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VAN DER WAALS EPITAXY OF THIN C_<60> FILMS ON SEVERAL SUBSTRATES AND THEIR MICROTRIBOLOGICAL PROPERTIES

Research Project

Project/Area Number 12450068
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 設計工学・機械要素・トライボロジー
Research InstitutionKobe University

Principal Investigator

OHMAE Nobuo  FACULTY OF ENGINEERING PROFESSOR, 工学部, 教授 (60029345)

Co-Investigator(Kenkyū-buntansha) TAGAWA Masahito  FACULTY OF ENGINEERING ASSOCIATE PROFESSOR, 工学部, 助教授 (10216806)
Project Period (FY) 2000 – 2002
Project Status Completed (Fiscal Year 2002)
Budget Amount *help
¥7,600,000 (Direct Cost: ¥7,600,000)
Fiscal Year 2002: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 2001: ¥1,400,000 (Direct Cost: ¥1,400,000)
Fiscal Year 2000: ¥5,200,000 (Direct Cost: ¥5,200,000)
KeywordsC_<60> / van del Waals / Domain Growth / Microtribology / Micro machine / フラーレン / ファンデルワールスエピタキシー / 原子間力顕微鏡 / 二硫化モリブデン / シリコン / MBE
Research Abstract

In this study, surface morphology and growth phenomena of thin C_<60> films epitaxially grown on several substrates were studied for nanotribological applications. C_<60> evaporated from the Knudsen-cell passes through a vacuum of 10^<-8> Pa to condensate a film on substrates, heated at 100℃~250℃. The epitaxial growth of C_<60> thin film was monitored by the Reflection High Energy Electron Deflection (RHEED). Surface morphological images of the epitaxially grown C_<60> films on several substrates were obtained using an atomic force microscope (AFM). From this in-situ analysis with RHEED, it has been found that the C_<60> on MoS_2 substrate makes an epitaxial growth with the lattice spacing of 1.0nm at the substrate temperature of 150℃, which exactly is the spacing of bulk C_<60>. The size of the domain of C_<60> thin film became large at an increased substrate temperatures. Thin C_<60> films with van der Waals epitaxy showed characteristic triangular domain. This result coincides well with the mirror-symmetrical growth of C_<60> films analyzed by RHEED. For H-terminated Si(001) substrate, an epitaxial growth was not found. Cone-like islands with a diameter and a height of several tens nm were formed on H-terminated Si(001) substrate.

Report

(4 results)
  • 2002 Annual Research Report   Final Research Report Summary
  • 2001 Annual Research Report
  • 2000 Annual Research Report
  • Research Products

    (38 results)

All Other

All Publications (38 results)

  • [Publications] Ohmae, N.: "Microtribological properties of fullerene C_<60>, carbon onion and other advanced carbon materials"IWM2002 2^<nd> International Workshop on Microtribology, April 16-19, 2002. (in CD-ROM). (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Ohmae, N.: "MBE of Fullerene C_<60> and its Tribological Application"International Conference on Metallurgical Coatings and Thin Films, California, April 10-14. 110 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Tagawa M.: "Micro-and Macrotribological properties of solid lubricants in a simulated low earth orbit space environment"Proceedings of the 6th International Space Conference, Protection of Materials and Structures from the Space Environment, May 1-3, 2002, Toronto, Canada. (in press). (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Ohmae N.: "Tribology in Space Station"Proceedings of Balkantrib 2002, June 12-14. 329-336 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Tagawa M.: "Effect of atomic oxygen exposures on the tribological properties of molybdenum disulfide lubricants"Space Technology Proceedings Volume 4, J.I.Kleiman and R.C.Tennyson Eds.. 73-84 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Ohmae N.: "Microstructure and tribology of ultrathin C_<60> films prepared by molecular beam epitaxy"Proceedings of international Tribology Conference, Nagasaki, Japan, October29-November2. 715-719 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Ohmae N.: "Tribology of mechanical systems : a guide to present and future technologies"ASME Press (in press). (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 大前伸夫: "新版機械工学便覧"(社)日本機械学会(印刷中). (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Tagawa, M.: "Micro- and Macrotribological properties of solid lubricants in a simulated low earth orbit space environment in: Proceedings of the 6th International Space Conference, Protection of Materials and Structures from the Space Environment, Toronto, Canada, May 1-3, 2002"in press (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Ohmae, N.: "Tribology in Space Station in: Proceedings of Balkantrib, June 12-14"329-336 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Tagawa, M., J. I. Kleinman, and R. C. Tennyson Eds.: "Effect of atomic oxygen exposures on the tribological properties of molybdenum disulfide lubricants in: Space Technology Proceedings Volume 4"73-84 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Ohmae, N.: "Microstructure and tribology of ultrathin C_<60> films prepared by molecular beam epitaxy in: Proceedings of International Tribology Conference, Nagasaki, Japan, October29-November"715-719 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Ohmae, N.: "Tribology of mechanical systems: a guide to present and future technologies"ASME Press. in press (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Ohmae, N.: "Microtribological properties of fullerene C_<60>, carbon onion and other advanced carbon materials in: IWM2002 2^<nd> International Workshop on Microbiology, April 16-19, 2002,"in CD-ROM (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Ohmae, N.: "New edition of mechanical engineering manual, in Japanese"The Japanese society of mechanical engineering. in press (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Ohmae, N.: "MBE of Fullerene C_<60> and its Tribological Application in: International Conference on Metallurgical Coatings and Thin Films, California, April 10-14"110 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 田川雅人: "低摩擦発現のための表面創成の現状と将来展望-DLC固体潤滑材の現状と原子ビームによる表面自由エネルギー制御-"平成14年度ものづくりクラスター協議会産学官連携促進事業 分野設定型研究「表面処理技術分野」第2回セミナー講演資料、大阪、2月18日. 45-52 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] Tagawa M.: "Micro-and Macrotribological properties of solid lubricants in a simulated low earth orbit space environment"Proceedings of the 6th International Space Conference, Protection of Materials and Structures from the Space Environment, May 1-3, 2002, Toronto, Canada. (in press).

