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Fabrication of VGCF incorporated C/C composite with high thermal property

Research Project

Project/Area Number 13305050
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Composite materials/Physical properties
Research InstitutionShinshu University

Principal Investigator

ENDO Morinobu  Shinshu University, Faculty of Engineering, Professor, 工学部, 教授 (10021015)

Co-Investigator(Kenkyū-buntansha) MIYAZAKI Takashi  Nagano National College of Technology, Professor, 電気工学科, 教授 (10141889)
OSHIDA Kyoichi  Nagano National College of Technology, Professor, 電子情報工学科, 教授 (90224229)
HAYASHI Takuya  Shinshu University, General Information Processing Center, an assistant professor, 総合情報処理センター, 助教授 (80313831)
Project Period (FY) 2001 – 2003
Project Status Completed (Fiscal Year 2003)
Budget Amount *help
¥47,190,000 (Direct Cost: ¥36,300,000、Indirect Cost: ¥10,890,000)
Fiscal Year 2003: ¥8,320,000 (Direct Cost: ¥6,400,000、Indirect Cost: ¥1,920,000)
Fiscal Year 2002: ¥15,600,000 (Direct Cost: ¥12,000,000、Indirect Cost: ¥3,600,000)
Fiscal Year 2001: ¥23,270,000 (Direct Cost: ¥17,900,000、Indirect Cost: ¥5,370,000)
KeywordsC / C composite / VGCF / Thermal Conductivity / Carbon Nanotube / Carbon Fiber / Precursor / ブレカーサ / BGCF / キャパシタ / ピッチ系材料 / 電子顕微鏡 / 元素分析 / ファジィ画像処理 / 気相成長炭素繊維 / カーボンナノファイバー / carbon nanotubes / 炭素 / 炭素複合材料
Research Abstract

Carbon nanotubes with multi walled structure have been successfully prepared and commercialized by Endo's process based on Catalytic Chemical Vapor Deposition (CCVD) Method. These multiwalled carbon nanotubes have an extremely high thermal conductivity as high as 1000-2000W/mK at room temperature. In the present work, plastic composite with the tubes filler has been prepared as a precursor of carbon nanotubes/carbon composite.
By controlling the precursor structure, the C/C composite has been obtained and the properties of C/C composite are very much depending upon the structure of presursor's. There have been lot of difficulties for preparing the precursor and carbonization as well as graphitization for C/C composite formation, and we can get the composite materials.
The thermal conductivity of the C/C composite is strongly affected by the structure of precursor, and we got the value more than 500W/mK thermal conductivity at room temperature. Not only thermal conductivity, but also other valuable functions have been clarified, which are also promising for future applications.
Present work have reviled the possibility of C/C composites of carbon nanotubes with high thermal conductivity as well as other functional properties, and for preparation of the materials the structural control of resin-based precursors is one of the most important process.

Report

(4 results)
  • 2003 Annual Research Report   Final Research Report Summary
  • 2002 Annual Research Report
  • 2001 Annual Research Report
  • Research Products

    (59 results)

All Other

All Publications (59 results)

