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Study on Interface Properties of Ti-Ni Shape Memory Films Sputtered on Si substrate

Research Project

Project/Area Number 12650703
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Structural/Functional materials
Research InstitutionKanazawa Institute of Technology

Principal Investigator

YAJIMA Zenjiro  Kanazawa Institute of Technology, Faculty of Engineering, Professor, 工学部, 教授 (60148145)

Co-Investigator(Kenkyū-buntansha) SHIMIZU Ken-ichi  Kanazawa Institute of Technology, Faculty of Engineering, Professor, 工学部, 教授 (60029832)
KISHI Yoichi  Kanazawa Institute of Technology, Faculty of Engineering, Associate Professor, 工学部, 助教授 (70265370)
Project Period (FY) 2000 – 2002
Project Status Completed (Fiscal Year 2002)
Budget Amount *help
¥2,900,000 (Direct Cost: ¥2,900,000)
Fiscal Year 2002: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 2001: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 2000: ¥1,600,000 (Direct Cost: ¥1,600,000)
KeywordsShape memory alloy / Martensitic transformation / Martensitic transformation induced stress / Transmission electron microscope / Micro-actuator / MEMS / マイクロアクチュエータ
Research Abstract

Ti-50at%Ni shape memory films with a thickness 1 μm were deposited on Si(100) substrate, using a D. C. magnetron sputtering system. Several depositions were made at different substrate temperatures, ranging from room temperature to 658 K. The films deposited over 523 K were completely crystalline. Cross-sectional TEM images revealed that the growth of the film is a 200nm diameter columnar. Selected area electron diffraction patterns show that B2 austenites transform to B19' martensites. Heusler-type NiMnGa ferromagnetic shape memory alloy (FMSMA) films were also deposited by DC magnetron sputtering, on silicone (100) cantilever-type substrates. NiMnGa FMSMA films show good ferromagnetic and shape memory properties if the substrate is heated above 623K or if films deposited at room temperature are annealed above 873K. The growth of the film is 200nm diameter columnar. Cross-sectional TEM images show typical martensitic variants while the selected area electron diffraction pattern suggests an orthorhombic structure. The thermo-mechanical spectroscopy data were measured with an acoustic elastometer permitting the simultaneous measurement of damping, modulus and the cantilever displacement as a function of temperature. It can be concluded that both of a full transition and large displacement develop in films deposited at 658K and in films deposited at room temperature and annealed at 873K.

Report

(4 results)
  • 2002 Annual Research Report   Final Research Report Summary
  • 2001 Annual Research Report
  • 2000 Annual Research Report
  • Research Products

    (49 results)

All Other

All Publications (49 results)

