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Dynamic Monitoring of Molecular Structure at Solid/Liquid Interfaces

Research Project

Project/Area Number 13304047
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionHokkaido University

Principal Investigator

UOSAKI Kohei  Hokkaido Univ., Grad.School of Sci., Prof., 大学院・理学研究科, 教授 (20133697)

Co-Investigator(Kenkyū-buntansha) TAKAKUSAGI Satoru  Hokkaido univ., Grad.School of Sci., Research Associate, 大学院・理学研究科, 助手 (30359484)
YAGI Ichizo  Hokkaido Univ., Grad.School of Sci., Lecturer, 大学院・理学研究科, 講師 (40292776)
近藤 敏啓  お茶の水女子大学, 理学部, 助教授 (70240629)
Project Period (FY) 2001 – 2003
Project Status Completed (Fiscal Year 2003)
Budget Amount *help
¥50,570,000 (Direct Cost: ¥38,900,000、Indirect Cost: ¥11,670,000)
Fiscal Year 2003: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2002: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2001: ¥40,040,000 (Direct Cost: ¥30,800,000、Indirect Cost: ¥9,240,000)
KeywordsSelf-assembled monolayer / Solid / liquid interface / Sun frequency generation / Visible pump IR probe technique / Scanning probe microscopy / Surface x-ray scattering / Quartz crystal microbalanc / Semiconductor nanocluster / 溶液界面 / SFG / 可視光ポンプ-SFGプローブ法
Research Abstract

・Construction of Sun frequency generation (SFG) system for dynamic structure change.
(a)A pump line using 355nm excitation beam was added to a ps-based SFG system so that time dependent structure change can be followed with 〜2Ops time resolution.
(b)A broad band SFG system was constructed based on a visible pump IR probe system using 100 fs laser.
・Applications of the SFG systems to solid/liquid interface.
(a)Monitoring of TiO_2 surface for the conversion to hydrophilic surface and adsorption of alcohol.
TiO_2 is the most studied photocatalyst and conversion of hydrophobic surface to hydrophilic surface by UV illumination is an interesting process. Here, SFG was used to monitor the conversion process from hydrophobic to hydrophilic surface and the adsorption of alcohol.
(b)Carrier dynamics in semiconductor nanoclusters
Semiconductor nanoclusters attract much attention due to their unique optical properties. Photoexcited carrier (electron and holes) dynamics in CdSSe nanoclusters dispersed in glass and CdS nanoclusters in reversed micelles were followed by visible pump-IR absorption probe technique.
(c)Determination of water structure at electrode/electrolyte interface.
Although structure of water at electrode surface attracts much interests from both fundamental and application view points, it is not well understood due to the limitation of techniques. Here, we were successful to measure the water structure at gold film electrode as a function of electrode potential using SFG.

Report

(4 results)
  • 2003 Annual Research Report   Final Research Report Summary
  • 2002 Annual Research Report
  • 2001 Annual Research Report
  • Research Products

    (95 results)

All Other

All Publications (95 results)

