| Project/Area Number |
12440161
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Physical chemistry
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| Research Institution | Fukui University |
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Principal Investigator |
SAITO Shuji Fukui University, Research Center for Development of Far-Infrared Region, Professor, 遠赤外領域開発研究センター, 教授 (30106158)
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| Project Period (FY) |
2000 – 2002
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| Project Status |
Completed (Fiscal Year 2002)
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| Budget Amount *help |
¥16,200,000 (Direct Cost: ¥16,200,000)
Fiscal Year 2002: ¥1,700,000 (Direct Cost: ¥1,700,000)
Fiscal Year 2001: ¥6,500,000 (Direct Cost: ¥6,500,000)
Fiscal Year 2000: ¥8,000,000 (Direct Cost: ¥8,000,000)
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| Keywords | Submillimeter-wave spectroscopy system / High sensitivity spectroscopy / Interstellar chemistry / Interstellar molecule / Interstellar free radical / Interstellar deuterides / Dark cloud core / Core evolution timescale / 分光器高感度化 / コアの進化年齢 / サブミリ波分光高感度化 / 星間分子イオン |
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| Research Abstract |
The main subject of the present proposal is high-sensitivity submillimeter-wave spectroscopy of interstellar deuterides, aiming to estimate the chemical evolutionary age of dark cloud cores from the degree of deuterium fractionation. The following results are obtained during three years proposed.
1. The present high-sensitivity submillimeter-wave spectrometer covering up to 600 GHz was improved to cover a new frequency region of 500-830 GHz, aided by the present Grant-in Aid and other sources. The new spectrometer was used to study a few interstellar deuterides given below.
2. The proposed method of estimating the chemical evolutionary age of dark cloud cores from the degree of deuterium fractionation is applied to two dark cloud cores, cyanopolyyne peak and ammonia peak, of Taurus Molecular Cloud 1, using the abundance ratios between DC0^+ and HCO^+ combined with the new standard model network of gas-phase chemical reactions. The difference in deuterium fractionation between the two cor
… More
es is explained by a time difference in the evolutionary age of more than 10^5 yr. This is the first example of the chemical evolutionary age of dark cloud cores estimated from the degree of deuterium fractionation.
3. The method proposed above is also applied to two cloud cores, the northeast NH_3 core and the southern NH_3 core, of L134N which is a typical dark cloud having no energy sources. An analysis including the degree of deuterium fractionation and C/0 depletion in cores shows that the southern core is in a more evolved stage than the northeast core. The C/0 depletion also indicates the degree of core evolution. The existence of highly fractionated NH_2D and NHD_2 recently detected at the southern core is consistent with the high C/0 depletion in the southern core.
4. Two interstellar deuterides, HDC1^+ and PHD were studied with a new high-sensitivity submillimeter-wave spectrometer. Spectral patterns of PHD were very complicated due to fine and hyperfine structures of phosphorus, hydrogen and deuterium nuclei. A detailed analysis of complicated spectral lines resulted in a precise determination of the hyperfine coupling constants of phosphorus, hydrogen, and deuterium. The principal axis and principal values of the magnetic dipole coupling tensors of hydrogen in PH_2 and deuterium in PD_2 were derived from the observed values of PHD, PH_2 and PD_2. The principal axis of the hydrogen magnetic coupling tensor in PH_2 makes an angle of 2.3^0 with the PH bond. This result is one of rare cases in which a relation between the hyperfine coupling tensor and the related chemical bond is clearly indicated. Less
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