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Gas separation and pervaporation through membranes with ultra-micropores

Research Project

Project/Area Number 13355031
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section展開研究
Research Field 反応・分離工学
Research InstitutionYamaguchi University

Principal Investigator

OKAMOTO Kenichi  Yamaguchi University, Faculty of Engineering, Professor, 工学部, 教授 (20029218)

Co-Investigator(Kenkyū-buntansha) YOSHINO Makoto  Yamaguchi University, Faculty of Engineering, Assistant, 工学部, 助手 (60311817)
TANAKA Kazuhiro  Yamaguchi University, Faculty of Engineering, Associate Professor, 工学部, 助教授 (30188289)
KITA Hidetoshi  Yamaguchi University, Faculty of Engineering, Professor, 工学部, 教授 (10177826)
KONDO Masakazu  Mitsui Eng.Shipbuilding Co.Ltd., Research Dept., Manager, 技術本部・主幹研究員
KUSUKI Yoshihiro  Ube Ind.Ltd., Research Dept., Manager, 研究開発本部, 主席研究員
Project Period (FY) 2001 – 2003
Project Status Completed (Fiscal Year 2003)
Budget Amount *help
¥50,700,000 (Direct Cost: ¥39,000,000、Indirect Cost: ¥11,700,000)
Fiscal Year 2003: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2002: ¥20,150,000 (Direct Cost: ¥15,500,000、Indirect Cost: ¥4,650,000)
Fiscal Year 2001: ¥24,960,000 (Direct Cost: ¥19,200,000、Indirect Cost: ¥5,760,000)
KeywordsMembrane Separation / Zeolite Membrane / Pervaporation / Gas Separation / Molecular Sieve Carbon Membrane / Microporous Membrane / Nano Technology / 分子ふるい膜 / ガス分離 / メンブレンリアクター
Research Abstract

Gas separation and pervaporation properties of microporous membranes derived from zeolites and molecular sieving carbon materials are developed. Compared with conventional polymeric membranes, these membranes are promising candidates for a high performance membrane. Here, we reported on the hydrothermal synthesis of Silicalite and zeolite Y and T membranes, and their pervaporation properties. The performance of these membranes is the most favorable one for pervaporation. Carbon membranes derived from a phenolic resin and polyimides were also investigated in order to develop a novel membrane that exhibits both high permeability and high selectivity

Report

(4 results)
  • 2003 Annual Research Report   Final Research Report Summary
  • 2002 Annual Research Report
  • 2001 Annual Research Report
  • Research Products

    (35 results)

All Other

All Publications (35 results)