  • [Publications] S.Ye et al.: "Stability of the Si-H Bond on the Hydrogen-Terminated Si(111) Surface Studied by Sum Frequency Generation"Surf.Sci.. 476,No.1-2. 121-128 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Ye et al.: "Conformational Order of Octadecanethiol (ODT) Monolayer at Gold/Solution Interface : Internal Reflection Sum Frequency Generation (SFG) Study"Studies in Surf.Sci.and Catal.. 132. 705-710 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Ye et al.: "Spectroscopic Studies on Electroless Deposition of Copper on a Hydrogen-Terminated Si(111) Surface in Fluoride Solutions"Electrochem.Soc.. 148,No.6. C421-C426 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Ye et al.: "Sum Frequency Generation (SFG) Study of the pH-dependent Water Structure on a Fused Quartz Surface Modified by an Octadecyltrichlorosilane (OTS) Monolayer"PCCP. 3,No.16. 3463-3469 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Nihonyanagi et al.: "Sum Frequency Generation Study on the Molecular Structures at the Interfaces between Quartz Modified with Amino-Terminated Self-Assembled Monolayer and Electrolyte Solutions of Various pH and Ionic Strengths"Electrochim.Acta. 46,Nos.20-21. 3057-3061 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Kondo et al.: "Control of the Charge-Transfer Rate at a Gold Electrode Modified with a Self-Assembled Monolayer Containing Ferrocene and Azobenzene by Electro- and Photochemical Structural Conversion of cis and trans Forms of the Azobenzene Moiety"Langmuir. 17,No.20. 6317-6324 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Kondo et al.: "Formation and Electrochemical Characteristics of Multilayers of Au Nanoclusters Covered by Mixed Self-Assembled Monolayers of Three Kinds of Alkanethiols with Methyl, Ferrocene, or Carboxylate Terminal Group on Au(111) Surface"Chem.Lett.. No.9. 930-931 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] J.Zhao et al.: "A Novel Nanolithography Technique for Self-Assembled Monolayers Using a Current Sensing Atomic Force Microscope"Langmuir. 17,No.25. 7784-7788 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Kondo et al.: "Anion Effect on the Electrochemical Characteristics of a Gold Electrode Modified with a Self-assembled Monolayer of Ferrocenylhexanethiol in Aqueous and Dichloromethane Solutions"J.Organometallic Chem.. 637-639,No.1. 841-844 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Wano et al.: "In Situ, Real-Time Monitoring of the Reductive Desorption Process of Self-Assembled Monolayers of Hexanethiol on Au(111) Surfaces in Acidic and Alkaline Aqueous Solutions by Scanning Tunneling Microscopy"Langmuir. 17,No.26. 8224-8228 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.E.Quayam et al.: "Formation of Organic Monolayer on a Hydrogen Terminated Si(111) Surface via Silicon-Carbon Bond Monitored by ATR FT-IR and SFG Spectroscopy : Effect of Orientational Order on the Reaction Rate"Chem.Lett.. No.2. 208-209 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] J.Zhao et al.: "Formation of Nanopatterns of a Self-Assembled Monolayer (SAM) within a SAM of Different Molecules Using a Current Sensing Atomic Force Microscope"Nano Letters. 2,No.2. 137-140 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Awatani et al.: "Second Harmonic Generation Study on Electrochemical Deposition of Palladium on a Polycrystalline Gold Electrode"J.Electroanal.Chem.. 524-525. 184-193 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Kondo et al.: "In situ Structural Study on Underpotential Deposition of Ag on Au(111) Electrode Using Surface X-ray Scattering Technique"J.Electroanal.Chem.. 532,Nos.1-2. 201-205 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Kondo et al.: "A Novel Spectroelectrochemical Cell for in situ Surface X-ray Scattering Measurements of Single Crystal Disk Electrodes"Electrochim.Acta. 47,No.17. 3075-3080 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Kondo et al.: "A Rotating Gold Ring-Gold Disk Electrode Study on Electrochemical Reductive Desorption and Oxidative Readsorption of a Self-Assembled Monolayer of Dodecanethiol"J.Electroanal.Chem.. 538-539. 