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Studies on Preparation of Polymer Membranes for Removal of Volatile Organic Compounds and Analysis of Membrane Characteristics

Research Project

Project/Area Number 12650892
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 高分子構造・物性(含繊維)
Research InstitutionKansai University

Principal Investigator

URAGAMI Tadashi  Kansai University, Faculty of Engineering, Professor, 工学部, 教授 (80067701)

Co-Investigator(Kenkyū-buntansha) MIYATA Takashi  Kansai University, Faculty of Engineering, Associate Professor, 工学部, 助教授 (50239414)
Project Period (FY) 2000 – 2002
Project Status Completed (Fiscal Year 2002)
Budget Amount *help
¥3,600,000 (Direct Cost: ¥3,600,000)
Fiscal Year 2002: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 2001: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 2000: ¥1,400,000 (Direct Cost: ¥1,400,000)
KeywordsPMMA-g-PDMS / Membrane / Benzene permselectivity / PFA-g-PDMS / tert-Butyl[4]calixarene / Transmission electron microscope / Microphase separation / Membrane structure / 吸着剤 / 高分子添加剤 / 撥水性 / アルキルメタクリレート / ジメチルシロキサンマクロモノマー / グラフト共重合体膜 / 希薄炭化水素水溶液 / 炭化水素選択透過性 / 透過分離機構 / ミクロ相分離構造 / モルホロジー
Research Abstract

Three kinds of graft copolymers were synthesized from alkylmethacrylate and dimethylsiloxane macromonomer (DMS). A membrane (DMS content 65mol%) prepared from methylmethacrylate (MMA) and DMS (PMMA-g-PDMS) showed high benzene permselectivity for an aqueous solution of dilute benzene during pervaporation. In order to improve higher benzene permselective membranes, a graft copolymer (PFA-g-PDMS) as polymer additive was synthesized from perfluoroalkyl acrylate and DMS, and PFA-g-PDMS / PMMA-g-PDMS membranes added PFA-g-PDMS to a casting solution of PMMS-g-PDMS (DMS: 65wt %) were prepared. The surface of these membranes became more hydrophobic, and consequently, the surface of the air-side of PFA-g-PDMS / PMMA-g-PDMS membranes was water-repellent. In order to prepare much more high benzene permselective membranes, tert-butyl [4]calixarene, which has high affinity for benzene, was added to a casting solution of PMMA-g-PDMS (DMS: 65wt %). Both permeation rate and benzene permselectivity of CA / PMMA-g-PDMS membranes increased with increasing CA content. Their improvement of the membrane performance with the addition of CA to PMMA-g-PDMS could be attributed to the fact that CA mainly existed in a continuous PDMS phase of the microphase separated structure.

Report

(4 results)
  • 2002 Annual Research Report   Final Research Report Summary
  • 2001 Annual Research Report
  • 2000 Annual Research Report
  • Research Products

    (56 results)

All Other

All Publications (56 results)

