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炭素クラスター複合体の精密有機合成化学

Research Project

Project/Area Number 13001002
Research Category

Grant-in-Aid for Specially Promoted Research

Allocation TypeSingle-year Grants
Review Section Chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

中村 栄一  東京大学, 大学院・理学系研究科, 教授 (00134809)

Co-Investigator(Kenkyū-buntansha) 松尾 豊  東京大学, 大学院・理学系研究科, 助手 (00334243)
赤阪 健 (赤坂 健)  筑波大学, 大学院・数理物質科学研究科, 教授 (60089810)
澤村 正也  北海道大学, 大学院・理学研究科・化学系専攻, 教授 (40202105)
Project Period (FY) 2001 – 2004
Project Status Completed (Fiscal Year 2004)
Budget Amount *help
¥503,100,000 (Direct Cost: ¥387,000,000、Indirect Cost: ¥116,100,000)
Fiscal Year 2004: ¥71,500,000 (Direct Cost: ¥55,000,000、Indirect Cost: ¥16,500,000)
Fiscal Year 2003: ¥118,300,000 (Direct Cost: ¥91,000,000、Indirect Cost: ¥27,300,000)
Fiscal Year 2002: ¥122,200,000 (Direct Cost: ¥94,000,000、Indirect Cost: ¥28,200,000)
Fiscal Year 2001: ¥191,100,000 (Direct Cost: ¥147,000,000、Indirect Cost: ¥44,100,000)
Keywordsフラーレン / 炭素クラスター / 有機銅試薬 / 付加反応 / バッキーフェロセン / シャトルコック分子 / シクロフェナセン / 金属内包フラーレン / DNA / 遺伝子導入 / ベシクル / 液晶 / ポリアセン / 錯体触媒 / 有機合成化学 / シャトルコック液晶 / ベクシル / 有機金属錯体 / 密度汎関数法計算 / 電導性ポリマー
Research Abstract

2002年よりフラーレン,ナノチューブの大量合成が企業化され,ナノテクノロジーの中核技術としてますます注目されている.フラーレンやカーボンナノチューブなどの炭素クラスターそのものの性質は相当程度解明されたといえるが,それらの材料としてのポテンシャルを高めるためには,「化学修飾炭素クラスターの精密合成化学」の研究を展開することが必須である.本研究の目的は,炭素クラスター同士の複合体,炭素クラスターと有機分子,金属,生体分子などとの複合体を,炭素共有結合形成を鍵にして高効率・高選択的に作り出すことである.その結果,次世代の材料科学,ナノテクノロジーや医学に資する新しい物質科学を創成できると同時に,精密合成化学,触媒化学など基礎化学分野での新発見が期待できる.
本年度は,機能性炭素クラスター分子合成の取りまとめとして,五重付加型フラーレン誘導体およびアミノ化フラーレン誘導体の工業製品レベルの大量供給の方法を確立した.また,フラーレン誘導体からさらに修飾して得られるフラーレン-遷移金属錯体についてもいくつか代表的なものについては簡便に大量合成を行う方法を開発した.さらに,官能基化されたフラーレン遷移金属錯体や多核のフラーレン-遷移金属錯体を合成する手法も確立し,今後,電子デバイスへの実用化に向けた研究を展開することが可能となった.新しい分子集合の様式で液晶性を示す炭素クラスター複合体液晶分子(シャトルコック液晶分子)についても,より液晶相を発現させやすく,種々の誘導化が簡便な第二世代のシャトルコック分子を大量合成を可能にする研究を行った。また,金属内包フラーレンイオン種の種々の反応(ケイ素化反応,カルベンとの反応,ジアゾ化合物との反応など)について研究を行い,得られる化合物の反応性と物性を調査した.