59-63 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Ye et al.: "Characterization of Self-Assembled Monolayers of Alkanethiol on GaAs Surface by Contact Angle and Angle-Resolved XPS Measurements"Surf.Sci.. 529,No.1-2. 163-170 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Sumi et al.: "Electrochemical Oxidative Adsorption and Reductive Desorption of the Self-Assembled Monolayer of Decanethiol on Au(111) Surface in KOH Ethanol Solution"J.Electroanal.Chem.. 550-551. 321-325 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Ye et al.: "Structural Changes in Poly(2-methoxyethyl acrylate) Thin Films Induced by Absorption of Bisphenol A. An Infrared and Sum Frequency Generation (SFG) Study"Macromolecules. 36,No.15. 5694-5703 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] J.Zhao et al.: "Dielectric Properties of Organic Monolayers Directly Bonded on Silicon Probed by Current Sensing Atomic Force Microscope"Appl.Phys.Lett.. 83,No.10. 2034-2036 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] W.Song et al.: "Electron and Ion Transport through Multilayers of Au Nanoclusters Covered by Self-Assembled Monolayers"J.Electroanal.Chem.. 554-555. 385-393 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] I.Yagi et al.: "Direct Proof for Electrochemical Substitution of Surface Hydrogen of Boron-doped Diamond Electrode by TOF-ESD Method"Chem.Lett.. 32,No.11. 1050-1051 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Y.-H.Kim et al.: "Formation and Electric Property Measurement of Nanosized Patterns of Tantalum Oxide by Current Sensing Atomic Force Mictroscope"J.Appl.Phys.. 94,No.12. 7733-7738 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] W.Song et al.: "Construction and Electrochemical Characteristics of Multilayer Assemblies of Au Nanoclusters Protected by Mixed Self-assembled Monolayers on Tin-doped Indium Oxide"PCCP. 5. 5279-5284 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Uosaki et al.: "Photophysical and Photo-electrochemical Characteristics of Multilayers of CdS Nanoclusters"Faraday Discuss.. 125. 39-53 (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Kondo et al.: "Decomposition Processes of Organic Monolayer Formed on Si(111) via Silicon-Carbon Bond by Exposure to UV Irradiation and/or Ozone"Langmuir. 20,No.4. 1207-1212 (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Ye et al.: "Stability of the Si-H Bond on the Hydrogen-Terminated Si(111) Surface Studied by Sum Frequency Generation"Surf.Sci.. 476, No.1-2. 121-128 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Ye et al.: "Conformational Order of Octadecanethiol (ODT) Monolayer at Gold/Solution Interface : Internal Reflection Sum Frequency Generation (SFG) Study"Studies in Surf.Sci.and Catal.. 132. 705-710 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Ye et al.: "Spectroscopic Studies on Electroless Deposition of Copper on a Hydrogen-Terminated Si(111) Surface in Fluoride Solutions"J.Electrochem.Soc.. 148, No.6. C421-C426 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Ye et al.: "Sum Frequency Generation (SFG) Study of the pH-dependent Water Structure on a Fused Quartz Surface Modified by an Octadecyltrichlorosilane (OTS) Monolayer"PCCP. 3, No.16. 3463-3469 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Nihonyanagi et al.: "Sum Frequency Generation Study on the Molecular Structures at the Interfaces between Quartz Modified with Amino-Terminated Self-Assembled Monolayer and Electrolyte Solutions of Various pH and Ionic Strengths"Electrochim.Acta. 46, Nos.20-21. 3057-3061 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Kondo et al.: "Control of the Charge-Transfer Rate at a Gold Electrode Modified with a Self-Assembled Monolayer Containing Ferrocene and Azobenzene by Electro-and Photochemical Structural Conversion of cis and trans Forms of the Azobenzene Moiety"Langmuir. 17, No.20. 6317-6324 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Kondo et al.: "Formation and Electrochemical Characteristics of Multilayers of Au Nanoclusters Covered by Mixed Self-Assembled Monolayers of Three Kinds of Alkanethiols with Methyl, Ferrocene, or Carboxylate Terminal Group on Au(111) Surface"Chem.Lett.. No.9. 