| Project/Area Number |
12558071
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 展開研究 |
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| Research Field |
環境保全
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| Research Institution | Nagoya University |
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Principal Investigator |
HIRAIDE Masataka Nagoya University, Graduate School of Engineering, Professor, 工学研究科, 教授 (20111833)
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| Co-Investigator(Kenkyū-buntansha) |
AKITA Shigendo Nagoya Municipal Industrial Research Institute, Reseacher, 資源環境部, 研究員
SAITOH Tohru Nagoya University, Graduate School of Engineering, Associate professor, 工学研究科, 教授 (40186945)
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| Project Period (FY) |
2000 – 2002
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| Project Status |
Completed (Fiscal Year 2002)
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| Budget Amount *help |
¥10,600,000 (Direct Cost: ¥10,600,000)
Fiscal Year 2002: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 2001: ¥2,900,000 (Direct Cost: ¥2,900,000)
Fiscal Year 2000: ¥7,000,000 (Direct Cost: ¥7,000,000)
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| Keywords | admicelle / sodium dodecylsulfate / alumina / hydrophobicity / pollutant / collection / zeta potential / flotation / クロロフェノール / 疎水性 |
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| Research Abstract |
A microscopic solvent property of surfactant aggregates dynamically sorbed on alumina surfaces (i.e., admicelles) was evaluated by the fluorometric method. From the relationship of emission wavelength and polarity of the selected solvent, sodium dodecylsulfate/alumina admicelles have the hydrophobicity larger than normal micelles. It corresponded to 1-octanol or ethylacetate. Many environmental pollutants including chlorophenols, alkylphenols, polyaromatic hydrocarbons, alkylated tin, formaldehyde, and pesticides were rapidly and effectively collected in the admicelles. The extent of the incorporation was correlated with the aqueous-octanol distribution coefficient, which represents the hydrophobicity of the compound. Highly hydrophobic, hence bio-accumulative compounds were efficiently incorporated and highly concentrated into the admicellar media. The incorporation was quite rapid and efficient because of higher wettability and permeability. Admicelles are also useful for the treatment of large volume samples. Alumina having positive zeta potential became negatively charged particles, when they sorbed anionic surfactant SDS molecules. In the moderate SDS sorption, the alumina particles were quantitatively floated on the solution surface by bubbling. This indicates the possibility of simple and rapid recovery of admicelles. Flotation was achieved within 15 s and the particles were retained on the water surface for several minutes. The proposed admicelle-air bubble flotation system has the high potential, in which different hydrophobic toxic compounds are successfully collected in admicelles and then rapidly separated from the bulk solutions by flotation.
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