Report

(4 results)
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • 2002 Annual Research Report
  • 2001 Annual Research Report
  • Research Products

    (87 results)

All 2005 2004 Other

All Journal Article (38 results) Book (4 results) Publications (45 results)

  • [Journal Article] Synthesis and Derivatization of Iridium(I) and Iridium(III) Pentamethyl[60]fullerene Complexes.2005

    • Author(s)
      Y.Matsuo, et al.
    • Journal Title

      Organometallics 24

      Pages: 4837-4840

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Reactivity and Stability of Organocopper(I), Silver(I), and Gold(I) Ate Compounds and Their Trivalent Derivatives2005

    • Author(s)
      W.Nakanishi, et al.
    • Journal Title

      J.Am.Chem.Soc. 127

      Pages: 1446-1453

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Chemical Reactivity of the Cation and Anion of M@C82 (M=Y,La,and Ce)2005

    • Author(s)
      Y.Maeda, et al.
    • Journal Title

      J.Am.Chem.Soc. 127

      Pages: 2143-2146

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Synthesis and Reactivity of Bucky Ruthenocene Ru(h5-C60Me5)(h5-C5H5)2004

    • Author(s)
      Y.Matsuo, et al.
    • Journal Title

      Chem.Lett. 33

      Pages: 328-329

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Stacking of Molecules Possessing a Fullerene Apex and a Cup-shaped Cavity Connected by Silicon-Connection2004

    • Author(s)
      Y.Matsuo, et al.
    • Journal Title

      J.Am.Chem.Soc. 126

      Pages: 432-433

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Mechanism of Addition of Organocuprates to Alkynyl Carbonyl Compounds. Mechanistic Bridge between Carbocupration and Conjugate Addition2004

    • Author(s)
      A.Mori, et al.
    • Journal Title

      Organometallics 23

      Pages: 1081-1088

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Synthesis of Functionalized Fullerene by Mono-alkylation of Fullerene Cyclopentadienide2004

    • Author(s)
      R.Hamasaki, et al.
    • Journal Title

      Chem.Lett. 33

      Pages: 328-329

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Iron-Catalyzed Cross-Coupling of Primary and Secondary Alkyl Halides with Aryl Grignard Reagents2004

    • Author(s)
      M.Nakamura, et al.
    • Journal Title

      J.Am.Chem.Soc. 126

      Pages: 3686-3687

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Zn(II)/Amine-Catalyzed Coupling Reaction of Alkylidenemalonates with Propargyl Alcohol : A One-Pot Synthesis of Methylenetetrahydrofurans2004

    • Author(s)
      M.Nakamura, et al.
    • Journal Title

      Org.Lett. 6

      Pages: 2015-2017

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Multi-layer Vesicles and Vesicle Clusters Formed by Fullerene-based Surfactant C60(CH3)5K2004

    • Author(s)
      Christian Burger, et al.
    • Journal Title

      J.of Colloid and Interface Science 275

      Pages: 632-641

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Mechanism and Regioselectivity of Reductive Elimination of h-Allylcopper (III) Intermediates2004

    • Author(s)
      M.Yamanaka, et al.
    • Journal Title

      J.Am.Chem.Soc. 126

      Pages: 6287-6293

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Selective deposition of a gadolinium(III) cluster in a hole opening of single-wall carbon nanohorn2004

    • Author(s)
      A.Hashimoto, et al.
    • Journal Title

      Proc.Natl.Acad.Sci.U.S.A. 101

      Pages: 8527-8530

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Nickel, Palladium and Platinum Complexes of h5- Cyclopentadienide C60R5 Ligands. Kinetic and Thermodynamic Stabilization Effects of C60Ph5 Ligand2004

    • Author(s)
      Y.Kuninobu, et al.
    • Journal Title

      Oxganometallics 23

      Pages: 3259-3266

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Creation of Hoop-and Bowl-Shaped Benzenoid Systems by Selective Detraction of [60]Fullerene Conjugation. [10]Cyclophenacene and Fused Corannulene Derivatives2004

    • Author(s)
      Y.Matsuo, et al.
    • Journal Title

      J.Am.Chem.Soc. 126

      Pages: 8725-8734

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Molecular orientation and electronic structure of epitaxial bucky ferrocene((Fe(C60(CH3)5)C5H5) thin films2004

