| Project/Area Number |
12480029
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Cultural property science
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| Research Institution | Takaoka National College |
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Principal Investigator |
YOKOTA Masaru Takaoka National College, Department of Industrial Arts and Crafts, Professor, 産業造形学科, 教授 (10029225)
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| Co-Investigator(Kenkyū-buntansha) |
NOSE Masateru Takaoka National College, Department of Industrial Arts and Crafts, Professor, 産業造形学科, 教授 (70269570)
MIFUNE Haruhisa Takaoka National College, Department of Industrial Arts and Crafts, Professor, 産業造形学科, 教授 (20181969)
SUGAYA Fuminori The University of Shiga Prefecture, School of Human Cultures, Professor, 人間文化学部, 教授 (10275175)
SHIMIZU Yasuzi Archaeological Institute of Kashihara, Research Division, Chief Researcher, 主任研究員 (90250381)
MIYAHARA Shinichi Archaeological Institute of Kashihara, Research Division, Chief Researcher, 総括研究員 (90250373)
清水 克郎 (清水 克朗) 高岡短期大学, 産業造形学科, 講師 (70235646)
小堀 孝之 高岡短期大学, 産業造形学科, 教授 (30279856)
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| Project Period (FY) |
2000 – 2002
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| Project Status |
Completed (Fiscal Year 2002)
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| Budget Amount *help |
¥13,000,000 (Direct Cost: ¥13,000,000)
Fiscal Year 2002: ¥3,200,000 (Direct Cost: ¥3,200,000)
Fiscal Year 2001: ¥4,000,000 (Direct Cost: ¥4,000,000)
Fiscal Year 2000: ¥5,800,000 (Direct Cost: ¥5,800,000)
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| Keywords | Cultural Metal Assets / Science of Cultural Properties / Ancient Bronze Mirror / Materials Science / Heat Treatment / Mechanical Properties / Corrosion in Clay / Microbially Influenced Corrosion (MIC) / 金属製文化財 / 青銅器 / 材料工学 / 金相学 / 腐食生成物 / 古代青銅器 / 純Cu析出 / Cu_2O析出 / ガラス質SiO_2 / Sn有機化合物 / 化学成分 / ブロンズ病 / 結晶構造 / 自然銅 |
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| Research Abstract |
We carried out researches into the heat treatment technique to ancient bronze mirrors for the aim at improvement of toughness, farther, corrosion of ancient bronze mirrors in clay. We obtained the following principal results.
1. Toughness of the home made high tin bronze alloy was improved remarkably when, for example, water quenching from 720℃ of solution treatment and 20 minutes holding was performed.
2. The rates of density reduction obtained from the measured and the calculated densities corresponded to the degree of corrosion of the mirrors.
3. The shapes of appearances of pure copper lumps in the mirrors show various modes, i.e., depositions like layers, large or fine particles, or depositions like string or flash of lightning just burring the cracks in the mirrors.
4. The oxide copper (Cu_2O) layers and particles were observed in the mirrors showing just the same shapes as those of pure copper depositions.
5. Amorphous SiO_2 had formed in the outermost corroded layer.
6. Cu_2O (cuprite) and Cu (OH)_2 had formed in the middle layer of corrosion, which comprise the first two internal layers adjacent to the layer.
7. Cu-Sn-Pb-complex oxide had formed in the middle layer corrosion, the next internal layer. Small amounts of PbSO_4 and an Sn-organic compound were also detected. We observed that Cu_2S (chalcocite) forms like mold on the polished surface of the corroded layers, especially notable on layer IV, after being mechanically polished and left to stand for about one month. Cu_2S is presumed to be the resultant of sulfate reducing bacteria.
8. Numerous pure copper lumps appeared in layers or particles and tended to form in the vicinity of the middle corrosion layer.
9. The evidence from these analyses suggests that microorganisms could have been the cause of the corrosion found in ancient bronze mirrors excavated from clay.
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