    • Related Report
      2002 Annual Research Report
  • [Publications] Ohmae N.: "Tribology in Space Station"Proceedings of Balkantrib 2002, June 12-14. 329-336 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Tagawa M.: "Effect of atomic oxygen exposures on the tribological properties of molybdenum disulfide lubricants"Space Technology Proceedings Volume 4, J. I. Kleiman and R. C. Tennyson Eds.. 73-84 (2001)

    • Related Report
      2002 Annual Research Report
  • [Publications] Ohmae N.: "Microstructure and tribology of ultrathin C_<60> films prepared by molecular beam epitaxy"Proceedings of International Tribology Conference, Nagasaki, Japan, October29-November2. 715-719 (2000)

    • Related Report
      2002 Annual Research Report
  • [Publications] Ohmae N.: "Tribology of mechanical systems : a guide to present and future technologies"ASME Press (in press). (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] 大前伸夫: "新版機械工学便覧"(社)日本機械学会(印刷中). (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] 大前伸夫: "(社)日本トライボロジー学会編"養賢堂. 883 (2001)

    • Related Report
      2002 Annual Research Report
  • [Publications] Ohmae, N. et al.: "Microtribological properties of fullerence C_<60>, carbon onion and other advanced carbon materials"Proc. 2^<nd> International Workshop on Microtribology. (in press). (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] 大前伸夫: "C_<60>薄膜の構造とトライボロジー特性"ニューダイヤモンド. 17・3. 26-27 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 大前伸夫: "トピックス、マイクロトライボロジーへの導入"トライボロジスト. 46・4. 311-312 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Ohmae, N., et al.: "Microstructure and tribology of ultrathin C_<60> films prepared by molecular beam epitaxy"Proc. International Tribology Conference. 715-719 (2000)

    • Related Report
      2001 Annual Research Report
  • [Publications] Ohmae, N., et al.: "MBE of fullerene C_<60> and its tribological applications"Int. Conf. On Metallurgical Coatings and Thin Films, Program and Abstracts. 110-110 (2000)

    • Related Report
      2001 Annual Research Report
  • [Publications] Nakagawa, H., et al.: "Microtribological properties of ultrathin C_<60> films grown by molecular beam epitaxy"Wear. 238. 45-47 (2000)

    • Related Report
      2001 Annual Research Report
  • [Publications] Ohmae, N.(共著): "Tribology of Mechanical Systems"ASME Press (in press). (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] 大前 伸夫(共著): "トライボラジーハンドブック"養賢堂. 908 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Ohame N., et al.: "Microstructure and tribology of ultrathin C60 films prepared by molecular beam epitaxy"Proceedings of International Tribology Conference. (in press). (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shiota T., et al.: "Field-stimulated exoemission of electrons induced by the distortion of atomic arrangement at tungsten surfaces"Proceedings of 13th International Symposium on Exoemission and Related Phenomena. (in press). (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Tagawa M., et al.: "Application of the first-principles calculation in the exoemission of electrons from aluminum tips"Proceedings of 13th International Symposium on Exoemission and Related Phenomena. (in press). (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shiota T., et al.: "Effect of low-energy ion bombardment upon field-stimulated exoelectron emission from tungsten surfaces"Japanese Journal of Applied Physics. Vol.39,No.2A. L110-L112. (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Ohmae N.: "MBE of fullerene C_<60> and its tribological applications"Int.Conf.On Metallur.Coatings and Thin Films, Program and Abstracts. 110-110 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Nakagawa H., et al.: "Microtribological properties of ultrathin C60 films grown by molecular beam epitaxy"Wear. Vol.238. 45-47 (2000)

    • Related Report
      2000 Annual Research Report

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Published: 2000-04-01   Modified: 2016-04-21  

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