    • Author(s)
      T.Kaji, et al.
    • Journal Title

      J.Phys.Chem.B 108

      Pages: 9914-9918

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Mechanism and Ligand-Transfer Selectivity of 1,2-Addition of Organozincate Complexes to Aldehyde2004

    • Author(s)
      M.Uchiyama, et al.
    • Journal Title

      J.Am.Chem.Soc. 126

      Pages: 10897-10903

    • Related Report
      2004 Annual Research Report
  • [Journal Article] α-Alkylation of Ketones by Addition of Zinc Enamides to Unactivated Olefins2004

    • Author(s)
      M.Nakamura, et al.
    • Journal Title

      J.Am.Chem.Soc. 126

      Pages: 11820-11825

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Thermal and palladium-catalyzed [3+2] synthesis of cyclopentadienone acetals from cyclopropenone acetals and acetylenes2004

    • Author(s)
      H.Isobe, et al.
    • Journal Title

      Org.Lett. 6

      Pages: 1522-2667

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Photoinduced change in the Raman spectrum of buckyferrocene (Fe(C60(CH3)5)C5H5)2004

    • Author(s)
      T.Shimada, et al.
    • Journal Title

      Solid State Commun. 132

      Pages: 141-288

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Mechanism of Substitution Reaction on sp2-Carbon Center with Lithium Organocuprate2004

    • Author(s)
      N.Yoshikai, et al.
    • Journal Title

      J.Am.Chem.Soc. 126

      Pages: 12664-12665

    • Related Report
      2004 Annual Research Report
  • [Journal Article] L-Shaped Three-Center Two-Electron (C-C-C)+ Bonding Array2004

    • Author(s)
      N.Yoshikai, et al.
    • Journal Title

      J.Am.Chem.Soc. 126

      Pages: 12941-12948

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Sequential Coupling of Zincated Hydrazone, Alkenylboronate, and Electrophile That Creates Several Contiguous Stereogenic Centers2004

    • Author(s)
      M.Nakamura, et al.
    • Journal Title

      J.Am.Chem.Soc. 126

      Pages: 14344-14345

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Enantioselective Allylic Substitution of Cinnamyl Esters Catalyzed by Iridium-Chiral Rryl Phosphite Complex : Conspicuous Change in the Mechanistic Spectrum by a Countercation and Solvent2004

    • Author(s)
      N.Kinoshita, et al.
    • Journal Title

      J.Org.Chem. 69

      Pages: 7960-7954

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Bucky ferrocene and ruthenocene : serendipity and discoveries2004

    • Author(s)
      E.Nakamura, et al.
    • Journal Title

      J.Organomet.Chem. 689

      Pages: 4630-4635

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Stereoselective Synthesis of Tetra-Substituted Olefins via Addition of Zinc Enolates to Unactivated Alkynes2004

    • Author(s)
      M.Nakamura, et al.
    • Journal Title

      Org.Lett. 6

      Pages: 4837-4840

    • Related Report
      2004 Annual Research Report
  • [Journal Article] 機能性有機フラーレンを用いた生命科学及び材料科学への展開2004

    • Author(s)
      中村栄一ら
    • Journal Title

      ファルマシア 40

      Pages: 1007-1011

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Supermolecular Dynamics of Cyclic [6]Paraphenyleneacetylene Complexes with [60]- and [70]Fullerene Derivatives : Electronic and Structural Effects on Complexation2004

    • Author(s)
      T.Kawase, et al.
    • Journal Title

      Angew.Chem.Int.Ed. 43

      Pages: 5060-5062

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Removal of Carbonaceous Materials from Single-Walled Carbon Nanotubes by a Simple Chemical Modification2004

    • Author(s)
      Y.Maeda, et al.
    • Journal Title

      ITE Lett. 5

      Pages: 263-266

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Lanthnaum Endohedral Metallofulleropyrrolidines : Synthesis, Isolation, and EPR Characterization2004

    • Author(s)
      B.Cao, et al.
    • Journal Title

      Chem.Eur.J. 10

      Pages: 716-720

    • Related Report
      2004 Annual Research Report
  • [Journal Article] A verification of the photolytic decomposition pathways of 3-tert-butyl-3-chlorodiazirine based on the application of the C60 probe technique2004

