| Project/Area Number |
12555243
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 展開研究 |
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| Research Field |
工業物理化学
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| Research Institution | Yamanashi University |
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Principal Investigator |
WATANABE Masahiro Clean Energy Research Center, Professor, クリーンエネルギー研究センター, 教授 (00020412)
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| Co-Investigator(Kenkyū-buntansha) |
MUSHIAKE Naofumi Japan Gore-Tex Inc., FC Group Chief, FCグループチーフ
KATOH Hiroshi JapanGore-TexInc., GroupLeader, グループリーダー
UCHIDA Hiroyuki Faculty of Engineering, Professor, 工学部, 教授 (20127434)
虫明 直史 ジャパンゴアテックス(株), アプライドテクロノジー, フューエルセルグループチーフ
五十嵐 寛 山梨大学, 工学部, 助手 (40242044)
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| Project Period (FY) |
2000 – 2001
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| Project Status |
Completed (Fiscal Year 2001)
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| Budget Amount *help |
¥6,500,000 (Direct Cost: ¥6,500,000)
Fiscal Year 2001: ¥2,600,000 (Direct Cost: ¥2,600,000)
Fiscal Year 2000: ¥3,900,000 (Direct Cost: ¥3,900,000)
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| Keywords | Polymer Electrolyte Fuel Cells / Self-Humidification / Pt Catalysts / Polymer Electrolyte Membrane / Oxide particles / Titanium oxide |
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| Research Abstract |
Recently, we have proposed new self-humidifying polymer electrolyte membranes with highly dispersed nanometer-sized Pt and/or metal oxides for polymer electrolyte fuel cells (PEFCs) operated with dry H_2 and O_2. The Pt particles were expected to suppress the crossover by the catalytic recombination of H_2 and O_2, while the oxide particles (TiO_2) that have hygroscopic property were expected to adsorb the water produced at Pt particles together with that produced at the cathode reaction and to release the water once the PEM needs water. The PEFCs with these new PEMs demonstrated the superior performances and suppression of the crossover even under externally non-humidified condition, which are comparable to that of the conventional PEM fully humidified. In order to construct a practical PEFC stack, however, a mechanical strength of the PEM is an important property. Japan Gore-Tex developed a reinforced PEM with both a sufficient mechanical strength and high proton conductivity. It is desirable to prepare the self-humidifying PEM from a commercial reinforced PEM.
In this research, we examined to develop a practical preparation protocol of such new PEMs and obtained the following results..
1. The preparation protocol of TiO_2 nanoparticles in a commercial PEM via in-situ sol-gel reactions was developed, resulting in a transparent membrane with uniform distribution of TiO_2 among the membrane. A water adsorbability increased more than two times by dispersing only 2 wt % TiO_2 in the PEM.
2. In order to get a uniform dispersion of Pt nanoparticles in the PEM, platinum-complex -cations were impregnated in the TiO2-PEM by an ion-exchanging reaction, followed by a reduction to Pt nanocrystals (0.1 mg/cm^2) with an aqueous solution containing excess neutral hydrazine. The Pt-dispersion process was optimized.
3. The newly prepared Pt-TiO_2-PEM was confirmed to perform a self-humidifying operation in a PEFC with dry H_2 and O_2.
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