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Development of sensitive detection of crystalline defects in wide gap semiconductor by Raman scattering measurements

Research Project

Project/Area Number 12650017
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Applied materials science/Crystal engineering
Research InstitutionMIYAZAKI UNIVERSITY

Principal Investigator

MAEDA Kouji (2001)  Miyazaki University, Electrical and Electronic Engineering, Associ. Prof., 工学部, 助教授 (50219268)

中島 信一 (2000)  宮崎大学, 工学部, 教授 (20029226)

Co-Investigator(Kenkyū-buntansha) YOSHINO Kenji  Miyazaki University, Electrical and Electronic Engineering, Associ. Prof., 工学部, 助教授 (80284826)
IKARI Tetsuo  Miyazaki University, Electrical and Electronic Engineering, Prof., 工学部, 教授 (70113214)
NAKASHIMA Shin-ichi  R & D Association for Future Electron Devices, Senior fellow, 特定研究員 (20029226)
前田 幸治  宮崎大学, 工学部, 助教授 (50219268)
Project Period (FY) 2000 – 2001
Project Status Completed (Fiscal Year 2001)
Budget Amount *help
¥3,000,000 (Direct Cost: ¥3,000,000)
Fiscal Year 2001: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 2000: ¥1,900,000 (Direct Cost: ¥1,900,000)
KeywordsSiC / stacking faults / Raman probe measurements / polytype / carrier concentration / ceramics / LO phonon plasmon coupled model / ラマン分光 / ラマン散乱 / 積層欠陥評価 / ラマンイメージング / ラマン強度プロファイルの解析
Research Abstract

Raman spectra of 3C, 6H, 4H-SiC crystals including stacking faults have been examined using a backscattering geometry. It is found that the intensity of the transverse optical phonon band at 796 cm^<-1>, which corresponds to the phonon mode at the gamma point in 3C-SiC, is sensitive to the stacking faults. We found that the intensity of this band depends on the stacking fault density. These results are explained on the basis of the bond polarizability model. The spatial distribution of the stacking faults is studied by Raman image measurements. The carrier concentration is determined from the line shape analysis of the LO phonon plasmon coupled model. We evaluate the spatial distribution of the carrier concentration and the mobility for modulation-doped 6H-SiC crystals. Our experimental results demonstrate the Raman micro probe imaging is useful to analyze local electrical properties. We also evaluate the polytype phases of the SiC ceramics from Raman probe measurements. The volume contents measured by the Raman intensity of the folded modes of 4H and 15R polytype phases relative to that of the 6H phase in the ceramics are consistent with those determined from x-ray diffraction analysis. We can examine the relation between the spatial distributions of the polytype domains and crystalline grains with a resolution of micro-meter scale.

Report

(3 results)
  • 2001 Annual Research Report   Final Research Report Summary
  • 2000 Annual Research Report
  • Research Products

    (33 results)

All Other

All Publications (33 results)

  • [Publications] S.Nakashima, Y.Nakatake, H.Harima, M.Katsuno, N.Ohtani: "Detection of stacking faults in 6H-SiC by Raman scattering""Appl.Phys.Letters. 77(22). 3612-3614 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Tomita, S.Saito, M.Baba, M.Hundhausen, T.Suemoto, S.Nakashiina: ""Selective resonance effect of the folder longitudinal phonon modes in the Raman spectra of SiC""Phys.Rev.B. 62(19). 12896-12901 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S.Nakashima, H.Harima, T.Toinita, T.Suemoto: ""Raman intensity profiles of folded longitudinal phonon modes in SIC polytype"Phys.Rev.B. 62(24). 16605-16611 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S.NaKashima, H.Harima: "Raman Imaging of Semiconductor Materials: Characterization of Static and Dynamic properties""Inst.Phys.Conf.Ser.. No165: Symposium). 25 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Tomita, S.Saito, M.Baba, M.Hundhausen, T.Suemoto, S.Nakashima: "Selectively Resonant Rainan Spectra of Folded Phonon Modes in SiC""Materials Science Forum. 338-342. 587-590 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Shin-ichi Nakashima, Makoto Higashihira, Kouji Maeda: "Raman scattering characterization of polytype in SIC ceramics: Comparison with x-ray diffraction""J.American Ceramic Society. (投稿中).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 中島信一, 播磨弘, 勝野正和, 大谷昇: "ラマン散乱分光法によるSiCの積層欠陥の評価"FEDジャーナル. Vol.11, No.2. 57-60 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 中島信一(分担執筆): "SiCセラミック新材料1.7ラマン分光とSiC多形の評価"日本学術振興会高温セラミック材料委員会、内田老鶴圃. 11 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S.Nakashima, H.Harima: "Handbook of Vibrational Spectroscopy vol.4, "Raman Spectroscopy of Semiconductors""John Wiley & Sons Ltd.. 2637-2650 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S. Nakashima, Y. Nakatake, H. Harima, M. Katsuno, N. Ohtani: "Detection of stacking faults in 6H-SiC by Raman scattering"Appl. Phys. Letters. 77[22]. 3612-3614 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Tomita, S. Saito, M. Baba, M. Hundhausen, T. Suemoto and S. Nakashima: "Selective resonance effect of the folder longitudinal phonon modes in the Raman spectra of SiC"Phys. Rev. B. 62[19]. 12896-12901 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S. Nakashima, H. Harima, M. Katsuno and N. Otani: "Raman scattering characterization of stacking faults in SiC"J. FED.. 11[2]. 57-60 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S. Nakashima, H. Harima, T. Tomita and T. Suemoto: "Raman intensity profiles of folded longitudinal phonon modes in SiC polytype"Phys. Rev. B. 62[24]. 16605-16611 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S. Nakashima and H. Harima: "Raman Imaging of semiconductor Materials : Characterization of Static and Dynamic properties"Inst. Phys. Conf. Ser.. No.165 : Symposium 1. (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Tomita, S. Saito, M. Baba, M. Hundhausen, T. Suemoto and S. Nakashima: "Selectively Resonant Raman Spectra of Folded Phonon Modes in SiC"Materials Science Forum. 338-342. 587-590 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S. Nakashima, Y. Nakatake, Y. Ishida, T. Takahashi and H. Okumura: "Detection of defects in SiC crystalline films by Raman scattering"Physica B. 308-310. 684-686 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Shin-ichi Nakashima, Makoto Higashihira, Kouji Maeda: "Raman scattering characterization of polytype in SiC ceramics : Comparison with x-ray diffraction"J. American Ceramic Society. (submitted).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S. Nakashima: "1.7 Raman Spectroscopy and evaluation of polytype"Advanced Silicon Carbide Ceramics. 79-89, Uchida Rokakuho Publixhing CO., LTD.. (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S. Nakashima and H. Harima: "Raman Spectroscopy of Semiconductors"Handbook of Vibrational Spectroscopy vol.4, pp2637-2650, John Wiley & Sons Ltd.. (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S.Nakashima, Y.Nakatake, H.Harima, M.Katsuno, N.Ohtani: ""Detection of stacking faults in 6H-SiC by Raman scattering""Appl. Phys. Letters. 77(22). 3612-3614 (2000)

