagi: "Complicated Effects of Aluminum on the Compressibility of Silicate Perovskite"Phys. Earth. Planet. Interious. (in press). (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T.Kondo: "Phase transitions of (Mg, Fe)O at megabar pressure"Phys. Earth. Planet. Interious. (in press). (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] K.Fujino: "Mineralogy of the lower mantle by a laser-heated diamond anvil cell experiment and analytical electron microscopy"Phys. Earth. Planet. Interious. (in press). (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 八木健彦: "高圧X線実験に基づく圧力測定は本当に信頼できるのか?"高圧力の科学と技術. 13. 66-71 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T.Yagi: "Physics Meets Minerology"Cambridge University Press. 396 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 八木健彦(共著): "新しい高圧力の科学"毛利信男編,講談社サイエンティフィック. 322 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Kondo, T. Yagi, Y. Syono, Y. Noguchi, T. Atou, T. Kikegawa, and O. Shimomura: "Phase transitions of MnO to 137 GPa"J. Appl. Phys.. 87. 4153-4159 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] M. Hasegawa, A. P. Tsai and T. Yagi: "Stability and compression behavior of icosahedral Zn-Mg-Y quasicrystal under high pressures up to 70 Gpa"Philosophical Magazine A. 80. 1769-1778 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H. Hirai, T. Kondo, M. Hasegawa, T. Yagi, Y. Yamamoto, T. Komai, K. Nagashima, M. Sakashita, H. Fujihisa and K. Aoki: "Methane Hydrate Behavior under High Pressure"J. Phys. Chem. B. 104. 1429-1433 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] M. Hasegawa and T. Yagi: "Growth of nitride crystals in a supercritical nitrogen fluid under high pressures and high temperatures yield using diamond anvil cell and YAG laser heating"Journal of Crystal Growth. 217. 349-354 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] A. Kubo, T. Yagi, S. Ono and M. Akaogi: "Compressibility of Mg_<0.9>Al_<0.2>Si_<0.9>O_3 perovskite"Proc. Japan. Acad.. 76B. 103-107 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] K. Oguri, N. Funamori, T. Uchida, T. Yagi, N. Miyajima, K. Fujino: "Post-Garnet Transition in a Natural Pyrope : a multi-anvil study based on in situ X-ray diffraction and transmission electron microscopy"Phys. Earth Planet Inter.. 122. 175-186 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Yagi, T. Kondo, T. Watanuki, O. Shimomura and T. Kikegawa: "Laser heated diamond anvil apparatus at the Photon Factory and SPrihg-8 : Problems and improvements"Rev. Sci. Instrum.. 72. 1293-1296 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] N. Miyajima, T. Yagi, K. Hirose, T. Kondo, K. Fujino, and H. Miura: "Potential host phase of aluminum and potassium in the Earth's lower mantle"Am. Mineral.. 86. 740-746 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] K. Hirose, Y. Fei, S. Ono, T. Yagi, and K. Funakoshi: "In situ measurements of the phase transition boundary in Mg_3 Al_2Si_3O_<12> : implications for the nature of the seismic discontinuities in the Earth's mantle"Earth Planet Sci. Lett.. 184. 567-573 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Watanuki, O. shimomura, T. Yagi, T. Kondo, and M. Isshiki: "Construction of laser-heated diamond anvil cell system for in situ x-ray diffraction study at SPring-8"Rev. Sci. Instrum.. 72. 1289-1292 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H. Hirai, Y. Uchihara, H. Fujihisa, M. Sakashita, E. Katoh, K. Aoki, K. Nagashima, Y. Yamamoto and T. Yagi: "High-pressure structures of methane hydrate observed up to 8 GPa at room temperature"J. Chem. Phys.. 115. 7066-7070 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H. Hirai, Y. Uchihara, T. Kawamura, Y. Yamamoto and T. Yagi: "Pressure-induced phase changes of argon hydrate and methane hydrate at room temperature"Proc. Jpn. Acad. 78 Ser.B. 39-44 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] M. Hasegawa, R. Tamura, T. Asao, T. Yagi, S. Takeuchi, A. Inoue: "Stability and compression behavior of approximants in Al-Pd-Os system under high pressures up to 70GPa"J. Alloys and Compounds. 342. 232-236 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] N. Takafuji, T. Yagi, N. Miyajima, T. Sumita: "Study on Al_2O_3 content and phase stability of aluminous-CaSiO_3 perovskite at high pressure and temperature"Chem. Minerals. 29. 532-537 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H. Hirai, Y. Uchihara, Y. Nishimura, T. Kawamura, Y. Yamamoto, T. Yagi: "Structural Changes of Argon Hydrate under Rich Pressure"J. Phys. Chem.. 106. 11089-11092 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Mukaide, T. Yagi, N. Miyajima, T. Kondo, N. Sata and T. Kikegawa: "High pressure and high temperature phase transformations in LiNbO_3"J. Appl. Phys.. 93. 