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Functional Design of Plasma-Polymerized Organic Thin Films and Its Application to an Electronic Nose

Research Project

Project/Area Number 12450039
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Applied physics, general
Research InstitutionKanazawa Institute of Technology

Principal Investigator

NANTO Hidehito  Kanazawa Institute of Technology, Department of Engineering, Professor, 工学部, 教授 (30133466)

Co-Investigator(Kenkyū-buntansha) TAKEI Yoshinori  Kanazawa Institute of Technology, Engineering, Researcher, 工学部, 研究員 (30350755)
KUSANO Eiji  Kanazawa Institute of Technology, Engineering Professor, 工学部, 教授 (00278095)
KINBARA Akira  Kanazawa Institute of Technology, Engineering, Professor, 工学部, 教授 (90010719)
Project Period (FY) 2000 – 2002
Project Status Completed (Fiscal Year 2002)
Budget Amount *help
¥10,100,000 (Direct Cost: ¥10,100,000)
Fiscal Year 2002: ¥1,600,000 (Direct Cost: ¥1,600,000)
Fiscal Year 2001: ¥2,700,000 (Direct Cost: ¥2,700,000)
Fiscal Year 2000: ¥5,800,000 (Direct Cost: ¥5,800,000)
Keywordsquartz crystal microbalance / surface plasmon resonance / electronic nose / plasma-polymerized thin film / molecular recognition membrane / kansei measurement / 半導体においセンサ / プラズマ重合法 / 酢の種類判別 / 水晶振動子においセンサ / 有機薄膜 / エレクトロニックノーズ / プラズマ重合 / においセンサ / 悪臭検知
Research Abstract

In order to develop a novel artificial electronic nose (e-NOSE) system, first of all, we tried to do the functional design of chemical sensors such as quartz crystal microbalance (QCM) sensor, surface plasmon resonance (SPR) sensor and metal oxide semiconductor (MOS) sensor. Then, we also tried to prepare such chemical sensors based on the thin film fabrication technologies of organic and inorganic materials using plasma, which can use as sensing membrane of e-NOSE. Furthermore, we examined the application of fabricated chemical sensors. The following results are obtained :
(1) It was found that the QCM odor sensor response for various gases strongly depended on the functional group of molecular recognition membrane. This is very important to prepare the QCM odor sensor with excellent selectivity.
(2) We developed a unique fabrication technique using plasma chemical vapor deposition which can polymerize the organic thin film as molecular recognition membrane for QCM and SPR chemical sensors.
(3) We developed a novel SPR odor sensor with molecular recognition membrane, which can use as one of useful sensor for e-Nose system.
(4) It was found that the magnetron sputtering technique is very useful for MOS thin film gas sensors having high sensitivity for many gases and for integration of MOS gas sensor array.
(5) It was found that quality of Japanese sake and vinegar can be estimated using developed QCM, SPR and MOS chemical sensors.
In order to develop intelligent e-NOSE system which can characterize the chemical component of gas mixture and many kinds of smell we are now working on QCM, SPR and MOS sensor in conjunction with pattern recognition analysis.

Report

(4 results)
  • 2002 Annual Research Report   Final Research Report Summary
  • 2001 Annual Research Report
  • 2000 Annual Research Report
  • Research Products

    (40 results)

All Other

All Publications (40 results)