  • [Publications] T.Miyata, T.Uragami: "Relationship between fractal microphase separation and permselectivity of block copolymer membranes containing poly(dimethylsiloxane)"J.Polym.Sci.: Part B : Polym.Phys.. 38. 584-589 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 浦上 忠, 宮田隆志: "抗原-抗体結合を利用する可逆性ヒドロゲル インテリジェント材料などの機能性高分子としての応用の可能性"化学と生物. 38・7. 427-429 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 宮田隆志, 浦上 忠: "多成分系高分子における相分離構造の新しい評価方法"日本接着学会誌. 36・7. 279-286 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 浦上 忠: "水中の環境ホルモンを選択的に除去する高分子膜"工業材料. 48・10. 94-102 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 浦上 忠: "内分泌攪乱物質を選択的に透過する高分子膜の開発"機能材料. 20・10. 58-65 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 浦上 忠, 宮田隆志: "新規な抗原応答性高分子ヒドロゲルの調製とその物質透過制御機能"高分子加工. 49・12. 530-536 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T.Uragami, T.Miyata: "Removal of Dilute Volatile Organic Compounds(VOCs)in Water through Graft Copolymer Membrane consisting of Poly(alkylmethacrylate)and Poly(dimethylsiloxane)by Pervaporation and Their Membrane Morphology"J.Membrane Science. 187. 255-269 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 浦上 忠, 宮田隆志: "親水性有機-無機ハイブリッド膜によるエタノール水溶液の分離濃縮に及ぼす膜構造の影響"ネットワークポリマー. 22. 157-162 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T.Uragami, T.Miyata: "Effect of the Addition of Calixarene to Microphase Separated Membranes for the Removal of Volatile Organic Compounds from Dilute Aqueous Solution"Macromolecules. 34. 6806-6811 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T.Uragami, T.Miyata: "Surface Modification of Microphase -Separated Membranes by Fluorine -Containing Polymer Additive and Removal of Dilute Benzene in Water through These Membranes"Macromolecules. 34. 8026-8033 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 浦上 忠, 宮田隆志: "架橋キトサン膜の構造と尿成分水溶液の透過分離特性との関係"ネットワークポリマー. 22. 212-217 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T.Miyata, T.Uragami: "Biomolecule -Sensitive Hydrogels"Adv.Drug Deliv.Rev.. 54. 79-98 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 浦上 忠: "キトサン誘導体膜の透過分離機能"BIO INDUSTRY. 19. 48-61 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T.Uragami, M.Takuno, T.Miyata: "Evapomeation Characteristics of Cross-linked Quaternized Chitosan Membranes for The Separation of An Ethanol / Water Azeotrope"Macromol.Chem.Phys.. 203. 1162-1170 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T.Uragami, Y.Tanaka, H.Nishida: "Permeation and Separation under High Temperature and High Pressure for Ethanol / Water Vapors through Cross-linked Quaternized Chitosan Composite Membranes"Desalination. 147. 449-454 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T.Uragami, K.Okazaki, H.Matugi, T.Miyata: "Structure and Permeation Characteristics of An Aqueous Ethanol Solution of Organic-Inorganic Hybrid Membranes Composed of Poly(vinyl alcohols)and Tetraethoxysilane"Macromolecules. 35. 9156-9163 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T.Uragami, S.Yamamoto, T.Miyata: "Dehydration from Alcohols by Polyion Complex Cross-linked Chitosan Composite Membranes during Evapomeation"Biomacromelecules. 4. 137-144 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T.Uragami: "Pervaporation Property of Surface Modified Poly [1-(trimethylsilyl)-1-propyne] Membranes, Membrane Formation and Modification"American Chemical Society. 361 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T.Uragami: "Structural Design for Improvement of Permselectivity of Chitosan derivative Membranes, CHITIN AND CHITOSAN"KODANSHA SCIENTIFIC LTD.. 572 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T.Uragami, T.Miyata: "Crosslinked Quaternized Chitosan Membranes, Chitosan in Pharmacy and Chemistry"Atec Edizioni. 524 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Miyata, T. Uragami: "Relationship between fractal microphase separation and permselectivity of block copolymer membranes containing poly(dimethylsiloxane)"J. Polym. Sci.: Part B: Polym. Phys.. 38. 584-589 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Uragami, T. Miyata: "Reversible Hydrogels using Antigen-Antibody binding. Possibility of Application as Functional Polymer such as Intelligent Materials"Chemistry and Biology. 38・7. 427-429 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Miyata, T. Uragami: "New Estimation of Phase Separated Structure in Multicomponent Polymers"J. Adhesion Soc. Jpn.. 36・7. 279-286 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Uragami: "Polymer Membranes for permselective Removal of Environmental Hormones in water"Ind. Mater.. 48・10. 94-102 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Uragami: "Development of Polymer Membranes for Selective Permeation of Endocrine Disruptors"Functional Mater.. 20・10. 58-65 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Uragami, T. Miyata: "Preparation of Novel Antigen-Responsive Hydrogels and Their Controlled Function for Permeation of Materials"Polym. Proc.. 49・12. 530-536 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Uragami, T. Miyata: "Removal of Dilute Volatile Organic Compounds (VOCs) in Water through Graft Copolymer Membrane Consisting of Poly(alkylmethacrylate) and Poly(dimethylsiloxane) by Pervaporation and Their Membrane Morphology"J. Membrane Science. 187. 255-269 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Uragami, T. Miyata: "Effect of Membrane structures on Separation Characteristics for an Aqueous Ethanol Solution Through Hydrophilic Organic-Inorganic Hybrid Membranes"Network Polym.. 22. 