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Development of low-damage low-temperature surface modification technique using laser detonation-induced broad atom beams

Research Project

Project/Area Number 12555200
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section展開研究
Research Field Material processing/treatments
Research InstitutionKobe University

Principal Investigator

OHMAE Nobuo  Kobe University, Faculty of Engineering, Professor, 工学部・機械工学科, 教授 (60029345)

Co-Investigator(Kenkyū-buntansha) YOKOTA Kumiko  Kobe University, Faculty of Engineering, Research Staff, 工学部, 教務職員(教育職) (20252794)
TAGAWA Masahito  Kobe University, Faculty of Engineering, Associate Professor, 工学部, 助教授 (10216806)
Project Period (FY) 2000 – 2002
Project Status Completed (Fiscal Year 2002)
Budget Amount *help
¥12,600,000 (Direct Cost: ¥12,600,000)
Fiscal Year 2002: ¥2,100,000 (Direct Cost: ¥2,100,000)
Fiscal Year 2001: ¥3,100,000 (Direct Cost: ¥3,100,000)
Fiscal Year 2000: ¥7,400,000 (Direct Cost: ¥7,400,000)
Keywordsatomic oxygen / space environment / hyperthermal atom beam / silicon / surface free energy / oxidation / surface modification / low earth orbit / シリコン酸化膜 / 原子ビーム
Research Abstract

This study aims at developing the new low-damage surface modification technique using laser detonation supersonic atoms beams. It was made clear that the hydrogen-terminated Si (001) surface can be oxidized by 5 eV atomic oxygen beam even at room temperature. This is due to the fact that more than 80 % of the translational energy was transferred from the impinging atom to the surface atom. The overall oxide growth follows linear-parabolic relationship that is similar to that observed high-temperature oxidation of Si. The initial linear growth was governed by the reaction-limit of oxidant, whereas parabolic one was due to volume diffusion inside the oxide film. It was also demonstrated that the surface free energy (or wettability) of polymer could be controlled by atom beam exposures. From the experimental results obtained in this study, potential advantages of the laser detonation supersonic beam-induced surface modification were identified.

Report

(4 results)
  • 2002 Annual Research Report   Final Research Report Summary
  • 2001 Annual Research Report
  • 2000 Annual Research Report
  • Research Products

    (32 results)

All Other

All Publications (32 results)