  • [Publications] 南戸秀仁, 関川祐司, 宮竹智樹, 草野英二, 金原 粲ほか: "匂いおよび味複合センサによる日本酒のアルコール度と甘辛口の識別"日本設備管理学会誌. 14. 23-27 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 南戸秀仁: "匂いセンサ"AROMA RESEARCH. Vol.3,No.2. 2-10 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H.Nanto, Y.Sekikawa, T.Miyatake, M.Komura, T.Takei: "Discrimination of Quality of Japanese Sake Using SPR Taste Sensor and QCM Odor Sensor"Technical Digest of the 9^<th> Inter. Symp. On Olfaction & Electronic Nose. 171-172 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H.Nanto, Y.Hamaguchi, S.Sanada et al.: "Odor Sensor Using Plasma-Polymerized-Film Coated QCM for Enviromental Monitorin"Proc. of SPIE-Advanced Environmental Sensing Technology-. 4576. 237-243 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H.Nanto, M.Komura, Y.Sekikawa, Y.Takei, E.Kusano, A.Kinbara: "Kansei-Biosensors System Using SPR aste Sensor and QCM Odor Sensor for Quality Mapping of Japanese Sake"Proceedings of the 6^<th> Inter. Conf. on Engineering Design and Automation. 705-710 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 南戸秀仁: "においセンサ"日本ロボット学会誌. Vol.21,No.1. 36-39 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H.Nanto, J.R.Stetter: "Handbook of Machine Olfaction (Electronic Nose Technology)"WILLEY-VCH (Ed. by T.C.Pearce, S.S.Schiffman, H.T.Nagle and J.W. Gardner. 592 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H. Nanto, Odor Sensor: "Introduction to Chemosensors"Journal of the Robotics of Japan. 21, No.1. 36-39 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H. Nanto: "Odor Sensor"AROMA RESEARCH. 3, No.2. 102-110 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H. Nanto, Y. Hamaguchi, M. Komura, Y. Takayama, T. Kobayashi, Y. Sekikawa, T. Miyatake, E. Kusano and A. Kinbara: "A Novel Chemosensor System Using Surface Plasmon Resonance taste Sensor and Metal Oxide Odor Sensor for Quality Control of Vinegar"Sensors and Materials. 14, No.1. 1-10 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H. Nanto, M. Komura, Y. Sekikawa, T. Miyatake, Y. Kitade, Y. Takei, E. Kusano and A. Kinbara: "Discrimination of Types of Japanese Sake Using SPR Taste Sensor and QCM Odor Sensor"Jpn. J. Taste Smell Research. 9, No.3. 515-518 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H. Nanto, Y. Sekikawa, T. Miyatake, M. Komura and T. Oyabu: "Discrimination of Types of Japanese Sake Using SPR Taste Sensor and QCM Odor Sensor"Journal of SOPE Japan. 14, No.2. 23-27 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H. Nanto, Y. Hamaguchi, S. Sanada and M. Komura: "Odor and Taste Sensors Using Thin Films (Invited Paper)"Tech. Digest of the 18th Sensor Symposium. 197-204 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H. Nanto, Y. Hamaguchi, S. Sanada, K. Nobuyama, T. Matsumoto, K. Tanabe and S. Kurosawa: "Odor sensor using plasma-polymerized-film coated QCM for environmental monitoring"Proceedings of SPIE-Advanced Environmental Sensing, Technology-. 4576. 237-243 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] S. Sanada, Y. Hamaguchi, K. Nobuyama, E. Kusano, A. Kinbara, H. Nanto, T. Matsumoto, S. Kurosawa and T. Tanabe: "QCM gas sensor with plasma-polymerized molecular recognition film prepared using plasma CVD method"Jpn. J. Taste Smell Research. 8, No.3. 427-430 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H. Nanto, Y. Hamaguchi, Y. Yokoi, S. Kurosawa, T. Oyabu, E. Kusano and A. Kinbara: "A Smart Ammonia Gas Sensor Using QCM with Plasma-Polymerized Membrane"Sensors and Materials. 13, No.2. 69-76 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] A. Sawada, T. Oyabu and H. Nanto: "Identification of Meal-degree for aged living in solitude using odor sensors"Tras. IEE of Japan. 121-E, No.8. 434-439 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Oyabu, A. Sawada and H. Nanto: "Diffusion characteristics of Chemicals Causing Sick-Building Syndrome"Sensors and Materials. 