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Development of Adsorption-photodegradation

Research Project

Project/Area Number 12555223
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section展開研究
Research Field 触媒・化学プロセス
Research InstitutionNagoya University

Principal Investigator

HATTORI Tadashi  Nagoya University Graduate School of Engineering Professor, 工学研究科, 教授 (50023172)

Co-Investigator(Kenkyū-buntansha) JOKO Isao  Kurita Water Industries Ltd. Corporate Research & Development Center Group Leader, 開発本部, 研究主幹
YOSHIDA Hisao  Nagoya University Graduate School of Engineering Assistant Professor, 工学研究科, 助手 (80273267)
SATSUMA Atsushi  Nagoya University Graduate School of Engineering Associate Professor, 工学研究科, 助教授 (00215758)
Project Period (FY) 2000 – 2001
Project Status Completed (Fiscal Year 2001)
Budget Amount *help
¥3,200,000 (Direct Cost: ¥3,200,000)
Fiscal Year 2001: ¥3,200,000 (Direct Cost: ¥3,200,000)
Keywordsendocrine disrupters / environmental hormons / phthalic acid esters / titania-pillared clay / photocatalyst / silica-supported titania / hydrothermal treatment / adsorption
Research Abstract

The chemicals called endocrine disrupters have been spread over the environment to influence the generative function of some species of living thing on the earth, and, therefore, the quick actions for this matter are required. The aim of this research is to find out the fundamental aspects on the adsorption-photodegradation system for diluted endocrine disrupters in water, and then to develop the system. In the first year, after establishing a simple estimation method for the activity of the system, we studied two systems for the degradation of dibutyl phthalate (DBF). One system was titania-pillared clay catalysts, and another was silica-supported titania catalysts. The results on the characterization of the catalysts and the activity for adsorption-photo-degradation clarified some aspects, e.g., (I) the adsorption amount influences on the photodegradation rate, (ii) the size and the crystallinity of the titania particle influence these activities, (iii) the hydrothermal treatment enhances the crystallinity of titania. (iv) our systems work under sunshine. In addition to them, in the second year, we investigated the influence of hydrophilicity/hydrophobicity of endocrine disrupters on the performance of the systems, and found that the enhanced crystallinity of titania by hydrothermal treatment were effective for each endocrine disruptors we examined.

Report

(3 results)
  • 2001 Annual Research Report   Final Research Report Summary
  • 2000 Annual Research Report
  • Research Products

    (9 results)

All Other

All Publications (9 results)

  • [Publications] T.Yoshida, T.Tanabe, Y.Miyashita, H.Yoshida, T.Hattori: "Degradation of dibutyl phthalate in water by the aid of metals under gamma-ray irradiation"Chemistry Letters. 876-877 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K.Shimizu, T.Kaneko, T.Fujishima, T.Kodama, H.Yoshida, Y.Kitayama: "Selective oxidation of liquid hydrocarbons over photoirradiated TiO_2 pillared clays"Applied Catalysis, A : General. 30. 151-162 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Yoshida, T.Tanabe, A Chen, Y.Miyashita, H.Yoshida, T.Hattori: "New Method for Degradation of Dibutyl Phthalate in Water by Gamma-ray Irradiation"Journal of Radioanalytical and Nuclear Chemistry, accepted. (印刷中). (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Yoshida, T. Tanabe, Y. Miyashita, H. Yoshida, T. Hattori: "Degradation of dibutyl phthalate in water by the aid of metals under gamma-ray irradiation"Chemistry Letters. 876-877 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K. Shimizu, T. Kaneko, T. Fujishima, T. Kodama, H. Yoshida, Y. Kitayama: "Selective oxidation of liquid hydrocarbons over photoirradiated TiO_2 pillared clays"Applied Cata|ysis, A : General. 30. 151-162 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Yoshida, T. Tanabe, A Chen, Y. Miyashita, H. Yoshida, T. Hattori: "New Method for Degradation of Dibutyl Phthalate in Water by Gamma-ray Irradiation"Journal of Radioanalytical and Nuclear Chemistry. in press. (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Yoshida, T. Tanabe, Y. Miyashita, H. Yoshida, T. Hattori: "Degradation of dibutyl phthalate in water by the aid of metals under gamma-ray irradiation"Chemistry Letters. 876-877 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] K. Shimizu, T. Kaneko, T. Fujishima, T. Kodama, H. Yoshida, Y. Kitayama: "Selective oxidation of liquid hydrocarbons over photoirradiated TiO_2 pillared clays"Applied Catalysis, A:General. 30. 151-162 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] T. Yoshida, T. Tanabe, A Chen, Y. Miyashita, H. Yoshida, T. Hattori: "New Method for Degradation of Dibutyl Phthalate in Water by Gamma-ray Irradiation"Journal of Radioanalytical and Nuclear Chemistry. (accepted). (2002)

    • Related Report
      2001 Annual Research Report

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Published: 2001-04-01   Modified: 2016-04-21  

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