  • [Publications] 遠藤守信, 村松寛之, 江坂昌也, 金 隆岩, 林 卓哉: "カーボンナノチューブ、ナノファイバーの量産"繊維と工業. Vo.59,No.12. 14-18 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Y.J.Kim, M.Kojima, Y.Horie, Y.Ohta, M.Endo: "Chemical Activation and Hydrogenation of Mesophase Pitch-based Carbon Fibers -Double-layer Capacitance Performance-"Tanso. No.210. 205-210 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.Endo, Y.A.Kim, T.Hayashi, Y.Fukai, K.Oshida, M.Terrones, T.Yanagisawa, S.Higaki, M.S.Dresselhaus: "Structural characterization of cup-stacked-type nanofibers with and entirely hollow core"Applied Physics Letters. Vol.80,No.7. 1267-1269 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Oshida, K.Osawa, T.Nakazawa, Y.Fukai, T.Hayashi, M.Endo: "Structural analysis of carbon nanofiber by transmission electron microscopy and image processing"Molecular Crystals and Liquid Crystals. Vol.387. [369]/145-[374]/150 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Osawa, K.Oshida, T.Nakazawa, K, Kashiwagi, S.Yamauchi, M.Endo: "Electrochemical characteristics of polyparaphenylene-based carbon"Molecular Crystals and Liquid Crystals. Vol.388. [537]/123-[542]/128 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Miyazaki, K.Oshida, T.Nakatsuka, H.Yamamoto, M.Okamoto, M.Endo: "Analysis of pore structure of activated carbon by using image processing of TEM images"Molecular Crystals and Liquid Crystals. Vol.388. [499]/85-[504]/90 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 押田京一, 遠藤守信: "最新の炭素材料実験技術(分析・解析編)第3章(炭素材料学会編)"サイペック社. 18-26 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.Endo, H.Muramatsu, M.Esaka, Y.A.Kim, T.Hayashi: "Production of Carbon Nanotube and Carbon Nanofiber"SEN'I Gakkaishi. Vol.59,N12. 412-416 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Y.J.Kim, M.Kojima, Y.Horie, Y.Ohta, M.Endo: "Chemical Activation and Hydrogenation of Mesophase Pitch-based Carbon Fibers -Double-layer Capacitance Performance-"Tanso. No.210. 205-210 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.Endo, Y.A.Kim, T.Hayashi, Y.Fukai, K.Oshida, M.Terrones, T.Yanagisawa, S.Higaki, M.S.Dresselhaus: "Structural characterization of cup-stacked-type nanofibers with and entirely hollow core"Applied Physics Letters. Vol.80,No.7. 1267-1269 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Oshida, K.Osawa, T.Nakazawa, Y.Fukai, T.hayashi, M.Endo: "Structural analysis of carbon nanofiber by transmission electron microscopy and image processing"Molecular Crystals and Liquid Crystals. Vol.387. [369]/145-[374]/150 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Osawa, K.Oshida, T.Nakazawa, K.Kashiwagi, S.Yamauchi, M.Endo: "Electrochemical characteristics of polyparaphenylene-based carbon"Molecular Crystals and Liquid Crystals. Vol.388. [537]/123-[542]/128 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Miyazaki, K.Oshida, T.Nakatsuka, H.Yamamoto, M.Okamoto, M.Endo: "Analysis of pore structure of activated carbon by using image processing of TEM images"Molecular Crystals and Liquid Crystals. Vol.388. [499]/85-[504]/90 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Y.A.Kim, T.Hayashi, K.Osawa, M.Endo, M.S.Dresselhaus: "Cone-type multi-shell in the hollow core of multi-wall carbon nanotube"Chemical physics letters. No.367. 537-540 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] M.Endo, Y.A.Kim, T.Hayashi, T.Yanagisawa, H.Muramatsu, M.Ezaka, H.Terrones, M.Terrones, M.S.Dresselhaus: "Microstructural changes induced in ''stacked cup'' carbon nanofibers by heat treatment"Carbon. Vol.41. 1941-1947 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] M.Endo, B.J.Lee, Y.A.Kim, Y.J.Kim, H.Muramatsu, T.Yanagisawa, T.Hayashi, M.Terrones, M.S.Dresselhaus: "Transitional behaviour in the transformation from active end planes to stable loops caused by annealing"New journal of physics. No.5. 121.1-121.9 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] M.Endo, T.Maeda, T.Takeda, Y.J.Kim, K.Kobayashi, H.Hara, M.S.Dresselhaus: "Capacitance and Pore-Size Distribution in Aqueous and Nonaqueous Electrolytes Using Various Activated Carbon Electrodes"Journal of The Electrochemical Society. 148・8. A910-A914 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Y.A.Kim, T.Havashi, Y.Fukai, M.Endo, T.Yanagisawa, M.S.Dresselhaus: "Effect of ball milling on morphology of cup-stacked carbon nanotubes"Chemical Physics Letters. 355. 279-284 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Hayashi, M.Terrones, C Scheu, Y.A.Kim, M.Ruhle, T.Nakajima, M.Endo: "Nanoteflons : Structure and EELS characterization of fluorinated carbon nanotubes and nanofibres"Nano Letters. 2・5. 491-493 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] M.Endo, Y.A.Kim, Fukai, T.Hayashi, K.Oshida, M.Terrones, T Yanagisawa, S.Higaki, M.S.Dresseihaus: "Structural characterization of cup-stacked type nanofibers with an entire hollow core"Applied Physics Letters. 80・7. 1267-1269 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] A.G.Umnov, T.Matsushita, M.Endo, Y.Takeuchi: "Field emission from flexible arrays of carbon nanotubes"Chemical Physics Letters. 356. 391-397 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] M.Endo, Y.J.Kim, T.Takeda, Kishii, T.Inoue, T.Maeda, M.S.Dresselhaus: "Structure and Application of Various Saran-Based Carbons Aqueous Electric Double-Layer Capacitors"Journal of The Electrochemical Society. 149・11. 1473-1480 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] M.Endo, Y.J.Kim, H.Ohta, K.Ishii, T.Inoue, T.Hayashi, Y Nishimura, T.Maeda, M.S.Dresselhaus: "Morphology and organic EDLC applications of chemically activated AR-Resin based carbons"Carbon. 40・14. 2613-2626 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Y.A.Kim, T.Hayashi, K.Osawa, M.Endo, M.S.Dresselhaus: "Cone-type multi-shell in the hollow core of multi-wall carbon nanotube"Chemical Physics Letters. 367・No.5-6. 537-540 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Y.J.Kim, K.Ishii, T.Inoue, M.Endo, M.S.Dresselhaus, T.Nomura, N.Miyashita: "Structure and EDLC applications PVDC based carbons as a function of carbonization time"Molecular Crystals and Liquid Crystals (MCLC), Proceeding of the 1st international symposium on Nanocarbons. 386. 67-72 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] M.Endo: "Tailoring Carbon Nano Structure: Nanocarbons and New Devices"Molecular Crystals and Liquid Crystals (MCLC), Proceeding of the 1st international symposium on Nanocarbons. 386. 159-166 (2000)