  • [Publications] Y.KISHI: "Microstructures and Transformation Behavior of Cobalt-Base Ferromagnetic Shape Memory Alloys"Proc. of International Conference of Martensitic Transformations '02 (ICOMAT'02). (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Y.KISHI: "Lorentz Study of Magnetic Domains in Heusler-Type Ferromagnetic Shape Memory Alloys"Proc. of International Conference of Martensitic Transformations '02 (ICOMAT'02). (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Y.KISHI: "Martensitic Transformation in Co_2NiGa Ferromagnetic Shape Memory Alloys"Scripta Materialia. 47. 285-288 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Y.KISHI: "Relation Between Tensile Deformation Behavior and Microstructure in a Ti-Ni-Co Shape Memory Alloy"Materials Transactions, JIM. 43. 834-839 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 清水謙一: "マルテンサイト変態:微視組織と一軸応力・磁場・静水圧効果"まてりあ(日本金属学会誌). 41・5. 327-333 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 清水謙一: "ICOMATの開催経緯とマルテンサイト変態研究の進展"まてりあ(日本金属学会誌). 42・2. 141-144 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] K.Shimizu: "Martensitic Transformations : Microstructures and Uniaxial Stress, Magnetic Field and Hydrostatic Effects"Materials Transactions, JIM. 43・8. 2050-2057 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] K.Shimizu: "Applications and Development of Shape-Memory and Superelastic Alloys in Japan"Materials Science Forum. 394-395. 61-68 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 岸陽一, 矢島善次郎, 清水謙一: "熱処理したTi-47at,%Al金属間化合物の高温曲げ変形挙動に及ぼすγ相等軸粒の影響"鋳造工学. 74・12. 846-851 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 矢島善次郎, 岸陽一, 清水謙一, 他: "オーステンパ球状黒鉛鋳鉄における塊状残留オーステナイトの応力誘起マルテンサイト変態に関する電子顕微鏡観察"鋳造工学. 73・11. 727-732 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 矢島善次郎, 岸陽一, 清水謙一, 他: "オーステンパ球状黒鉛鋳鉄材の疲労亀裂進展挙動に及ぼす塊状残留オーステナイトの影響"鋳造工学. 73・10. 649-655 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Y.Kishi, Z.Yajima, K.Shimizu: "Effect of Aging Period on Tensile Deformation and Microstructure of a Ti-Ni-Co Shape Memory Alloy"Proc. of 4th Pacific Rim International Conference on Advanced Materials and Processing (PRICM 4). 1843-1846 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Y.Kishi, Z.Yajima, K.Shimizu, K.Morii: "Aging Effect on Thansformation Characteristics and Tensile Properties of a Ti-Ni-Co alloy"Journal de Physique IV. 11. Pr8-101-Pr8-106 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Y.Kishi, Z.Yajima, K.Shimizu, M.ASai: "X-Ray Characterization of Tensile Deformed Microstructure in a Ti-Ni-Cu Shape Memory Alloy"Nondestructive Characterization of Materials X. 99-104 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H.Mochizuki, Z.Yajima, Y.Kishi, T.Yoshida, K.Shimizu: "Nondestructive evaluation of Residual Strain for a Cast Iron Using the Ultra Sonic Measurement"Nondestructive Characterization of Materials X. 411-416 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Y.Kishi, Z.Yajima, K.Shimizu, M.Asai: "Influence on Deformation Speed on Fatigue and Tensile Properties of a Ti-Ni-Cu Shape Memory Alloy"Materials Research Society Symposium Proceedings. 604. 123-128 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 岸陽一, 矢島善次郎, 清水謙一, 森井浩一: "Ti-47at.%Al金属間化合物鋳造材の高温曲げ破壊特性と変形組織"鋳造工学. 72. 247-252 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Y. KISHI: "Microstructures and Transformation Behavior of Cobalt-Base Ferromagnetic Shape Memory Alloys"Proc. Of International Conference of Martensitic Transformations '02 (ICOMAT '02). (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Y. KISHI: "Lorentz Study of Magnetic Domains in Heusler-Type Ferromagnetic Shape Memory Alloys"Proc. Of International Conference of Martensitic Transformations '02 (ICOMAT '02). (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Y. KISHI: "Martensitic Transformation in Co2NiGa Ferromagnetic Shape Memory Alloys"Scripta Materialia. 47. 285-288 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Y. KISHI: "Relation Between Tensile Deformation Behavior and Microstructure in a Ti-Ni-Co Shape Memory Alloy"Materials Transactions, JIM. 43. 834-839 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] K. Shimizu: "Martensitic Transformations : Microstructures and Uniaxial Stress, Magnetic Field and Hydrostatic Effects"Materia, Japan. 41. 327-333 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] K. Shimizu: "Martensitic Transformations : Microstructures and Uniaxial Stress, Magnetic Field and Hydrostatic Effects"Materials Transactions, JIM. 43. 2050-2057 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] K. Shimizu: "Applications and Development of Shape-Memory and Superelastic Alloys in Japan"Materials Science Forum. 394-395. 61-68 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Y. Kishi, Z. Yajima, K. Shimizu and K. Morii: "Effect of Eqiaxed γ-phase Grains on High-temperature Bending Deformation Behavior of Annealed Ti-47at.%A1 Intermetaric Compound"Journal of Japan Foundry Engineering Society. 73. 846-851 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Z. Yajima, Y. Kishi, K. Shimizu, et al: "Electron Microscopy Observations of Stress-Induced Martensitic Transformation for Retained Massive γ in Austempered Ductile Irons"Journal of Japan Foundry Engineering Society. 73. 727-732 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Z. Yajima, Y. Kishi, K. Shimizu, et al: "Influence of Retained Massive γ on Fatigue Crack Growth Behavior of Austempered Ductile Irons"Journal of Japan Foundry Engineering Society. 73. 649-655 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Y. Kishi, Z. Yajima and K. Shimizu: "Effect of Aging Period on Tensile Deformation and Microstructure of a Ti-Ni-Co Shape Memory Alloy"Proc. Of 4th Pacific Rim International Conference on Advanced Materials and Processing (PRICM 4). 1843-1846 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Y. Kishi, Z. Yajima, K. Shimizu and K. Morii: "Aging Effect on Transformation Characteristics and Tensile Properties of a Ti-Ni-Co alloy"Journal do Physique IV. 11. Pr8-101-Pr8-106 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Y. Kishi, Z. Yajima, K. Shimizu and M. Asai: "X-Ray Characterization of Tensile Deformed Microstructure in a Ti-Ni-Cu Shape Memory Alloy"Nondestructive Characterization of Materials X. 99-104 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H. Mochizuki, Z. Yajima, Y. Kishi, T. Yoshida and K. Shimizu: "Nondestructive evaluation of Residual Strain for a Cast Iron Using the Ultra Sonic Measurement"Nondestructive Characterization of Materials X. 411-416 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Y. Kishi, Z. Yajima, K. Shimizu and M. Asai: "Influence on Deformation Speed on Fatigue and Tensile Properties of a Ti-Ni-Cu Shape Memory Alloy"Materials Research Society Symposium Proceedings. 604. 123-128 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Y. Kishi, Z. Yajima, K. Shimizu and K. Morii: "High temperature Bending Fracture Properties and Deformation Structures of As Casted. Ti-47at.%A1 Intermetaric Compound"Journal of Japan Foundry Engineering Society. 72. 247-252 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Y.KISHI: "Microstructures and Transformation Behavior of Cobalt-Base Ferromagnetic Shape Memory Alloys"Journal de Physique IV. (in press).