13, No.2. 87-97 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H. Nanto and J. R. Stetter, Ed. By T. C. Pearce et al.: "Introduction to Chemosensors, Handbook of Machine Olfaction-Electronic Nose Technology"Wiler-VCH. 79-104 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H. Nanto, Odor Sennsors, Ed. By K. Toko: "Kansei-biosensors"Asakura Shoten. 186-225 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H. Nanto: "Science of Smell, Science of Color and Smell, Parity Books"Maruzen. 89-102 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 南戸秀仁, 関川祐司, 宮竹智樹, 草野英二, 金原 粲ほか: "匂いおよび味複合センサによる日本酒のアルコール度と甘辛口の識別"日本設備管理学会誌. 14. 23-27 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 南戸秀仁: "匂いセンサ"AROMA RESEARCH. Vol.3,No.2. 2-10 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] H.Nanto, Y.Sekikawa, T.Miyatake, M.Komura, Y.Takei: "Discrimination of Quality of Japanese Sake Using SPR Taste Sensor and QCM Odor Sensor"Technical Digest of the 9^<th> Inter. Symp. on Olfaction and Electronic Nose. 171-172 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] H.Nanto, Y.Hamaguchi, S.Sanada et al.: "Odor Sensor Using Plasma-Polymerized-Film Coated QCM for environmental monitoring"Proc. of SPIE-Advanced Environmental Sensing Technology II. 4576. 237-243 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] H.Nanto, M.Komura, Y.Sekikawa, Y.Takei, E.Kusano, A.Kinbara: "Kansei Biosensor System Using SPR taste Sensor and QCM Odor Sensor for Quality Mapping of Japanese Sake"Proceedings of the 6^<th> Inter. Conf. on Engineering Design and Automation. 705-710 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] H.Nanto, J.R.Stetter: "Handbook of Machine Olfaction(Electronik Nose Technology)"WILLEY-VCH(Ed. by T.C.Pearce, S.S.Schiffman, H.T.Nagle and J.W.Gardner). 1-592 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] H.Nanto et al.: "A smart Gas Sensor Using QCM with Plasma-Polymerized Membrane"Sensors and Materials. 13. 69-76 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 南戸秀仁: "エレクトロニックノース(人工電子鼻)"化学センサ. 17. 99-112 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 真田尚治, 草野英二, 金原粲, 南戸秀仁 他: "プラズマCVD法で作製した分子認識膜を持つ水晶振動子式ガスセンサ"日本味と匂学会誌. 8. 427-430 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 大薮多可志, 沢田史子, 南戸秀仁: "ニオイセンサアレイによる人間の基本的室内活動の同定"臭気学会論文誌. 121-E. 20-25 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 沢田史子, 大薮多可志, 南戸秀仁: "ニオイセンサのマハラノビヌの距離による人間のふるまい判別"ライフサポート学会誌. 13. 2-7 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] H.Nanto, E.Kusano, A.Kinbara et al.: "A Novel Chemosensor System Using SPR Taste Sensor and Metal Oxide Odor Sensor for Quality Control of Vinegar"Sensors and Materials. 14. 1-10 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] 南戸秀仁(分担執筆): "色とにおいの科学"丸善. 152 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] H.Nanto,E.Kusano,A.Kinbara et al.: "A smart gas sensor using polymer-bilm-coated quartz resonator microbalance"Sensors & Actuators. B66. 16-18 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] H.Nanto,Y.Yokoi,E.Kusano,A.Kinbara et al.: "Novel gas sensor using polymer-bilm-coated quartz resonator for environmental monitoring"Materials Sci.& Engineering. C12. 43-48 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 松本高利,田辺和俊,南戸秀仁 ほか: "水晶振動子式ガスセンサ測定とケモメトリクス解析による揮発ガス分析"化学とソフトウェア. 22巻,3号. 85-90 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 南戸秀仁,浜口佑樹,草野英二,金原粲 ほか: "表面プラズモン共鳴化学センサの酢に対する応答特性"日本味と勾学会誌. 7巻3号. 655-657 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.,Oyabu,H.Nanto,T.Onodera: "Odor sensing characteristics of a lavatory in a general domicile"Sensors & Actuators. (印刷中). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] 都甲潔,南戸秀仁 ほか: "感性バイオセンサ"朝倉書店(印刷中). (2001)

    • Related Report
      2000 Annual Research Report

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Published: 2000-04-01   Modified: 2016-04-21  

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