    • Author(s)
      T.Wakahara, et al.
    • Journal Title

      Tetrahedron Lett. 45

      Pages: 553-556

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Chemical reactivity and redox property of Sc3@C822004

    • Author(s)
      T.Wakahara, et al.
    • Journal Title

      Chem.Phys.Lett. 398

      Pages: 553-556

    • Related Report
      2004 Annual Research Report
  • [Journal Article] C60 field effect transistor with electrodes modified by La@C822004

    • Author(s)
      K.Tanigaki, et al.
    • Journal Title

      Chem.Phys.Lett. 400

      Pages: 235-238

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Reduction of Endohedral Metallofullerenes : A Convenient Method for Isolation2004

    • Author(s)
      Tsuchiya, et al.
    • Journal Title

      Chem.Mater. 16

      Pages: 4343-4346

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Nondestructive and High-Recovery-Yield Purification of Single-Walled Carbon Nanotubes by Chemical Functionalization2004

    • Author(s)
      Y.Lian, et al.
    • Journal Title

      J.Phys.Chem.B. 108

      Pages: 8848-8854

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Dispersion of Single-Walled Carbon Nanotube Bundles in Non-Aqueous Solution2004

    • Author(s)
      Y.Maeda, et al.
    • Journal Title

      J.Phys.Chem.B. 108

      Pages: 18395-18397

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Characterization of Ce@C82 and Its Anion2004

    • Author(s)
      T.Wakahara, et al.
    • Journal Title

      J.Am.Soc.Chem. 126

      Pages: 4483-4487

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Isolation and Characterization of a Carbene Derivative of La@C822004

    • Author(s)
      Y.Maeda, et al.
    • Journal Title

      J.Am.Soc.Chem. 126

      Pages: 6858-6859

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Isolation, Characterization, and Theoretical Study of La2@C782004

    • Author(s)
      B.Cao, et al.
    • Journal Title

      J.Am.Chem.Soc. 126

      Pages: 9164-9165

    • Related Report
      2004 Annual Research Report
  • [Book] 実験化学講座(第5版) 12巻 計算化学 2章3節の12004

    • Author(s)
      森 聖治, 中村栄一
    • Total Pages
      11
    • Publisher
      丸善
    • Related Report
      2004 Annual Research Report
  • [Book] 実験化学講座(第5版) 21巻 有機金属化合物・超分子錯体 10章1節 有機銅錯体2004

    • Author(s)
      中村栄一, 中村正治
    • Total Pages
      13
    • Publisher
      丸善
    • Related Report
      2004 Annual Research Report
  • [Book] 水溶性高分子の新展開 10章 水溶性フラーレンの可能性2004

    • Author(s)
      磯部寛之, 中村栄一
    • Total Pages
      7
    • Publisher
      シーエムシー出版
    • Related Report
      2004 Annual Research Report
  • [Book] 超分子科学-ナノ材料創製に向けて 37章 水溶性フラーレンの合成とバイオ機能2004