    • Related Report
      2001 Annual Research Report
  • [Publications] T.Tomita, S.Saito, M.Baba, M.Hundhausen, T.Suemoto, S.Nakashima: ""Selective resonance effect of the folder longitudinal phonon modes in the Rarnan spectra of SiC""Phys. Rev. B. 62(19). 12896-12901 (2000)

    • Related Report
      2001 Annual Research Report
  • [Publications] S.Nakashima, H.Harima, T.Tomita, T.Suemoto: ""Raman intensity profiles of folded longitudinal phonon modes in SiC polytype""Phys.Rev. B. 62(24). 16605-16611 (2000)

    • Related Report
      2001 Annual Research Report
  • [Publications] S.Nakashima, H.Harima: ""Raman Imaging of Semiconductor Materials : Characterization of Static and Dynamic properties""Inst. Phys. Conf. Ser.. No165:Symposium. 25 (2000)

    • Related Report
      2001 Annual Research Report
  • [Publications] T.Tomita, S.Saito, M.Baba, M.Hundhausen, T.Suemoto, S.Nakashima: ""Selectively Resonant Raman Spectra of Folded Phonon Modes in SiC""Materials Science Forum. 338-342. 587-590 (2000)

    • Related Report
      2001 Annual Research Report
  • [Publications] 中島 信一, 播磨 弘, 勝野 正和, 大谷 昇: "ラマン散乱分光法によるSiCの積層欠陥の評価"FEDジャーナル. vo1.11, No2. 57 (2000)

    • Related Report
      2001 Annual Research Report
  • [Publications] 中島 信一(分担執筆): "SiCセラミック新材料 1.7ラマン分光とSiC多形の評価"日本学術振興会高温セラミツク材料委員会. 11 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] S.Nakashima,Y.Nakatake,H,Harima,M.Katsuno,N.Ohtani: "Detection of stacking faults in 6H-SiC by Raman scattering"Appl.Phys.Letters. 77(22). 3612-3614 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Tomita,S.Saito,M.Baba,M.Hundhausen,T.Suemoto and S.Nakashima: "Selective resonance effect of the folder longitudinal phonon modes in the Raman spectra of SiC"Physical Review B. 62(19). 12896-12901 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] S.Nakashima,H.Harima,T.Tomita,and T.Suemoto: "Raman intensity profiles of folded longitudinal phonon modes in SiC polytype"Physical Review B. 62(24). 16605-16611 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] S.Nakashima and H.Harima: "Raman Imaging of Semiconductor Materials : Characterization of Static and Dynamic properties"Inst.Phys.Conf.. Series 165. 25-26 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Tomita,S.Saito,M.Baba,M.Hundhausen,T.Suemoto and S.Nakashima: "Selectively Resonant Raman Spectra of Folded Phonon Modes in SiC"Materials Science Forum. 338-342. 587-590 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 中島信一,播磨弘,勝野正和,大谷昇: "ラマン散乱分光法によるSiCの積層欠陥の評価"FEDジャーナル. 11(2). 57-60 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 中島信一(分担執筆): "SiCセラミック新材料 1.7ラマン分光とSiC多形の評価"日本学術振興会高温セラミック材料委員会第124委員会(内田老鶴圃). 10 (2000)

    • Related Report
      2000 Annual Research Report

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Published: 2000-04-01   Modified: 2016-04-21  

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