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Study on Development of Second Harmonic Generation Microscopy (SHGM)

Research Project

Project/Area Number 12555240
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section展開研究
Research Field 工業物理化学
Research InstitutionUtsunomiya University

Principal Investigator

KATO Teiji  Utsunomiya University, Faculty of Engineering, Department of Applied Chemistry, Professor, 工学部, 教授 (60008068)

Co-Investigator(Kenkyū-buntansha) IIMURA Ken-ichi  Utsunomiya University, Faculty of Engineering, Department of Applied Chemistry, research associate, 工学部, 助手 (10272220)
SUZUKI Noboru  Utsunomiya University, Faculty of Engineering, Department of Applied Chemistry, associate Professor, 工学部, 助教授 (40134259)
YOSHIDA Masaaki  Utsunomiya University, Faculty of Engineering, Department of Applied Chemistry, associate Professor, 工学部, 助教授 (90114173)
Project Period (FY) 2000 – 2001
Project Status Completed (Fiscal Year 2001)
Budget Amount *help
¥12,400,000 (Direct Cost: ¥12,400,000)
Fiscal Year 2001: ¥2,700,000 (Direct Cost: ¥2,700,000)
Fiscal Year 2000: ¥9,700,000 (Direct Cost: ¥9,700,000)
KeywordsSecond Harmonic Generation Microscopy (SHGM) / Langmuir Monolayers / Structure Observation / Gibbs Monolayers / Brewster Angle Microscopy / Pulse YAG Laser / 二次非線形光学 / YAGレーザー
Research Abstract

The first object of this project was to develop a Second Harmonic Generation Microscopy (SHGM) using a strong pulse YAG laser. This is to apply for study of monolayers at the water surface, solution surfaces or at the transparent solid surfaces. The YAG laser and an optical zooming microscope were set on the arms of a goniometer. The incident angle of the p-polarized laser light can be adjusted to the Brewster angle of the transparent medium to avoid exposure the CCD camera of higher sensitivity to the strong reflected light. We could observe SHG images from some samples on transparent supporting medium. Beside of the development of the SHGM, we proceeded studies on the structures of Langmuir and Gibbs monolayers using vibrational spectroscopy and Atomic Force Microscopy (AFM).

Report

(3 results)
  • 2001 Annual Research Report   Final Research Report Summary
  • 2000 Annual Research Report
  • Research Products

    (49 results)

All Other

All Publications (49 results)