    • Author(s)
      磯部寛之, 中村栄一
    • Total Pages
      18
    • Publisher
      化学同人
    • Related Report
      2004 Annual Research Report
  • [Publications] Masahiro Yamanaka: "Theoretical Studies on Structures and Reactivities of Organocuprate(I) and Organocopper(III) Species"Journal of Computational Chemistry. 24. 1401-1409 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Masaharu Nakamura: "Reaction Pathways of the Simmons-Smith Reaction"Journal of the American Chemical Society. 125. 2341-2350 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Eiichi Nakamura: "Synthesis, Structure, and Aromaticity of a Hoop-Shaped Cyclic Benzenoid [10] Cyclophenacene"Journal of the American Chemical Society. 125. 2834-2835 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Yutaka Matsuo: "Ruthenium (II) Complexes of Pentamethylated [60]Fullerene Alkyl, Alkynyl, Chloro, Isocyanide, Phosphine Complexes"Organometallics. 22. 2554-2563 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Masaharu Nakamura: "Iron-Catalyzed Regio-and Stereoselective Ring Opening of [2.2.1]- and [3.2.1]Oxabicyclic Alkenes with a Grignard Reagent"Organic Letters. 5. 1373-1375 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Masaharu Nakamura: "Enantioselective Synthesis of Alpha-Substituted Ketones by Asymmetric Addition of Chiral Zinc Enamides to 1-Alkenes"Journal of the American Chemical Society. 125. 6362-6363 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Motoki Toganoh: "Regioselective Synthesis of [60]Fullerene η^5-Indenide R_3C_<60>^- and η^5-Cyclopentadienide R_5C_<60>^-Bearing Different R Groups"Organic & Biomolecular Chemistry. 1. 2604-2611 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Tomoki Shirakawa: "Doping Effects of Novel Fullerene Derivatives in Conducting Polymer"Synthetic Metals. 137. 1415-1416 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Motoki Toganoh: "Rhenium-templated Regioselective Polyhydrogenation of [60]Fullerene and Derivatives. Rhenium η^5-Complexes of Hydrofullerenes"Angewandte Chemie International Edition. 42. 3530-3532 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Yutaka Matsuo: "Theoretical Studies on Structures and Reactivities of Finite-Length Single Wall Armchair Carbon Nanotubes"Organic Letters. 5. 3181-3184 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Naohiko Yoshikai: "Theoretical Studies on Diastereo- and Enantioselective Rhodium-Catalyzed Cyclization of Diazo Compound via Intramolecular C-H Bond Insertion"Advanced Synthesis and Catalysis. 345. 1139-1145 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Masaharu Nakamura: "Indium-Catalyzed Addition of Active Methylene Compounds to 1-Alkynes"Journal of the American Chemical Society. 125. 13002-13003 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Hiroyuki Isobe: "Synthesis of Fullerene Glycoconjugates through Sulfide Connection in Aqueous Media"Organic Letters. 5. 4461-4463 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Motoki Toganoh: "Synthesis and Catalytic Activity of Rhodium Diene Complexes Bearing Indenyl-Type Fullerene η^5-Ligand"Journal of Organometallic Chemistry. 683. 295-300 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Motoki Toganoh: "Synthesis of Ferrocene/Hydrofullerene Hybrid and Functionalized Bucky Ferrocenes"Journal of the American Chemical Society. 125. 13974-13975 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Yutaka Matsuo: "Synthesis and Reactivity of Bucky Ruthenocene Ru(η^5-C_<60>Me_5)(η^5-C_5H_5)"Chemistry Letters. 33. 68-69 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Yutaka Matsuo: "Stacking of Molecules Possessing a Fullerene Apex and a Cup-shaped Cavity Connected by Silicon-Connection"Journal of the American Chemical Society. 126. 432-433 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Ryo Hamasaki: "Synthesis of Functionalized Fullerene by Mono-alkylation of Fullerene Cyclopentadienide"Chemistry Letters. 33. 328-329 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] 中村栄一, 松尾豊(Chapter2-1執筆): "有機金属反応剤ハンドブック(玉尾皓平編)"化学同人. 260 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 澤村正也: "Regioselective Penta-addition of 1-Alkenyl Copper Reagent to [60]Fullerene. Synthesis of Penta-alkenyl FCp Ligand"Journal of the Organometallic Chemistry. 652. 31-35 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 中村正治: "Carbozincation of Dipolar Trimethylenemethane. A New Route to Functionalized Organozinc Reagents"Chemistry Letters. 146-147 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 磯部寛之: "Synthesis of Disubstituted Cucurbit[6]uril and Its Rotaxane Derivative"Organic Letters. 4. 1287-1289 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 中村栄一: "Mechanism of C-H Bond Activation/C-C Bond Formation Reaction between Diazo Compound and Alkane Catalyzed by Dirhodium Tetracarboxylate"Journal of the American Chemical Society. 124. 7181-7192 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 澤村正也: "Cu(I)-Mediated Regioselective Tri-addition of Grignard Reagent to [70]Fullerene. Synthesis of Indenyl-type Metal Ligand Embedded into Graphitic Structure"Journal of Materials Chemistry. 12. 2109-2115 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 澤村正也: "Hybrid of Ferrocene and Fullerene"Journal of the American Chemical Society. 124. 9354-9355 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 山中正浩: "Density Functional Studies on Kinetic Reactivity of "Higher Order"Lipshutz Cuprate in Addition Reaction to Acetylene"Bulletin of the Chemical Society Japan. 75. 1815-1818 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 澤村正也: "Stacking of conical molecules with a fullerene apex into polar columns in crystals and liquid crystals"Nature. 419. 702-705 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 中村正治: "Reaction Pathways of the Simmons-Smith Reaction"Journal of the American Chemical Society. 125. 2341-2350 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] 中村栄一: "Synthesis, Structure and Aromaticity of a Hoop-shaped Cyclic Benzenoid [10]Cyclophenacene"Journal of the American Chemical Society. 125. 2834-2835 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] 藤井彰彦: "Photocurrent Enhancement in Conducting Polymer Device by Doping with Endohedral Metallofullerene La@C_<82>"Japan Journal of Applied Physics. 41. 2254-2255 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 高口 豊: "Reversible C_<60> Binding to Anthracene-Having Dendritic Poly(amide amine)Substituent Producing an Acidic Water-soluble Fullerodendrimer"Angewante Chemie International Eddition. 41. 817-819 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Y.Niino: "Photochemical Decomposition of Pyrazoline Produced in the Reaction of C_<60> with Diazoadamantane"ITE Letters. 3. C60-C63 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 中島直敏: "Construction of a Metallofullerene La@C_<82>/Artificial Lipid Film-Modified Electrode Device and Its Electron Transfer"Journal of Physical Chemistry B. 106. 3523-3525 (2002)