    • Related Report
      2002 Annual Research Report
  • [Publications] M.Endo, Y.J.Kim, K.Ishii, T.Inoue, T.Takeda, T.Maeda, T.Nomura, N.Miyashita, M.S.Dresselhaus: "Structure and Application of Various Saran-Based Carbons to Aqueous Electric Double-Layer Capacitors"Journal of The Electrochemical Society. 149・11. A1473-A1480 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] K.Osawa, T.Nakazawa, K.Oshida, M.Endo, M.S.Dresselhaus: "Relation between heat-treatment temperature and characteristics of polyparaphenylene(PPP)-based carbon materials for lithium ion secondary batteries"Materials Research Society.Symposium Proceedings. 699. R7.5.1-R7.5.8 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] K.Osawa, K.Oshida, T.Havashi, M.Endo: "Heat treatment conditions of ployparaphenylene-based carbon for negative electrode of lithium ion secondary batteries"TANSO2002. 205. 255-259 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] M.Endo, Y.J.Kim, K.Ishii, T.Inoue, T.Nomura, N.Miyashita, M.S.Dresselhaus: "Heat treatment retention time dependence of PVDC-based carbons on its application to Electric double layer capacitors"Journal of Materials Research. 18・3. (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] M.Endo, Y.J.Kim, K.Ishii, T.Inoue, T.Nomura, N.Miyashita, M.S.Dresselhaus: "High capacitance EDLC using a carbon material obtained by carbonization of PVIDC, The Effect of the crystallite size of the pristine PVDC"Electrochemical and Solid-State Letters. 6・2. 1 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] Y.A.Kim, T.Hayashi, Y.Fukai, M.Endo, T.Yanagisawa, M.S.Dresselhaus: "Effect of ball milling on morphology of cup-stacked carbon nanotubes"Chemical Physics Letters. 355. 279-284 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Hayashi, M.Terrones, C.Scheu, Y.A.Kim M.Ruhle, T.Nakajima, M.Endo: "Nanoteflons Structure and EELS characterization of fluorinated carbon nanotubes and nanofibres"Nano Letters. 2・5. 491-496 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] M.Endo, Y.A.KIm, T.Fukai, T.Hayashi, K.Oshida, M.Terrones, T.Yanagisawa, S.Higaki, M.S.Dresselhaus: "Structural characterization of cup-stackeed type nanofibers with an entire hollow core"Applied Physics Letters. 80・7. 1267-1269 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Hayashi, Y.A.Kim, Y.Fukai, M Endo, T.Yanagisawa: "HRTEM Observation of ball-milled lampshade carbon nanofiber"Molecular Crystals and Liquid Crystals. 387. 365-368 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] K.Oshida, K.Osawa, T.Nakazawa, Y.Fukai, T.Hayashi, M.Endo: "Structural analysis of carbon nanofiber by transmission electron microscopy and image processing"Molecular and Liquid Crystals. 387. 369-374 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] K.Osawa, K.Oshida, T.Nakazawa, K.Kashiwagi, S.Yamauchi, M.Endo: "Electrochemical characteristics of polyparaphenylene-based carbon"Molecular and Liquid Crystals. 388. 537-542 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] K.Oshida, S.Bonnamy: "Primary Carbonization of an anisotropic "mesophase"pitch compared to conventional isotropic pitch"Carbon. 40・14. 2699-2711 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] K.Osawa, T.Nakazawa, K.Oshida, M.Endo, MS.Dresselhaus: "Relation Between Heat-Treatment Temperature and Characteristics of Polyparaphenylene(PPP)-Based Carbon Materials for Lithium Ion Secondary Batteries"Proc.of MRS Fall Meeting 2001. 699. R7.5.1-R7.5.8 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Miyazaki, K.Oshida, T.Nakatsuka, H.Yamamoto, M.Okamoto, M.Endo: "Analysis of pore structure of activated carbon by using image processing of TEM images"Molecular Crystals and Liquid Crystals. 388. 499-504 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] M.Endo, T.Hayash, Y.A.Kim, H.Ohta, S.H.Hong: "Carbon Alloys, Chapter 3"Novel Concepts to Develop Carbon Science and Technology. 41-55 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] M.Endo, Y.A.Kim: "Carbon Alloys, Chapter 5"Novel Concepts to Develop Carbon Science and Technology. 417-432 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] M.Endo, Y.A.Kim, T.Hayashi(Eds.E.Osawa): "Structure and Applications, in Perspectives of Fullerene Nanotechnology"Kluwer Academic Publishers. 83-92 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Y.A.Kim, T.Hayashi, Y.Fukai, M.Endo, T.Yanagisawa, M.S.Dresselhaus: "Effect of ball milling on morphology of cup-stacked carbon nanotubes"Chemical Physics Letters. (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] M.Endo, Y.A.Kim, T.Hayashi, Y.Fukai, K.Oshida, M.Terrones, T.Yanagisawa, S.Higaki, M.S.Dresselhaus: "Structural characterization of cup-stacked-type nanofibers with an entirely hollow core"Applied Physics Letters. 80・7. 1267-1269 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 前田崇志, 金 龍中, 小柴健二, 石井聖啓, 笠井利幸, 遠藤守信, 西村嘉介, 河淵祐二: "メソフェーズピッチ系炭素繊維のKOH賦活"炭素. 201. 7-11 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] M.Endo, T.Hayashi, Seong-Hwa Hong, T.Enoki, M.S.Dresselhaus: "Scanning tunneling microscope study of boron-doped highly oriented pyrolytic graphite"Journal of Applied Physics. 90・11. 5670-5674 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] M.Endo, Y.A.Kim, Y.Fukai, M.Terrones, H.Terrones, M.S.Dresselhaus: "Comparison study of semi-crystalline and highly crystalline multiwalled carbon nanotubes"Applied Physics Letters. 79・10. (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] M.Endo, Y.A.Kim, T.Takeda, S.H.Hong, T.Matsushita, T.Hayashi, M.S.Dresselhaus: "Structural characterization of carbon nanofibers obtained by hydrocarbon pyrolysis"Carbon. 39. 2003-2010 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Y.A.Kim, T.Matsushita, T.Hayashi, M.Endo, M.S.Dresselhaus: "Topological changes of vapor grown carbon fibers during heat treatment"Carbon. 39. 1747-1752 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] H.Terrones, T.Hayashi, M.Munoz-Navia, M.Terrones, Y.A.Kim, N.Grobert, R.Kanalakaran, J.Dorantes-Davila, R.Escudero, M.S.Dresselhaus, M.Endo: "Graphitic cones in palladium catalysed carbon nanofibers"Chemical Physics Letters. 343. 241-250 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] M.Inagaki, K.Fujita, Y.Takeuchi, K.Oshida, H.Iwata, H.Konno: "Formation of graphite crystals at 1000-1200℃ from mixtures of vinyl polymers with oxides"Carbon. 39. 921-929 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] T.Nakazawa, K.Oshida, T.Miyazaki, M.Endo, M.S.Dresselhaus: "A structural analysis method for graphite intercalation compounds"Proc. of MRS Fall Meeting. 658. GG6.18.1-GC6.18.6 (2001)