  • [Publications] M.M.Hossain, T.Suzuki, T.Kato: "Phase behavior of n-Hexadecyl Phosphate in Gibbs Adsorption Layers"Colloids and Surfaces, A. 198-200. 53-57 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y.Ren, K.Iimura, T.Kato: "Surface Micelles of F(CF_2)_m(CH_2)_<22> COOH on the Aqueous Cadmium Acetate Solution Investigated by in Situ and Ex Situ JR Spectroscopy"J. Phys. Chem., B,. 106. 1327-1333 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K.Iimura, Y.Yamauchi, T.Kato: "Two-Dimensional Dendritic Growth of Condensed Phase Domains in Spread Monolayers of cis-Unsaturated Fatty Acids"Langmuir. 17. 4602-4609 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y.Ren, M.M.Hossain, K.Iimura, T.Kato: "CH_3(CH_2)_nCOOH/Cd^<2+> System on the Aqueous Cadmium Acetate Solution Investigated in Situ by Polarization Modulation IR Soectroscopy"J. Phys. Chem., B. 105. 7723-7729 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y.Ren, K.Iimura, T.Kato: "Crystal Lattice Transition of Behenic Acid Monolayer on Pure Water Surface Observed by Polarization Modulation IR Spectroscopy"J. Chem. Phys.. 114. 6502-6504 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y.Ren, K.Iimura, T.Kato: "Crystal Lattice of Cadmium Alkanoate Monolayer at the Air/Water Surface Investigated by Polarization Modulation IR Spectroscopy"J. Chem. Phys.. 114. 1949-1951 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Urai, C. Ohe, K. Itoh, M. Yoshida, K. Iimura, T. Kato: "Phase Transition of Octadecylurea at the Air-Water Interface Studied by Infrared External Reflection Absorption Spectroscopy"Langmuir. 16. 3920-3926 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Md M. Hossain, M. Yoshida, T. Kato: "Higher-order structure formation in adsorbed monolayers at aqueous solution surfaces studied by Brewster angle microscopy"Langmuir. 16. 3345-3348 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Ren, K. Iimura, T. Kato: "Polarized Infrared Study on the Structure of Two-dimensional Nanoclusters of Partially Fluorinated Long-Chain Fatty Acid Salts at Ambient and Elevated Temperatures"J. Chem. Phys.. 113. 1162-1169 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Md. M. Hossain, T. Kato: "Line Tension Induced Instability of Condensed Domains Formed in Gibbs Monolayers"Langmuir. 16. 10175-83 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Md. M. Hossain, T. Suzuki, T. Kato: "Unusual Transition in a Two-Dimensional Condensed Phase to a Mosaic Texture"Langmuir. 16. 9109-12 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Ren, Md. M. Hossain, K. Iimura, T. Kato: "Orthorhombic Structure of Cadmium Behenate Monolayers on the Water Surface of a Langmuir Trough Detected by Polarization Modulation Infrared Spectroscopy"Chem. Phys. Lett.. 325. 503-507 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Ren, K. Iimura, T. Kato: "Monodispersed Two-Dimensional Nanoclusters of CF_3(CF_2)_3(CH_2)_<22>COOH on the Aqueous Cd^<2+> Subphase Investigated by Polarization Modulation Infrared Spectroscopy"Chem. Phys. Lett.. 332. 339-343 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K. Iimura, N. Nakajima, T. Kato: "A Study on Structures and Formation Mechanisms of Self-assembled Monolayers of n-Alkyltrichlorosilanes using Infrared Spectroscopy and Atomic Force Microscopy"Thin Solid Films. 379. 230-239 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Ren, M. Asanuma, K. Iimura, T. Kato: "Substrate and Chain Length Dependencies of the Thermal Behavior of [CF_3(CF_2)_m(CH_2)_nCOO]_2Cd Single Monolayers Investigated by Infrared Reflection Absorption Spectroscopy"J. Chem. Phys.. 114. 923-930 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Ren, K. Iimura, T. Kato: "Crystal Lattice of the Cadmium Alkanoate Monolayer at the Air/Water Interface Investigated by Polarization Modulation Infrared Spectroscopy"J. Chem. Phys.. 114. 1949-1951 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M. M. Hossain, J. Okano, T. Kato: "Phase Transition in Gibbs Monolayers of Mixed Surfactants"Studies in Surface Science and Catalysis. 132. 169-172 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Ren, K. Iimura, T. Kato: "Structure of Barium Stearate Films at Air/Water Interface investigated by Polarization Modulation IR Spectroscopy and π-A Isotherms"Langmuir. 17. 2688-2693 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Ren, K, Iimura, A. Ogawa, T. Kato: "Surface Micelles of CF_3(CF_2)_7(CH_2)_<10>COOH on Aqueous La^<3+> Subphase Investigated by Atomic Force Microscopy and Infrared Spectroscopy"J. Phys. Chem. B. 105. 4305-4312 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Ren, K. Iimura, T. Kato: "Crystal lattice transition of behenic acid monolayer on pure water surface observed by polarization modulation infrared spectroscopy"J. Chem. Phys. 114. 6502-6504 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Ren, M. M. Hossain, K. Iimura, T. Kato: "(CH_3(CH_2)_nCOO^-)_2Cd^<2+> System on the Aqueous Cadmium Acetate Solution Investigated in situ by Polarization Modulation Infrared"J. Physical Chem. B. 105. 7723-7729 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K. Iimura, Y. Yamauchi, Y. Tsuchiya, T. Kato, M. Suzuki: "Two-Dimensional Dendritic Growth of Condensed Phase Domains in Spread Monolayers of cis-Unsaturated Fatty Acids"Langmuir. 17. 4602-4609 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M. M. Hossain, T. Suzuki, T. Kato: "Phase Behavior of n-Hexadecyl Phosphate in Gibbs Adsorption Layers"Colloids and Surface A. 198-200. 53-57 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Ren, K. Iimura, T. Kato: "Surface Micelles of F(CF_2)_m(CH_2)_<22>COOH on Aqueous Cadmium Acetate Solution Investigated in Situ and ex Situ by Infrared Spectroscopy"J. Phys. Chem. B. 106. 