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Development of Selective Alkene Hydrogenation with Atomic Hydrogen Permeating through a Pd Sheet Electrode for Industrialization

Research Project

Project/Area Number 12650848
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Synthetic chemistry
Research InstitutionThe University of Electro-Communications

Principal Investigator

MAKI Shojiro  Department of Applied Physics and Chemistry, Faculty of Electro-Communications, The University of Electro-Communications、Research Associate, 電気通信学部, 助手 (20266349)

Co-Investigator(Kenkyū-buntansha) HIRANO Takashi  Department of Applied Physics and Chemistry, Faculty of Electro-Communications, The University of Electro-Communications、Associate Professor, 電気通信学部, 助教授 (20238380)
NIWA Haruki  Department of Applied Physics and Chemistry, Faculty of Electro-Communications, The University of Electro-Communications、Professor, 電気通信学部, 教授 (20135297)
Project Period (FY) 2000 – 2001
Project Status Completed (Fiscal Year 2001)
Budget Amount *help
¥3,600,000 (Direct Cost: ¥3,600,000)
Fiscal Year 2001: ¥1,400,000 (Direct Cost: ¥1,400,000)
Fiscal Year 2000: ¥2,200,000 (Direct Cost: ¥2,200,000)
KeywordsSeslective hydrogenation / catalytic reaction / palladium / electroorganic chemistry / industrialization / 環境調和型 / 触媒 / 有機合成 / 工業合成 / 新規機能材料 / 水素
Research Abstract

Hydrogenation of an alkene is quite important for organic' syntheses employing a catalyst (Pd, Ni, Pt) which chemisorbes active hydrogen, however, hydrogenolysis of allylic C-O bonds and benzyloxy groups (Bn-O-) also takes place under the same conditions. Therefore, it is difficult for alkenes having an allyloxy and/or benzyloxy group to be hydrogenated by active hydrogen without the hydrogenolysis.
A new hydrogenation system utilizing electrochemically produced activehydrogen has been successful in the saturation of several unsaturated organic compounds such as styrene and its derivates.
The reaction cell is made up of two compartments separated by a Pd sheet as cathode, where galvanostatic electrolysis of water is carried out to produce the active hydrogen atone side of the Pd sheet, and a substrate is hydrogenated at the opposite side surface by active hydrogen permeating through the Pd sheet.

Report

(3 results)
  • 2001 Annual Research Report   Final Research Report Summary
  • 2000 Annual Research Report
  • Research Products

    (9 results)

All Other

All Publications (9 results)

  • [Publications] Shojiro Maki: "Selective Alkene Hydrogenation with Atomic Hydrogen Permeating through a Pd Sheet Electrode"Synthetic Communications. 30. 3575-3583 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Shojiro Maki: "Hydrogenolysis-free Hydrogenation by Pd Black Powder Catalyst"Synlett. 10. 1590-1592 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Shojiro Maiki: "Effect of Solvent and Hydrogen during Selective Hydrogenation"Tetrahedron Letters. 42. 8323-8327 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S. Maki, Y. Harada, T. Hirano, H. NIwa, Y. Yoshida, S. Ogata, S. Nakamatsu, H. Inolue, and C. Iwakura: "Selective Alkene Hydrogenation with Atomic Hydrogen Permeating through a Pd Sheet Eelctrode"Synthetic Communications. 30. 3575-3583 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Shojiro Maki, Makiko Okawa, Ryo Matui, Takashi Hirano and Haruki Niwa: "Hydrogenolysis-free Hydrogenation by Pd Black Powder Catalyst"Synlett. 10. 1590-1592 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Shojiro Maki, Yasuhiro Harada, Ryo Matsui, Makiko Okawa, Takashi Hirano, Haruki Niwa, Megumi Koizumi, Yoshinori Nishiki, Hiroshi Inoue, and Chiaki Iwakura: "Effect of Solvent and Hydrogen during Selective Hydrogenation"Tetrahedron Letters. 42. 8323-8327 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Shojiro Maki: "Selective Alkene Hydrogenation with Atomic Hydrogen Permeating through a Pd Sheet Electrode"Synthetic Communications. 30. 3575-3583 (2000)

    • Related Report
      2001 Annual Research Report
  • [Publications] Shojiro Maki: "Hydrogenolysis-free Hydrogenation by Pd Black Powder Catalyst"Synlett. 10. 1590-1592 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Shojiro Maki: "Effect of Solvent and Hydrogen during Selective Hydrogenation"Tetrahedron Letters. 42. 8323-8327 (2001)

    • Related Report
      2001 Annual Research Report

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Published: 2000-04-01   Modified: 2016-04-21  

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