3852-3858 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Yagi, N. Nishiyama, K. Okabe, A. Kubo, T. Kikegawa: "Complicated Effects of Aluminum on the Compressibility of Silicate Perovskite"Phys. Earth. Planet. Interious. in press. (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Kondo, E. Ohtani, N. Hirao, T. Yagi, T. Kikegawa: "Phase transitions of (Mg, Fe)O at megabar pressure"Phys. Earth. Planet. Interious. in press. (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] K. Fujino, Y. Sasaki, T. Komori, H. Ogawa, N. Miyajima, N. Sata, T. Yagi: "Mineralogy of the lower mantle by a laser-heated diamond anvil cell experiment and analytical electron microscopy"Phys. Earth. Planet. Interious. in press. (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Yagi and M. Yamakata , eds. by Aoki, Syono and Hemley: "Effect of Hydrostaticity on the Phase Transformation of Cristobalite , Transformation of Cristobalite, "Physics Meets Mineralogy""Cambridge University Press. 242-255 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Yagi , eds. by R. J. Hemley, G. L. Chiarotti, M. Bernasconi and L. Ulivi: "Behavior of Earth materials under deep mantle conditions , Proceedings of the International School of Physics "Enrico Fermi" Course CXLVII"IOS Press. 643-655 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Yagi , eds. by R. J. Hemley, G. L. Chiarotti, M. Bernasconi and L. Ulivi: "Experimental overview of large-volume techniques , Proceedings of the International School of Physics "Enrico Fermi" Course CXLVII"IOS Press. 41-54 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T.Yagi: "Behavior of Earth materials under deep mantle conditions"Proceedings of the International School of Physics "Enrico Fermi" Course CXL VII, R.J.Hemley, G.L.Chiarotti, M.Bernasconi and L.Ulivieds., IOS Press. 643-651 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Yagi: "Experimental overview of large-volume techniques"Proceedings of the International School of Physics "Enrico Fermi" Course CXL VII, R.J.Hemley, G.L.Chiarotti, M.Bernasconi and L.Ulivieds, IOS Press. 41-54 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Mukaide: "High pressure and high temperature phase transformations in LiNbO_3"J.Appl.Phys.. (in press). (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Yagi: "Complicated Effects of Aluminum on the Compressibility of Silicate Perovskite"Phys.Earth.Planet. Interious. (in press). (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Kondo: "Phase transitions of (Mg, Fe)O at megabar pressure"Phys.Earth, Planet. Interius,. (in press). (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] N.Nishiyama: "Phase relation and mineral chemistry in pyrolite to 2200℃ under the lower mantle pressures and implications for dynamics of mantle plumes"J.Geophys.Res.. (in press). (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Yagi: "Laser heated diamond anvil apparatus at the Photon Factory and SPring-8 : Problems and improvements"Rev. Sci. Instrum.. 72. 1293-1296 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] N.Miyajima: "Potential host phase of aluminum and potassium in the Earth's lower mantle"Am. Mineral.. 86. 740-746 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] K.Hirose: "In situ measurements of the phase transition boundary in Mg_3Al_2Si_3O_12:implications for the nature of the seismic discontinuities in the Earth's mantle"Earth Planet. Sci. Lett.. 184. 567-573 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] T.Watanuki: "Construction of laser-heated diamond anvil cell system for in situ x-ray diffraction study at SPring-8"Rev. Sci. Instrum.. 72. 1289-1292 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] H.Hirai: "High-pressure structures of methane hydrate observed up to 8 GPa at room temperature"J. Chem. Phys.. 115. 7066-7070 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] T.Kondo: "Phase transitions of MnO to 137 GPa"J.Appl.Phys.. 87. 4153-4159 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Yagi: "Effect of Hydrostaticity on the Phase Transformation of Cristobalite"Physics Meets Minerology" Aoki, Syono and Hemley eds, Cambridge University Press. 242-255 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] M.Hasegawa: "Stability and compression behaviour of icosahedral Zn-Mg-Y quasicrystal under high pressures up to 70 GPa"Philogophical Magazine A. 80. 1769-1778 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] H.Hirai: "Methane Hydrate Behavior under High Pressure"J.Phys.Chem.B. 104. 1429-1433 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] A.Kubo: "Compressibility of Mg0.9Al_<0.2>Si_<0.9>O_3 perovskite"Proc.Japan.Acad.. 76. 103-107 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] K.Oguri: "Post-Garnet Transition in a Natural Pyrope : a multi-anvil study based on in situ X-ray diffraction and transmission electron microscopy"Phys.Earth Planer Inter.. 122. 175-186 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] N.Miyajima: "A new host phase of aluminium and potassium in the Earth's lower mantle "Am.Mineral. (in press).

    • Related Report
      2000 Annual Research Report

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Published: 2000-04-01   Modified: 2016-04-21  

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