1327-1333 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Ren, K. Iimura, T. Kato: "Structure of Cadmium Arachidate Monolayers at the Air/Water Interface at 283 and 293 K Investigated by Polarization Modulation Infrared Spectroscopy"J. Phys. Chem.. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M. M. Hossain, M. N. Islam, T. Okano, T. Kato: "Condensed Structure Formation in Mixed Monolayers of Anionic Surfactants and 2-Hydroxyethyl Laurate at the Air-Water Interface"Colloids and Surface A. (accepted).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M.M.Hossain, T.Suzuki, T.Kato: "Phase behavior of n・Hexadecyl Phosphate in Gibbs Adsorption Layers"Colloids and Surfaces, A. 198・200. 53-57 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] Y.Ren, K.Iimura, T.Kato: "Surface Micelles of F(CF_2)_m(CH_2)_<22>COOH on the Aqueous Cadmium Acetate Solution Investigated by in Situ and Ex Situ IR Spectroscopy"J. Phys. Chem., B,. 106. 1327-1333 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] K.Iimura, Y.Yamauchi, T.Kato: "Two-Dimensional Dendritic Growth of Condensed Phase Domains in Spread Monolayers of cis-Unsaturated Fatty Acids"Langmuir. 17. 4602-4609 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Y.Ren, M.M.Hossain, K.Iimura, T.Kato: "CH_3(CH_2)_nCOOH/Cd^<2+> System on the Aqueous Cadmium Acetate Solution Investigated in Situ by Polarization Modulation IR Spectroscopy"J. Phys. Chem., B,. 105. 7723-7729 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Y.Ren, K.Iimura, T.Kato: "Crystal Lattice Transition of Behenic Acid Monolayer on Pure Water Surface Observed by Polarization Modulation IR Spectroscopy"J. Chem. Phys.,. 114. 6502-6504 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Y.Ren, K.Iimura, T.Kato: "Crystal Lattice of Cadmium Alkanoate Monolayer at the Air/Water Surface Investigated by Polarization Modulation IR Spectroscopy"J. Chem. Phys.,. 114. 1949-1951 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Y.Ren,K.Iimura,A.Ogawa,T.Kato: "Sutface Micelles of a Partially Fluorinated Long-Chain Acid on Aqueous La^<3+> Investigated by AFM and FT-IR Spectroscopy"J.Phys.Chem., B. (accepted). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] Y.Ren,K.Iimura,T.Kato: "Crystal Lattice Transitions of Behenic Acid Monolayers on Pure Water Surface by Polarization Modulation IR Spectroscopy"J.Chem.Phys.,. (in press). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] Y.Ren,K.Iimura,T.Kato: "Structure of Barium Stearate Films st Air/Water Interface Investigated by Polarization Modulation IR Spectroscopy"Langmuir,. (in press). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] M.M.Hossain,T.Suzuki,T.Kato: "Phase Behavior of n-Hexadecyl Phosphate in Gibbs Adsorption Layers"Colloids and Surfaces A,. (in press). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] M.M.Hossain,T.Okano,T.Kato: "Crystal Lattice of Cadmium Alkanoate Monolayers at the Air/water Interface Investigated by Polarization Modulation IR Spectroscopy"J.Chem.Phys.,. Vol.114. 1945-1951 (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] M.M.Hossain,T.Kato: "Line Tension Induced Instability of Condensed Domains Formed in Adsorbed Monolayers at the Air/Water Interface"Langmuir,. Vol.16. 10175-10183 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Y.Ren,K.Iimura,T.Kato: "Substrate and Chain Length Dependencies of the Thermal Behavior of Partially Fluorinated Acid Salts Investigated by IRRAS"J.Chem.Phys.,. Vol.114. 923-930 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] K.Iimura,T.Kato: "Comparative Studies on Thermal, Solvent, pH, and Mechanical Resistance 1-Layer LB Films and SA Films of Alkylchlorosilanes"Colloids and Surfaces A,. Vol.171. 249-264 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Y.Ren,K.Iimura,T.Kato: "Polarization IR Study on the Structure of Two-Dimensional Nanoclusters of Partially Fluorinated Long-Chain Acid Salts"J.Chem.Phys.,. Vol.113. 1162-1169 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] K.Iimura,T.Kato: "A Study on Structures and Formation Mechanisms of SA Monolayers of n-Alkyltrichlorosilanes by IR Spectroscopy and AFM"Thin Solid Films,. Vol.379. 230-239 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 加藤貞二: "プローブ顕微鏡による単分子膜系のダイナミクス(総説)"表面科学(日本表面科学会誌). Vol.21. 608-614 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 加藤貞二: "単分子膜系における構造観察と緩和現象(総説)"日本油化学会誌,. Vol.49. 1089-1098 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Y.Ren,K.Iimura,T.Kato: "Monodispersed Two-Dimensional Nano-Clusters of a Partially Fluorinated Acid on the Aqueous Cd^<2+> Subphase by FT-IR"Chem.Phys.Lett.,. Vol.322. 339-346 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] M.M.Hossain,T.Suzuki,T.Kato: "Unusual Transition in a Two-Dimensional Condensed Phase to a Mosaic Texture"Langmuir,. Vol.16. 9109-9112 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Y.Ren,M.M.Hossain,K.Iimura,T.Kato: "Orthrhombic Structure of Cadmium Behenate Monolayers on the Water Surface detected by Polarization Modulation IR Spectroscopy"Chem.Phys.Lett.,. Vol.325. 503-507 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] M.M.Hossain,M.Yoshida,T.Kato: "Higher Order Structure Formation in Adsorbed Monolayers at Aqueous Solution Surfaces Studied by BAM"Langmuir,. Vol.16. 3345-3348 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] M.M.Hossain,M.Yoshida,K.Iimura,T.Kato: "Phase Transition in Adsorbed Monolayers of 2-Hydroxyethyl Laurate at the Air/Water Interface"Colloids and Surfaces A,. Vol.171. 105-113 (2000)

    • Related Report
      2000 Annual Research Report

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Published: 2000-04-01   Modified: 2016-04-21  

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