  • [Publications] X.Lin, H.Kita, K.Okamoto: "Silica lite Membrane Preparation, Characterization, and Separation Performance"Ind.Eng.Chem.Res.. 40. 4069-4078 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Kita, K.Fuchida et al.: "Preparation of Faugasite Membrane and their Permeation Properties"Separation Purification Tech.. 25. 261-268 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] W.Zhou, M.Yoshino et al.: "Carbon Molecular Sieve Membranes derived from Phenolic Resin"Ind.Eng.Chem.Res.. 40. 4801-4807 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] W.Zhou, T.Watari et al.: "Gas Permeation Properties of Flexible Pyrolytic Membranes from Sulfonated Polyimides"Chem.Lett.. 534-535 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.Kondo, T.Nakane et al.: "Pervaporation and Vapor Permeation Properties of Commercialized T-type zeolite Membranes"Trans.Meter.Res.Soc.Jpn. 27. 395-398 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Tanaka, R.Yoshikawa et al.: "Application of Zeolite T Membrane to Vapor-Permeation-aided Esterification"Chem.Eng.Sci.. 57. 1577-1584 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Kita: "Fabrication and Application of Zeolite Membranes"MRS Proceedings. 752. 239-249 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] X.Lin, X.Chen et al.: "Synthesis of Silicalite Tubular Membranes by in Situ Crystallization"AIChE J.. 49. 237-247 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] W.Zhou, M.Yoshino et al.: "Preparation on a Gas Permeation Properties of Carbon Molecular Sieve Membranes"J.Membr.Sci.. 217. 55-67 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Y.Cui, H.Kita et al.: "Preparation and Gas Separation of Zeolite T Membranes"J.Chem.Soc.Chem.Comm. 2154-2155 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Y.Cui, H.Kita et al.: "Preparation and Gas Separation of Zeolite T Membrane"J.Mater.Chem.. 14. 924-932 (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Y.Cui, H.Kita, K.Okamoto: "Zeolite T Membrane : Preparation, Characterization Pervaporation of water/organic liquid"J.Membr.Sci.. 236. 17-27 (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] X.Lin, H.Kits, K.Okamoto: "Silicalite Membrane Preparation, Characterization, and Separation Performance"Ind.Eng.Chem.Res.. 40. 4069-4078 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Kita, K.Fuchida, T.Horita, H.Asamura, K.Okamoto: "Preparation of Faujasite Membranes and their Permeation Properties"Sep.Purification Tech.. 25. 261-268 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] W.Zhou, M.Yoshino, H.Kita, K.Okamoto: "Carbon Molecular Sieve Membranes Derived from Phenolic Resin with a Pendant Sulfonic Acid Group"Ind.Eng.Chem.Res.. 40. 4801-4807 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Tanaka, R.Yoshikawa, C.Ying, H.Kita, K.Okamoto.: "Application of Zeolite Membranes to Esterification Reactions"Catalysis Today. 67. 121-125 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] W.Zhou, T.Watari, H.Kita, K.Okamoto: "Gas Permeation Properties of Flexible Pyrolytic Membranes from Sulfonated Polyimides"Chem.Lett.. 534-535 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.Kondo, T.Nakane, H.Kita, K.Okamoto: "Pervaporation and Vapor Permeation Properties of Commercialized T type Zeolite Membranes"Trans.Mater.Res.Soc.Jpn.. 27. 395-398 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Tanaka, R.Yoshikawa, C.Ying, H.Kita, K.Okamoto: "Application of Zeolite T Membrane to Vapor-permeation aided Esterification of Lactic Acid with Ethanol"Chem.Eng.Sci.. 57. 1577-1584 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Kita: "Fabrication and Application of Zeolite Membranes"MRS Proceedings. 752. 239-249 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] X.Lin, X.Chen, H.Kits, K.Okamoto: "Synthesis of Silicalite Tubular Membranes by In Situ Crystallization"AIChE J.. 49. 237-247 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] W.Zhou, M.Yoshino, H.Kita, K.Okamoto: "Preparation and Gas Permeation Properties of Carbon Molecular Sieve Membranes based on Sulfonated Phenolic Resin"J.Membr.Sci.. 217. 55-67 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Y.Cui, H.Kits, K.Okamoto: "Preparation and Gas Separation Properties of Zeolite T Membrane"J.Chem.Soc.Chem.Comm. 2154-2155 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Y.Cui, H.Kita, K.Okamoto: "Preparation and Gas Separation Performance of Zeolite T Membrane"J.Mater.Chem.. 14. 924-932 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Ying Cui et al.: "Preparation and gas separation properties of zeolite T membrane"Chem.Commun.. 2154-2155 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Weiliang Zhou et al.: "Preparation and gas permeation properties of Carbon molecular sieve membranes based on gulfonated phendic resin"J.Membr.Sci.. 217. 55-67 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Ying Cui et al.: "Preparation and gas separation performance of zeolite T membrane"J.Mater.Chem.. 14. 924-932 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Ying Cui et al.: "Zoolite T membrane : Preparation, Characterization, pervaporation of water/organic liquid and stability"J.Membr.Sci.. (in press). (2000)

    • Related Report
      2003 Annual Research Report
  • [Publications] Makoto Yoshino: "Olefin/Paraffin separation performance of asymmetric hollow fiber membrane of 6FDA/BPDA-DDBT copolyimide"J.Membr.Sci.. 212巻. 13-27 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] Xiao Lin: "Synthesis of Silicalite Tubular Membranes by In situ Crystallization"AIChE Journal. 49巻1号. 237-247 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] Weiliang Zhou: "Gas Permeation Properties of Flexible Pyrolytic Membranes from Sulfonated Polyimides"Chem.Letters. 2002,5号. 534-535 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Makoto Yoshino: "Olefin/Paraffin separation performance of carbonized membranes denied from an asymmetric hollow fiber membrane of 6FDA/BPDA-DDBT copolyimide"J.Membr.Sci.. (in press). (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] Weiliang Zhou: "Preparation and Gas Permeation Properties of Carbon Moleculor sieve membranes Based on Sulfonated phenplic Resin"J.Membr.Sci.. (in press). (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] Weiliang Zhou 他: "Gas Permeation Properties of Flexible Pyrolytic Membranes from Sulfonated Polycimides"Chemistry Letters. (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] Kazuhiro Tanaka 他: "Application of Zeolite T Membrane to Vapor-Permeation-Fided Esterification of Lactic Acid with Ethanol"Chemical Engineering Science. (2002)

    • Related Report
      2001 Annual Research Report

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Published: 2001-04-01   Modified: 2016-04-21  

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