930-931 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] J.Zhao et al.: "A Novel Nanolithography Technique for Self-Assembled Monolayers Using a Current Sensing Atomic Force Microscope"Langmuir. 17, No.25. 7784-7788 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Kondo et al.: "Anion Effect on the Electrochemical Characteristics of a Gold Electrode Modified with a Self-assembled Monolayer of Ferrocenylhexanethiol in Aqueous and Dichloromethane Solutions"J.Organometallic Chem.. 637-639, No.1. 637-639 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Wano et al.: "In Situ, Real-Time Monitoring of the Reductive Desorption Process of Self-Assembled Monolayers of Hexanethiol on Au(111) Surfaces in Acidic and Alkaline Aqueous Solutions by Scanning Tunneling Microscopy"Laugmuir. 17, No.26. 8224-8228 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.E.Quayam et al.: "Formation of Organic Monolayer on a Hydrogen Terminated Si(111) Surface via Silicon-Carbon Bond Monitored by ATR FT-IR and SFG Spectroscopy : Effect of Orientational Order on the Reaction Rate"Chem.Lett.. No.2. 208-209 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] J.Zhao et al.: "Formation of Nanopatterns of a Self-Assembled Monolayer (SAM) within a SAM of Different Molecules Using a Current Sensing Atomic Force Microscope"Nano Letters. 2, No.2. 137-140 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Awatani et al.: "Second Harmonic Generation Study on Electrochemical Deposition of Palladium on a Polycrystalline Gold Electrode"J.Electroanal.Chem.. 524-525. 184-193 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Kondo et al.: "In situ Structural Study on Underpotential Deposition of Ag on Au(111) Electrode Using Surface X-ray Scattering Technique"J.Electroanal.Chem.. 532, Nos.1-2. 201-205 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Kondo et al.: "A Novel Spectroelectrochemical Cell for in situ Surface X-ray Scattering Measurements of Single Crystal Disk Electrodes"Electrochim.Acta. 47, No.17. 3075-3080 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Kondo et al.: "A Rotating Gold Ring-Gold Disk Electrode Study on Electrochemical Reductive Desorption and Oxidative Readsorption of a Self-Assembled Monolayer of Dodecanethiol"J.Electroanal.Chem.. 538-539. 59-63 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Ye et al.: "Characterization of Self-Assembled Monolayers of Alkanethiol on GaAs Surface by Contact Angle and Angle-Resolved XPS Measurements"Surf.Sci.. 529, No.1-2. 163-170 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Sumi et al.: "Electrochemical Oxidative Adsorption and Reductive Desorption of the Self-Assembled Monolayer of Decanethiol on Au(111) Surface in KOH Ethanol Solution"J.Electroanal.Chem.. 550-551. 321-325 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Ye et al.: "Structural Changes in Poly(2-methoxyethyl acrylate) Thin Films Induced by Absorption of Bisphenol A. An Infrared and Sum Frequency Generation (SFG) Study"Macromolecules. 36, No.15. 5694-5703 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] J.Zhao et al.: "Dielectric Properties of Organic Monolayers Directly Bonded on Silicon Probed by Current Sensing Atomic Force Microscope"Appl.Phys.Lett.. 83, No.10. 2034-2036 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] W.Song et al.: "Electron and Ion Transport through Multilayers of Au Nanoclusters Covered by Self-Assembled Monolayers"J.Electroanal.Chem.. 554-555. 385-393 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] I.Yagi et al.: "Direct Proof for Electrochemical Substitution of Surface Hydrogen of Borondoped Diamond Electrode by TOF-ESD Method"Chem.Lett.. 32, No.11. 1050-1051 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Y.-H.Kim et al.: "Formation and Electric Property Measurement of Nanosized Patterns of Tantalum Oxide by Current Sensing Atomic Force Microscope"J.Appl.Phys.. 94, No.12. 