  • [Publications] Yokota K., Tagawa M., Ohmae N.: "Impingement angle dependence of erosion rate of polyimide in atomic oxygen exposures"Journal of Spacecraft and Rockets. 39・1. 155-156 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Tagawa M., Yokota K., Ohmae N., Kinoshita H.: "Effect of ambient air exposure on the atomic oxygen-exposed Kapton films"Journal of Spacecraft and Rockets. 39・3. 447-451 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Yokota K., Kida T., Ishikawa K., Tagawa M., Ohmae N.: "Atomic oxygen-induced erosion of PMDA-ODA polyimide films : effect of incident angle, temperature and simultaneous UV exposure"Proceedings of the 23^<rd> International Symposium on Space Technology and Science. 2002-r-06 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Tagawa M., Ohki Y., Matsuo T., Ohmae N., Gotoh K., Tagawa Y.: "Wettability of atomic oxygen-exposed polymeric materials in low Earth orbit : surface free energy and its effect on contamination control"Proceedings of the 23^<rd> International Symposium on Space Technology and Science. 2002-r-07 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Matsumoto K., Yokota K., Tagawa M., Ohmae N.: "Development of an atomic oxygen concentrator rising concave mirrors"Proceedings of the 23^<rd> International Symposium on Space Technology and Science. 2002-h-04 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Tagawa M., Dejima K., Tsumamoto S., Yokota K., Ohmae N., Kinoshita H.: "Utilization of low Earth orbit space environment in the formation of an insulating oxide layer on semiconductor surface"Proceedings of the 23^<rd> International Symposium on Space Technology and Science. 2002-h-05 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Yokota K., Tagawa M., Ohmae N.: "Impingement angle dependence of erosion rate of polyimide in atomic oxygen exposures"Journal of Spacecraft and Rockets. 39-1. 155-156 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Tagawa M., Yokota K., Ohmae N., Kinoshita H.: "Effect of ambient air exposure on the atomic oxygen-exposed Kapton films"Journal of Spacecraft and Rockets. 39-3. 447-451 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Yokota K., Kida T., Ishikawa K., Tagawa M., Ohmae N.: "Atomic oxygen-induced erosion of PMDA-ODA polyimide films: effect of incident angle, temperature and simultaneous UV exposure"Proceedings of the 23^<nd> International Symposium on Space Technology and Science. 2002-r-06. (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Tagawa M., Ohki Y., Matsuo T., Ohmae N., Gotoh K., Tagawa Y.: "Wettability of atomic oxygen-exposed polymeric materials in low Earth orbit: surface free energy and its effect on contamination control"Proceedings of the 23^<nd> International Symposium on Space Technology and Science. 2002-r-07. (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Matsumoto K., Yokota K., Tagawa M., Ohmae N.: "Development of an atomic oxygen concentrator using concave mirrors"Proceedings of the 23^<nd> International Symposium on Space Technology and Science. 2002-h-04. (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Tagawa M., Dejima K., Tsumamoto S., Yokota K., Ohmae N., Kinoshita H.: "Utilization of low Earth orbit space environment in the formation of an insulating oxide layer on semiconductor surface"Proceedings of the 23^<nd> International Symposium on Space Technology and Science. 2002-h-05. (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Yokota K., Tagawa M., Ohmae N.: "Impingement angle dependence of erosion rate of polyimide in atomic oxygen exposures"Journal of Spacecraft and Rockets. 39・1. 155-156 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Tagawa M., Yokota K., Ohmae N., Kinoshita H.: "Effect of ambient air exposure on the atomic oxygen-exposed Kapton films"Journal of Spacecraft and Rockets. 39・3. 447-451 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Yokota K., Kida T., Ishikawa K., Tagawa M., Ohmae N.: "Atomic oxygen-induced erosion of PMDA-ODA polyimide films : effect of incident angle, temperature and simultaneous UV exposure"Proceedings of the 23^<rd> international Symposium on Space Technology and Science. 2002-r-06 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Tagawa M., Ohki Y., Matsuo T., Ohmae N., Gotoh K., Tagawa Y.: "Wettability of atomic oxygen-exposed polymeric materials in low Earth orbit : surface free energy and its effect on contamination control"Proceedings of the 23^<rd> international Symposium on Space Technology and Science. 2002-r-07 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Matsumoto K., Yokota K., Tagawa M., Ohmae N.: "Development of an atomic oxygen concentrator using concave mirrors"Proceedings of the 23^<rd> international Symposium on Space Technology and Science. 2002-h-04 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Tagawa M., Dejima K., Tsumamoto S., Yokota K., Ohmae N., Kinoshita H.: "Utilization of low Earth orbit space environment in the formation of an insulating oxide layer on semiconductor surface"Proceedings of the 23^<rd> international Symposium on Space Technology and Science. 2002-h-05 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Yokota K., Tagawa M., Ohmae N.: "Impingement angle dependence of erosion rate of polyimide in atomic oxygen exposures"Journal of Spacecraft and Rockets. Vol.39,No.1. 155-156 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] Tagawa M., Yokota K., Ohmae N., Kinoshita H: "Effect of ambient air exposure on the atomic oxygen-exposed Kapton films"Journal of Spacecraft and Rockets. Vol.39,No.2(in press). (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] Kinoshita H., Tagawa M., Yokota K., Ohmae N: "Nonlinear phenomenon in the mass loss of polyimide films under hyperthermal atomic oxygen beam exposures"High Performance Polymers. Vol.13,No.4. 225-234 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Tagawa M., Yokota K., Ohmae N., Kinoshita H., Umeno M: "Oxidation properties of hydrogen-terminated Si(001) surfaces following use of a hyperthermal broad atomic oxygen beam at low temperatures"Japanese Journal of Applied Physics. Vol.40,No.10. 6152-6156 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Gotoh K., Tagawa M., Ohmae N., Kinoshita H., Tagawa M.: "Surface characterization of atomic oxygen-exposed polyimide films using contact angle measurements"Colloid and Polymer Science. Vol.279. 214-220 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 田川雅人, 横田久美子, 大前伸夫, 木之下博: "超熱原子状酸素ビームによる宇宙環境シミュレーションと固体表面改質への応用"日本真空協会関西支部平成12年度第2回研究例会資料. 21-28 (2000)

    • Related Report
      2001 Annual Research Report
  • [Publications] 田川雅人: "低軌道宇宙環境における材料劣化現象とその地上シミュレーション"真空. 44(in press). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] Kinoshita H., et al.: "The degradation of polyimide films due to the hyperthermal atomic oxygen exposures : in-situ mass loss measurement and effect of air exposures"Proceedings of the 8th International Symposium on Materials in a Space Environment. (in press). (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 田川雅人 ほか: "超熱原子線と固体表面の反応ダイナミクス"神戸大学ベンチャー・ビジネス・ラボラトリー年報. Vol.5. 105-108 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Tagawa M.: "Space material durability in the LEO space environment"Proceedings of Advanced Space Technology Symposium. NASDA-ETR-00004. 54-61 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Matsumoto K., et al.: "Effect of applied load on tribological properties of sputtered MoS2 films exposed to LEO environment"Proceedings of the 22nd International Symposium on Space Technology and Science,. 2000-c-32. (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Tagawa M., et al.: "Volume diffusion of atomic oxygen in a-SiO_2 protective coating"High Performance Polymers. Vol.12,No.1. 53-63 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 田川雅人 ほか: "宇宙環境利用のサイエンス"裳華房. 315 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Tagawa M. et al.: "Polymer Surface Modification : Relevance to Adhesion"VSP. 626 (2000)

    • Related Report
      2000 Annual Research Report

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Published: 2000-04-01   Modified: 2016-04-21  

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