• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Study on local electronic states of transition metal atoms occupied the centers of octahedral and tetrahedral structures by ATS scattering

Research Project

Project/Area Number 12640323
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 固体物性Ⅰ(光物性・半導体・誘電体)
Research InstitutionTokyo University of Science

Principal Investigator

ISHIDA Kohtaro  Tokyo University of Science, Faculty of Science and Technology Professor, 理工学部, 教授 (30012404)

Co-Investigator(Kenkyū-buntansha) KOKUBUN Jun  Tokyo University of Science, Faculty of Science and Technology Researcher, 理工学部, 助手 (90318204)
KATOH Hiroyuki  Tokyo University of Science, Faculty of Science and Technology Researcher, 理工学部, 助手 (80084482)
Project Period (FY) 2000 – 2002
Project Status Completed (Fiscal Year 2002)
Budget Amount *help
¥4,000,000 (Direct Cost: ¥4,000,000)
Fiscal Year 2002: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 2001: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 2000: ¥2,400,000 (Direct Cost: ¥2,400,000)
KeywordsATS Scattering / X-ray Magnetic Scattering / Dipole transition / Quadrupole transition] / Hematite / Eskolaite / X-ray Resonant Scattering / 赤鉄鉱 / 赤銅鉱 / 磁気散乱
Research Abstract

In 2002, we studied on Hematite (Fe_2O_3) and Eskolaite (Cr_O_3), which belong to the same crystal structure, corundum structure. We measured ATS scattering from these crystals near the K-absorption edge of Fe or Cr, using synchrotron beams in Photon Factory in Tukuba. The main results are the following
1) Just below the edges, (003) and (009) ATS intensities were observed in both crystals
2) The azimuthal dependence of the ATS peaks from Hematite showed three-hold symmetry
3) On the other hand, six-hold symmetry was observed in Eskolatie
4) From the azimuthal dependence, we conclude that the ATS scattering is caused by interference of quadrupole-quadrupole and dipole-quadrupole transitions in Hematite
5) In Eskolaite, the ATS scattering is due to quadrupole-quadrupole transition
6) In Hematite, two-hold azimuthal dependence of the ATS intensity was observed far from the edge
7) But, in Eskolaite, we did not observe such non-resonant ATS scattering
8) We conclude these non-resonant ATS scattering is due to the magnetic scattering and the difference in Hematite and Eskolaite caused by their magnetic structure

Report

(4 results)
  • 2002 Annual Research Report   Final Research Report Summary
  • 2001 Annual Research Report
  • 2000 Annual Research Report
  • Research Products

    (8 results)

All Other

All Publications (8 results)

  • [Publications] M.Kanazawa, K.Hagiwara, J.Kokubun, K.Ishida: "ATS Scattering from the Tetrahedral and Octahedral Site in Magnetite and Franklinite"J. Phys. Soc. Jpn.. 71. 1765-1770 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] V.E.Dmitrienko, K.Ishida, A.Kirfel, J.Kokubun, E.N.Ovchinnikova: "A Novel Method for Studying Thermal Motion and Point Defects in Crystals by X-Ray Resonant Diffraction"AIP Conf. Proceedings. 652. 317-322 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 國分 淳, 石田 興太郎: "ATS散乱の最近の展開"日本結晶学会誌. 44. 161-167 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] M.Kanazawa, K. Hagiwara, J. Kokubun and K. Ishida: "ATS Scattering from the Tetrahedral and Octahedral Site in Magnetite and Franklinite."J. Phys. Soc. Jpn. 71. 1765-1770 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] V. E. Dmitrienko, K. Ishida, A. Kirfel, J. Kokubun and E. N. Ovchinnikova: "A Novel Method for Studying Thermal Motion and Point Defects in Crystals by X-ray Resonant Diffraction."AIP Conf. Proceedings. 652. 317-322 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] J. Kokubun and K. Ishidsa: "Resent Developments in ATS Scattering (in Japanese)"J. Cryst. Soc. Jpn.. 44. 161-167 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] M.Kanegawa: "ATS Scattering from the Tetrahedral and Octahedral Site in Magnetite and Franklinite"J. Phys. Soc. Jpn. 71. 1765-1770 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] J.Kokubun: "Temperature-induced diotortions of electronic state observed via for bidden Bragg reflection in jermanium"Phys.Rev.B. 64-7. 732031-732034 (2001)

    • Related Report
      2001 Annual Research Report

URL: 

Published: 2000-04-01   Modified: 2020-05-15  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi