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液液界面ナノ領域の未開拓化学機能の開発

Research Project

Project/Area Number 13129101
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionOsaka University

Principal Investigator

渡會 仁  大阪大学, 大学院・理学研究科, 教授 (30091771)

Co-Investigator(Kenkyū-buntansha) KOVALENKO Andriy (KOVALENKO Andry)  岡崎国立共同研究機構, 分子科学研究所, 助手 (10332181)
澤田 嗣郎  東京大学, 大学院・新領域創成科学研究科, 教授 (90011105)
寺前 紀夫  東北大学, 大学院・理学研究科, 教授 (70114569)
後藤 雅宏  九州大学, 大学院・工学研究院, 教授 (10211921)
中谷 清治  筑波大学, 化学系, 助教授 (00250415)
Project Period (FY) 2001 – 2004
Project Status Completed (Fiscal Year 2004)
Budget Amount *help
¥16,000,000 (Direct Cost: ¥16,000,000)
Fiscal Year 2004: ¥1,500,000 (Direct Cost: ¥1,500,000)
Fiscal Year 2003: ¥5,200,000 (Direct Cost: ¥5,200,000)
Fiscal Year 2002: ¥5,200,000 (Direct Cost: ¥5,200,000)
Fiscal Year 2001: ¥4,100,000 (Direct Cost: ¥4,100,000)
Keywords液液界面ナノ化学 / Interfacial Nanochemistry / 液液界面 / 界面構造 / 一分子計測 / 錯形成反応 / 界面分離工学 / 分子認識 / 界面不安定化 / 自己組織化 / 界面物性
Research Abstract

平成13〜15年度に実施された特定領域研究「液液界面ナノ領域の化学」(略称:液液界面ナノ化学)の成果をとりまとめるとを目的とし、以下の活動を行った。
1、平成16年10月18日に終了ヒアリングを受け、Aの評価をいただいた。
2、日本分析化学会の国際学術誌Anal. Sci.誌に、"Analytical Chemistry at Liquid-Liquid Interfaces"の特集号No.11(2004)を刊行し、分担研究者、協力研究者の研究成果を含む22報を掲載した。領域代表者がGuest Editorを務めた。
3、Kluwer Academic/Plenum Publishersより領域代表者と研究計画代表者2名がEditorとなって、"Interfacial Nanochemistry"を刊行(2005.1)し、研究代表者等の研究成果を公表した。
4、Pacifichem2005(2005.12.15-20)にて、Symposium "Advances in Nanochemistry at Liquid Interfaces"の開催を企画し、本特定領域研究の成果を含めて発表することとした。
5、平成17年3月6-7日に、成果とりまとめ会を関西にて開催した。終了ヒアリングの結果の吟味と、終了後の成果の公表状況、成果報告書(冊子体)の作成計画等について議論した。また、今後も、本特定領域研究を継続的に発展させる必要性が要望され、そのための方策について意見の交換を行った。

Report

(4 results)
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • 2002 Annual Research Report
  • 2001 Annual Research Report
  • Research Products

    (23 results)

All 2005 2004 Other

All Journal Article (2 results) Book (1 results) Publications (20 results)

  • [Journal Article] Total internal reflection second-harmonic generation spectrometer system optimized for the liquid/liquid interface2005

    • Author(s)
      K.fujiwara, H.Monjushiro, H.Watarai
    • Journal Title

      Rev.Sci.Instrum 76

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Complex Formation of Copper(II) and Iron(II) with Octadecyloxythiazolylazophenol at the Heptane-Water Interface2004

    • Author(s)
      H.Oyama, A.Ohashi, H.Watarai
    • Journal Title

      Anal.Sci 20

      Pages: 1543-1547

    • NAID

      40006493966

    • Related Report
      2004 Annual Research Report
  • [Book] Interfacial Nanochemiatry : Molecular Science and Engineering at Liquid-Liquid Interfaces2005

    • Author(s)
      H.Watarai, N.Teramae, T.Sawada
    • Total Pages
      321
    • Publisher
      Kluwer Academic/Plenum Publishers
    • Related Report
      2004 Annual Research Report
  • [Publications] Fujiwara Kazuhiko, Watarai Hitoshi: "Interfacial hydrolysis in the m-oxo dimer formation of tetraphenylporphinatomanganese(III) in the toluene/water system"Analytical Sciences. 20. 369-372 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Watarai hitoshi, Tsukahara Satoshi, Nagatani Hirohisa, Ohashi Akira: "Interfacial Nannochemistry in liquid-liquid extraction systems"Bulletin of the Chemical Society of Japan. 76(8). 1471-1492 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Suwa Masayori, Watarai Hitoshi: "Magnetophoretic velocity of microorganic droplets adsorbed by disprosium(III) laurate in water."Journal of Chromatography A. 1013. 3-8 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Tokimoto Takahira, Tsukahara Satoshi, Watarai Hitoshi: "Measurements of interfacial complexation of samarium(III) and its fluorescent lifetime by micro-two-phase sheath flow/fluorescence microscopy"Chemistry Leters. 32(10). 940-941 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Sasaki Naoko, Monjushiro Hideaki, Watarai Hitoshi: "Fabrication of a centrifugal liquid menbrane cell for a direct spectroscopic measurement of electlytic reaction in two-phase liquid-menbrane system"Bunseki Kagaku. 52(9). 701-705 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Nishizawa Seiichi, Yokobori Tomoyuki, Kato Ryo, Yoshimoto Keitaro, Kamaishi Tomoyuki, Teramae Norio: "Hydrogen-bond forming ionophore for highly efficient transport of phosphate anions across the nitrobenzene-water interface."Analyst. 128(6). 663-669 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fujinami Masanori, Murakawa Hiromi, Sawada Tsuguo: "Highly sensitive detection of molecules at the liquid/liquid interface using total internal reflection-optical beam deflection based on photothermal spectroscopy"Review of Scientific Instruments. 74(1,Pt.2). 352-354 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Chikama Katsumi, Negishi Takayuki, Nakatani Kiyoharu: "Transfer mechanism of dodecyl sulfate with methylene blue across an oil/water interface studied by single-droplet injection and microabsorption methods."Bulletin of the Chemical Society of Japan. 76(2). 295-299 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] A.Kovalenko, F.Hirata: "Molecular description of electrolyte solution in a carbon aerogel electrode"Condensed Matter Physics. 36. 583-609 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Miyako Eijiro, Maruyama Tatsuo, Kamiya Noriho, Goto Masahiro: "Transport of organic acids through a supported liquid membrane driven by lipase-catalyzed reactions"Journal of Bioscience and Bioengineering. 96(4). 370-374 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Kenji Katayama, Kohei Shibamoto, Tsuguo Sawada: "Direct Observation of Ultrafast Charge Transfer in Relation to the Surface Enhanced Raman Scattering Activation Detected by Transient Reflecting Grating Spectroscopy"Chem. Phys. Lett.. 345. 265-271 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Tetsuya Takahashi, Hiroharu Yui, Tsuguo Sawada: "Direct Observation of Dynamic Molecular Behavior at a Water/Nitrobenzene Interface in a Chemical Oscillation System"J. Phys. Chem. B. 106. 2314-2318 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] H.Watarai, Y.Onoe: "Molecular dynamics simulation of interfacial adsorption of 2-hydroxy oxime at heptane/water interface"Solv. Extr. Ion Exch.. 19(1). 155-166 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] N.Fujiwara, S.Tsukahara, H.Watarai: "In situ Fluorescence Imaging and Time-Resolved Total Internal Reflection Fluorometry of Palladium(II)-Tetrapyridylporphine Complex Assembled at Toluene-Water Interface"Langmuir. 17(17). 5337-5342 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] K.Nakatani, T.Negishi: "Kinetic Analysis of Fast Mass Transfer across Oil/Water Interface using Single Microdroplet Injection and Potential Step Electrolysis"Anal. Sci.. 17. 1109-1111 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] K.Nakatani, H.Nagatani, D.J.Fermin, H.H.Girault: "Transfer and Adsorption of 1-Pyrene Sulfonate across the Water/1,2-Dichloro-ethane Interface Studied by Potential Modulated Fluorescence Spectroscopy"J. Electroanal. Chem.. 518(1). 1-5 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] S.Nishizawa, T.Yokobori, R.Kato, T.Shioya, N.Teramae: "Chloride transfer across the liquid-liquid interface fascilitated by a mono-thiourea as a hydrogen-bonding ionophore"Bull. Chem. Soc. Jpn.. 74(12). 2343-2347 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] S.Nishizawa, T.Yokobori, T.Shioya, N.Teramae: "Facilitated transfer of hydrophilic anions across the nitrobenzene-water interface by a hydrogen bond-forming ionophore : Applicability for multianalyte detection"Chem. Lett.. (10). 1058-1059 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Fukiko KUBOTA, Masahiro GOTO: "Extraction of Rare Earth Metals by Calix[4]arene Solubilized in AOT Reversed Micellar Solution"Sep. and Pur. Technol.. 24. 93-100 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 上江洲一也, 後藤雅宏: "界面分子インプリントポリマーのマトリクスに影響を与える因子の解明とその制御"化学工学論文集. 27(6). 753-755 (2001)

    • Related Report
      2001 Annual Research Report

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Published: 2001-04-01   Modified: 2018-03-28  

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