157-162 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Uragami, T. Miyata: "Effect on the Addition of Calixarene to Microphase Separated Membranes for the Removal of Volatile Organic Compounds from Dilute Aqueous Solution"Macromolecules. 34. 6806-6811 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Uragami, T. Miyata: "Surface Modification of Microphase-Separated Membranes by Fluorine-Containing Polymer Additive and Removal of Dilute Benzene in Water through These Membranes"Macromolecules. 34. 8026-8033 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Uragami, T. Miyata: "Relationship between Structure of Cross-linked Chitosan Membranes and Their Permeation and Separation Chracteristics for an Aqueous Solution containing Urine Components"Network Polym.. 22. 212-217 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Uragami, T. Miyata: "Biomolecule-Sensitive Hydrogels"Adv. Drug Deliv. Rev.. 54. 79-98 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Uragami: "Function of Permeation and Separation of Chitosan Derivative Membranes"BIO INDUSTRY. 19. 48-61 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Uragami, M. Takuno, T. Miyata: "Evapomeation Characteristics of Cross-linked Quaternized Chitosan Membranes for The Separation of An Ethanol/ Water Azeotrope"Macromol. Chem. Phys.. 203. 1162-1170 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Uragami, Y. Tanaka, H. Nishida: "Permeation and Separation under High Temperature and High Pressure for Ethanol / Water Vapors through Cross-linked Quaternized Chitosan Composite Membranes"Desalination. 147. 449-454 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Uragami, K. Okazaki, H. Matsugi, T. Miyata: "Structure and Permeation Characteristics of An Aqueous Ethanol Solution of Organic-Inorganic Hybrid Membranes composed of Poly(vinyl alcohols) and Tetraethoxysilane"Macromolecules. 35. 9156-9163 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Uragami, S. Yamamoto, T. Miyata: "Dehydration from Alcohols by Polyion Complex Cross-linked Chitosan Composite Membranes during Evapomeation"Biomacromolecules. 4. 137-144 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T.Miyata, T.Uragami: "Biomolecule-Sensitive Hydrogels"Adv. Drug Deliv. Rev.. 54. 79-98 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 浦上 忠: "キトサン誘導体膜の透過分離機能"BIO INDUSTRY. 19. 48-61 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Uragami, T.Miyata: "Evapomeation Characteristics of Cross-linked Quaternized Chitosan Membranes for The Separation of An Ethanol/Water Azeotrope"Macromol. Chem. Phys.. 203. 1162-1170 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Uragami: "Permeation and Separation under High Temperature and High Pressure for Ethanol/Water Vapors through Cross-linked Quaternized Chitosan Composite Membranes"Desalination. 147. 449-454 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Uragami, T.Miyata: "Structure and Permeation Characteristics of An Aqueous Ethanol Solution of Organic-Inorganic Hybrid Membranes composed of Poly (vinyl alcohol) and Tetraethoxysilane"Macromolecules. 35. 9156-9163 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Uragami, T.Miyata: "Dehydration from Alcohols by Polyion Complex Cross-linked Chitosan Composite Membranes during Evapomeation"Biomacromolecules. 4. 137-144 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Uragami, T.Miyata: "Crosslinked Quaternized Chitosan Membranes, Chitosan in Pharmacy and Chemistry"R.A.A.Muzzarelli, C.Muzzarelli. 524 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Uragami, T.Miyata: "Removal of Dilute Volatile Organic Compounds (VOCs) in Water through Graft Copolymer Membrane consisting of Poly(alkylmethacrylate) and Poly(dimethylsiloxane) by Pervaporation and Their Membrane Morphology"J. Membrane Science. 187. 255-269 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 浦上 忠, 宮田隆志: "親水性有機-無機ハイブリッド膜によるエタノール水溶液の分離濃縮に及ぼす膜構造の影響"ネットワークポリマー. 22. 157-162 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] T.Uragami, T.Miyata: "Effects of the Addition of Calixarene to Microphase Separated Membranes for the Removal of Volatile Organic Compounds from Dilute Aqueous Solution"Macromolecules. 34. 6806-6811 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] T.Uragami, T.Miyata: "Surface Modification of Microphase-Separated Membranes by Fluorine-Containing Polymer Additive and Removal of Dilute Benzene in Water through These Membranes"Macromolecules. 34. 8026-8033 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 浦上 忠, 宮田隆志: "架橋キトサン膜の構造と尿成分水溶液の透過分離特性との関係"ネットワークポリマー. 22. 212-217 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 浦上 忠: "先端高機能材料"吉川昌範(編集委員長),エヌジーティー. 587 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] T.Miyata,T.Uragami: "Relationship between fractal microphase separation and permselectivity of block copolymer membranes containing poly (dimethylsiloxane)"J.Polym.Sai.: Part B : Polym.Phys.. 38. 584-589 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 浦上忠,宮田隆志: "抗原-抗体結合を利用する可逆性ヒドロゲルインテリジェント材料などの機能性高分子としての応用の可能性"化学と生物. 38・7. 427-429 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 宮田隆志,浦上忠: "多成分系高分子における相分離構造の新しい評価方法"日本接着学会誌. 36・7. 279-286 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 浦上忠: "水中の環境ホルモンを選択的に除去する高分子膜"工業材料. 48・10. 94-102 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 浦上忠: "内分泌攪乱物質を選択的に透過する高分子膜の開発"機能材料. 20・10. 58-65 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 浦上忠,宮田隆志: "新規な抗原応答性高分子ヒドロゲルの調製とその物質透過制御機能"高分子加工. 49・12. 530-536 (2000)

    • Related Report
      2000 Annual Research Report

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Published: 2000-04-01   Modified: 2016-04-21  

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