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  • [Publications] 若原孝次: "Silylation of Higher Fullerenes"Journal of Materials Chemical. 12. 2061-2064 (2002)

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  • [Publications] 若原孝次: "Ionization and Structural Determination of the Major Isomer of Pr@C_<82>"Chemical Physics Letters. 360. 235-239 (2002)

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  • [Publications] 若原孝次: "A Non-spectroscopic Method to Determine the Photolytic Decomposition Pathways of 3 Chloro-3-alkyldiazirine ; Carbene, Diazo and Rearrangement in Excited State"Journal of the American Society. 124. 9465-9468 (2002)

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  • [Publications] 中村栄一(分担), Manfred Schlosser編: "Organometallic Chemistry, Method, 2^<nd> edition"Wiley. (2002)

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  • [Publications] 中村栄一(分担), Nobert Krause Ed編: "Organocopper Chemistry"Wiley-VCH. (2002)

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  • [Publications] 中村栄一(分担), 有機合成化学協会編: "有機合成 創造の軌跡(My Favorite Organic Synthesis)"化学同人. (2002)

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  • [Publications] E.Nakamura, M.Sawamura et al.: "Spherical Bilayer Vesicles of Fullerene Based Surfactants in Water"Science. 291. 1944-1947 (2001)

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  • [Publications] E.Nakamura et al.: "Atomic Force Microscope Studies on Condensation of Plasmid DNA with Functionalized Fullerene"Angew. Chem. Int. Ed. 40. 3364-3367 (2001)

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  • [Publications] E.Nakamura et al.: "Theoretical Studies on Solvent and Substituent Effects of Cuprate Conjugate Addition"Organometallics. 20. 5675-5681 (2001)

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  • [Publications] E.Nakamura et al.: "Synthesis and Transfection Capability of Multi-functionalized Fullerene Polyamine"Chem. Lett. 1214-1215 (2001)

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  • [Publications] E.Nakamura et al.: "Doping Effects of Tetra (amino) fullerene Epoxide in Conducting Polymer Thin Film"Jpn. J. Appl. Phys.. 40. L1390-L1393 (2001)

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  • [Publications] T.Akasaka: "Structral Department of the La@CB2 isomer"J. Phys. Chem. B. 105. 2971-2974 (2001)

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Published: 2001-04-01   Modified: 2018-03-28  

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