    • Related Report
      2002 Annual Research Report
  • [Publications] Y.KISHI: "Lorentz Study of Magnetic Domains in Heusler-Type Ferromagnetic Shape Memory Alloys"Journal de Physique IV. (in press).

    • Related Report
      2002 Annual Research Report
  • [Publications] Y.KISHI: "Martensitic Transformation in Co_2NiGa Ferromagnetic Shape Memory Alloys"Scripta Materialia. 47. 285-288 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Y.KISHI: "Relation Between Tensile Deformation Behavior and Microstructure in a Ti-Ni-Co Shape Memory Alloy"Materials Transactions, JIM. 43. 834-839 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 矢島善次郎: "オーステンパ球状黒鉛鋳鉄材の疲労亀裂進展挙動に及ぼす塊状残留オーステナイトの影響"鋳造工学. 73・10. 649-655 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 矢島善次郎: "オーステンパ球状黒鉛鋳鉄における塊状残留オーステナイトの応力誘起マルテンサイト変態に関する電子顕微鏡観察"鋳造工学. 73・11. 727-732 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 岸 陽一: "熱処理したTi-47at.%Al金属間化合物の高温曲げ変形挙動に及ぼすγ相等軸粒の影響"鋳造工学. 73・12. 846-851 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Hideharu Mochizuki: "Nondestructive Evaluation of a Grey Cast Iron Using the Ultrasonic Measurement"Nondestructive characterization of Materials X. 411-416 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Yoichi Kishi: "X-Ray Characterization of the Strain State in a Tensile Deformed Ti-Ni-Cu Shape Memory Alloy"Nondestructive characterization of Materials X. 99-104 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Yoichi Kishi: "Effect of Aging Period on Tensile Deformation Behavior and Microstructure of a Ti-Ni-Co Shape Memory Alloy"Proc.of Fourth Pacific Rim International Conference on Advanced Materials and Processing. (印刷中). (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] 岸陽一: "Ti-47at.%A1金属間化合物鋳造材の高温曲げ破壊特性と変形組織"鋳造工学. 72・4. 247-252 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Yoichi Kishi: "Influence of Deformation Speed on Fatigue and Tensile Properties of a Ti-Ni-Cu Shape Memory Alloy"Proc.of 1999 MRS Fall Meeting. 123-128 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Yoichi Kishi: "X-Ray Characterization of Tensile Deformed Microstructure in a Ti-Ni-Cu Shape Memory Alloy"Proc.of 10th Iketani Coference. (印刷中). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] Hideharu Mochizuki: "Nondestructive Evaluation of Residual Strain for a Cast Iron Using the Ultra Sonic Measurement"Proc.of 10th Iketani Coference. (印刷中). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] Yoichi Kishi: "Aging Effect on Transformation Characteristics and Tensile Properties of a Ti-Ni-Co alloy"Proc.of 5th European Symposium on Martensitic Transformations and Shape Memory Alloys. (印刷中). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] Yoichi Kishi: "Effect of Aging Period on Tensile Deformation Behavior and Microstructure of a Ti-Ni-Co Shape Memory Alloy"Proc.of Fourth Pacific Rim International Conference on Advanced Materials and Processing. (発表予定).

    • Related Report
      2000 Annual Research Report

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Published: 2000-04-01   Modified: 2016-04-21  

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