7733-7738 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] W.Song et al.: "Construction and Electrochemical Characteristics of Multilayer Assemblies of Au Nanoclusters Protected by Mixed Self-assembled Monolayers on Tindoped Indium Oxide"PCCP. 5. 5279-5284 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Uosaki et al.: "Photophysical and Photoelectrochemical Characteristics of Multilayers of CdS Nanoclusters"Faraday Discuss.. 125. 39-53 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Kondo et al.: "Decomposition Processes of Organic Monolayer Formed on Si(111) via Silicon-Carbon Bond by Exposure to UV Irradiation and/or Ozone"Langmuir. 20, No.4. 1207-1212 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Ye: "Surface Molecular Structures of Langmuir-Blodgett Films of Stearic Acid on Sol Substrates Studied by Sum Frequency Generation Spectroscopy"Langmuir. 19・6. 2238-2242 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] C.Humbert: "Probing a Molecular Electronic Transition by Two-colour Sum-frequency Generatic Spectroscopy"Appl.Surf.Sci. 212-213. 797-803 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] S.Ye: "Characterization of Self-Assembled Monolayers of Alkanethiol on GaAs Surface b Contact Angle and Angle-Resolved XPS Measurements"Surf.Sci. 529・1-2. 163-170 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] S.Ye: "Structural Changes in Poly (2-methoxyethyl acrylate) Thin Films Induced by Absorption of Bisphenol A. An Infrared and Sum Frequency Generation (SFG) Study"Macromolecules. 36・15. 5694-5703 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] I.Yagi: "Direct Proof for Electrochemical Substitution of Surface Hydrogen of Boron-dope Diamond Electrode by TOF-ESD Method"Chem.Lett.. 32・11. 1050-1051 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Uosaki: "Photophysical and Photoelectrochemical Characteristics of Multilayers of CdS Nanoclusters"Faraday Discuss.. 125. 39-53 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] 魚崎浩平: "ナノテクノロジーハンドブックII編 観る(第2分冊)"オーム社. 169 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] H.Kawamura: "Evidence for the Diffusion of Au Atoms into the Te UPD Layer Formed on a Au(111) Substrate"Journal of Electrochemical Society. 149. C83-C88 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] M.E.Quayam: "Formation of Organic Monolayer on a Hydrogen Terminated Si(111)Surface via Silicon-Carbon Bond Monitored by ATR FT-IR and SFG Spectroscopy : Effect of Orientational Order on the Reaction Rate"Chemistry Letters. (2). 208-209 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] J.Zhao: "Formation of Nanopatterns of a Self-Assembled Monolayer(SAM) within a SAM of Different Molecules Using a Current Sensing Atomic Force Microscope"Nano Letters. 2. 137-140 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Awatani: "Second Harmonic Generation Study on Electrochemical Deposition of Palladium on a Polycrystalline Gold Electrode"Journal of Electroanalytical Chemistry. 524. 184-193 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Kondo: "In situ Structural Study on Underpotential Deposition of Ag on Au(111)Electrode Using Surface X-ray Scattering Technique"Journal of Electroanalytical Chemistry. 532. 201-205 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Saito: "In situ Study of Ultra-thin Film Formation on Au(111)Surface in Propylene Carbonate by Scanning Tunneling Microscopy Under Potential Control"Journal of Electrochemical Society. 149. E286-E291 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Kondo: "A Novel Spectroelectrochemical Cell for in situ Surface X-ray Scattering Measurements of Single Crystal Disk Electrodes"Electrochimica Acta. 47. 3075-3080 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Kondo: "A Rotating Gold Ring-Gold Disk Electrode Study on Electrochemical Reductive Desorption and Oxidative Readsorption of a Self-Assembled Monolayer of Dodecanethiol"Journal of Electroanalytical Chemistry. 538. 59-63 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Saito: "In Situ Scanning Tunneling Microscopy Study on Surface Film Formation and Lithium Underpotential Deposition Process on Au(111)Surface in Propylene Carbonate"Journal of Electrochemical Society. (in press).