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      2001 Annual Research Report
  • [Publications] K.Oshida, T.Nakazawa, T.Miyazaki, M.Endo: "Application of image processing techniques for analysis of nano-and micro-space in carbon materials"Synthetic Metals. 125. 223-230 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] K.Oshida, S.Bonnamy: "Primary Carbonization of an anisotropic "mesophase" pitch compared to conventional isotropic pitch"Carbon. (in press).

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      2001 Annual Research Report
  • [Publications] 林 卓哉, 遠藤守信, 松下卓生: "カーボンナノチューブ-ナノデバイスへの挑戦-,第7章,カーボンナノチューブの機械的強度"化学同人. 111-117 (2001)

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      2001 Annual Research Report
  • [Publications] M.Endo, Y.A.Kim, T.Matsushita, T.Hayashi: "From vapor-grown carbon fibers(VGCFs)to carbon nanotubes, Carbon Filaments and Nanotubes : Common Origins, Differing Applications, Editors by L.P.Biro, et al."Kluwer Academic Publishers. 51-61 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] M.Endo, Y.A.Kim, K.Nishimura, T.Hayashi, T.Matsushita: "Preparation and structure of carbon fibers and carbon nanotubes from the vapour phasa : Design and Control of Structure of Advanced Carbon Materials for Enhanced Performance, Editors by B.Rand, et al."Kluwer Academic Publishers. 207-216 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 押田京一, 遠藤守信: "最新の炭素材料実験技術(分析・解析技術),炭素材料学会編,第3章"サイペック社. 18-26 (2001)

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      2001 Annual Research Report

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Published: 2001-04-01   Modified: 2016-04-21  

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