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Sumi: "Electrochemical Oxidative Adsorption and Reductive Desorption of the Self-Assembled Monolayer of Decanethiol on Au(111)Surface in KOH Ethanol Solution"Journal of Electroanalytical Chemistry. (in press).

    • Related Report
      2002 Annual Research Report
  • [Publications] S.Ikeda et al.: "Photocatalytic Activity of Transition-metal-loaded Titanium (IV) Oxide Powders Suspended in Aqueous Solutions : Correlation with Electron-hole Recombination Kinetics"Physical Chemistry Chemical Physics. 3. 267-273 (2001)

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      2001 Annual Research Report
  • [Publications] Hideo Naohara et al.: "Thickness Dependent Electrochemical Reactivity of Epitaxially Electrodeposited Palladium Thin Layers on Au(111) and Au(100)"Journal of Electroanalytical Chemistry. 500・1-2. 435-445 (2001)

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      2001 Annual Research Report
  • [Publications] Shen Ye et al.: "Stability of the Si-H Bond on the Hydrogen Terminated Si(111) Surface Studied by Sum Frequency Generation"Surface Science. 476. 121-128 (2001)

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      2001 Annual Research Report
  • [Publications] Shen Ye et al.: "Conformational Order of Octadecanethiol (ODT) Monolayer at Gold/Solution Interface : Internal Reflection Sum Frequency Generation (SFG) Study"Studies in Surf. Sci. and Catal.. 132. 705-710 (2001)

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      2001 Annual Research Report
  • [Publications] Shen Ye et al.: "Spectroscopic Studies on Electroless Deposition of Copper on a Hydrogen Terminated Si(111) Surface in Fluoride Solutions"Journal of Electrochemical Society. 148・6. C421-C426 (2001)

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      2001 Annual Research Report
  • [Publications] Ryo Yamada et al.: "Structural Investigation of the Self-Assembled Monolayer of Decanethiol on the Reconstructed-and (1x1)-Au(100) Surfaces by Scanning Tunneling Microscopy"Langmuir. 17・14. 4148-4150 (2001)

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      2001 Annual Research Report
  • [Publications] A.Sato et al.: "A Ligand Substitution Reaction of Oxo-centred Triruthenium Complexes Assembled as Monolayers on Gold Electrodes"Physical Chemistry Chemical Physics. 3. 3420-3426 (2001)

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      2001 Annual Research Report
  • [Publications] Shen Ye et al.: "Sum Frequency Generation (SFG) Study of the pH-dependent Water Structure on the Fused Quartz Surface Modified by Octadecyltrichlorosilane (OTS) Monolayer"Physical Chemistry Chemical Physics. 3. 3463-3469 (2001)

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      2001 Annual Research Report
  • [Publications] Satoshi Nihonyanagi et al.: "Sum Frequency Generation Study on the Molecular Structures at the Interfaces Between Quartz Modified with Amino-Terminated Self-Assembled Monolayer and Electrolyte Solutions of Various pH and Ionic Strengths"Electrochimica Acta. 46・20-21. 3057-3061 (2001)

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      2001 Annual Research Report
  • [Publications] Toshihiro Kondo et al.: "Control of the Charge Transfer Rate at a Gold Electrode Modified with a Self-Assembled Monolayer Containing Ferrocene and Azobenzene by Electro- and Photochemical Structural Conversion of cis- and trans-forms of the Azobenzene Moiety"Langmuir. 17・20. 6317-6324 (2001)

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      2001 Annual Research Report
  • [Publications] Toshihiro Kondo et al.: "Formation and Electrochemical Characteristics of Multilayers of Au Nanoclusters Covered by Mixed Self-Assembled Monolayers of Three Kinds of Alkanethiols with Methyl, Ferrocene, or Carboxylate Terminal Group on Au(111) Surface"Chemistry Letters. 930-931 (2001)

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      2001 Annual Research Report
  • [Publications] H.Koshima et al.: "Synthesis, Structure and Second-harmonic Generation of Noncentrosymmetric Cocrystals of 2-amino-5-nitropyridine with Achiral Benzenesulfonic Acids"Crystal Growth & Design. 1・6. 467-471 (2001)

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      2001 Annual Research Report
  • [Publications] Jianwei Zhao et al.: "A Novel Nanolithography Technique for Self-Assembled Monolayer Using Current Sensing Atomic Force Microscope"Langmuir. 17・25. 7784-7788 (2001)

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      2001 Annual Research Report
  • [Publications] Toshihiro Kondo et al.: "Anion effect on the electrochemical characteristics of a gold electrode modified with a self-assembled monolayer of ferrocenylhexanethiol in aqueous and dichloromethane solutions"Journal of Organometallic Chemistry. 637-639・1. 841-844 (2001)

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      2001 Annual Research Report
  • [Publications] Hiromi Wano et al.: "In Situ, Real Time Monitoring of the Reductive Deposition Process of Self-Assembled Monolayer of Hexanethiol on Au(111) Surface in Acidic and Alkaline Aqueous Solutions by Scanning Tunneling Microscopy"Langmuir. 17・26. 8224-8228 (2001)

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      2001 Annual Research Report
  • [Publications] Ichizo Yagi et al.: "The Effects of Nitrogen and Plasma Power on Electrochemical Properties of Boron-doped Diamond Electrodes Grown by MPCVD"Journal of Electrochemical Society. 149・1. E1-E5 (2002)

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  • [Publications] H.Kawamura et al.: "Evidence for the Diffusion of Au Atoms into the Te UPD Layer Formed on a Au(111) Substrate"Journal of Electrochemical Society. 149・2. C83-C88 (2002)

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      2001 Annual Research Report
  • [Publications] T.Nakanishi et al.: "Enantioselective Adsorption of Phenylalanine onto Self-Assembled Monolayer of 1,1'-Binaphthalene-2,2'-dithiol on Gold"Journal of American Chemical Society. 124・5. 740-741 (2002)

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      2001 Annual Research Report
  • [Publications] M.E.Quayam et al.: "Formation of Organic Monolayer on a Hydrogen Terminated Si(111) Surface via Silicon Carbon Bond Monitored by ATR FT-IR and SFG Spectroscopy : Effect of Orientational Order on the Reaction Rate"Chemistry Letters. 2. 208-209 (2002)

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      2001 Annual Research Report
  • [Publications] A.Di Paola et al.: "Preparation of Polycrystalline TiO_2 Photocatalysis Impregnated with Various Transition Metal Ions : Characterization and Photocatalytic Activity for the Degradation of 4-Nitrophenol"Journal of Physical Chemistry B. 106. 637-645 (2002)

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      2001 Annual Research Report
  • [Publications] Jianwei Zhao et al.: "Formation of Nano-patterns of a Self-Assembled Monolayer (SAM) within a SAM of Different Molecules Using a Current Sensing Atomic Force Microscope"Nano Letters. 2・2. 137-140 (2002)

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      2001 Annual Research Report
  • [Publications] M.E.Quayam et al.: "Mechanism for Nucleation and Growth of Electrochemical Palladium Deposition on an Au(111) Electrode"Journal of Electroanalytical Chemistry. (in press).

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      2001 Annual Research Report
  • [Publications] Tadashi Awatani et al.: "Second Harmonic Generation Study on Electrochemical Deposition of Palladium on a Polycrystalline Gold Electrode"Journal of Electroanalytical Chemistry. (in press).

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      2001 Annual Research Report
  • [Publications] Toshihiro Kondo et al.: "In situ Structural Study on Underpotential Deposition of Ag on Au(111) Electrode Using Surface X-ray Scattering Technique"Journal of Electroanalytical Chemistry. (in press).

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      2001 Annual Research Report
  • [Publications] M.Takahashi et al.: "Heteroepitaxial Growth of CdTe on p-Si(111) Substrate by Pulsed-light Assisted Electrodeposition"Applied Physics Letters. (in press).

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      2001 Annual Research Report
  • [Publications] Toshiya Saito et al.: "In situ Study of Ultra-thin Film Formation on Au(111) Surface in Propylene Carbonate by Scanning Tunneling Microscopy Under Potential Control"Journal of Electrochemical Society. (in press).

    • Related Report
      2001 Annual Research Report

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Published: 2001-04-01   Modified: 2016-04-21  

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