• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Construction of new electrochemical-membrane-reactor system for simulutaneous environmental purification/chemical conversation

Research Project

Project/Area Number 13355032
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section展開研究
Research Field 工業物理化学
Research InstitutionKYUSHU UNIVERSITY

Principal Investigator

MIURA Norio  KYUSHU UNIVERSITY, Art, Science and Technology for Cooperative Research, Prof., 産学連携センター, 教授 (70128099)

Co-Investigator(Kenkyū-buntansha) SAKAI Go  KYUSHU UNIVERSITY, Faculty of Engineering Sciences, Research Associate, 大学院・総合理工学研究院, 助手 (40284567)
YAMAZOE Noboru  KYUSHU UNIVERSITY, Faculty of Engineering Sciences, Prof., 大学院・総合理工学研究院, 教授 (40037817)
TERAOKA Yasutake  KYUSHU UNIVERSITY, Faculty of Engineering Sciences, Prof., 大学院・総合理工学研究院, 教授 (70163904)
SETOGUCHI Toshihiko  Mitsubishi Heavy Industries, Ltd., Nagasaki R & D Center, Leader, 長崎研究所, 主任
ISHIHARA Tatsumi  KYUSHU UNIVERSITY, Faculty of Engineering Sciences, Prof., 大学院・工学研究院, 教授 (80184555)
正宝 敏貴  麻生セメント(株), 中央研究所, 研究員
Project Period (FY) 2001 – 2003
Project Status Completed (Fiscal Year 2003)
Budget Amount *help
¥50,180,000 (Direct Cost: ¥38,600,000、Indirect Cost: ¥11,580,000)
Fiscal Year 2003: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Fiscal Year 2002: ¥15,860,000 (Direct Cost: ¥12,200,000、Indirect Cost: ¥3,660,000)
Fiscal Year 2001: ¥27,950,000 (Direct Cost: ¥21,500,000、Indirect Cost: ¥6,450,000)
KeywordsMixed conductor / Perovskite / Membrane reactor / Oxygen permeating membrane / Environmental purification / Partial oxidation of methane / Nitrogen oxide / メンブレンリアクタ / 窒素酸化物 / 混合誘導体 / NO_X分解 / NO_x分解
Research Abstract

In this research project, we investigated each process of the newly proposed electrochemical membrane-reactor system and obtained the following results.
(1)Oxygen permeation property of the barium ferrites(Ba-Fe system) was examined. Partial substitution of Ba by rare earth metals as well as alkaline earth metals was found to stabilize cubic perovskite structure even at room temperature. It was also found that oxygen permeation appeared at lower temperature. Partial substitution of Fe by Ni,Mg,or Zn was quite effective for improvement of oxygen permeability. (2)Fe/Mn-based perovskites exhibited oxygen permeability and high stability against the reduction, and could be used as quite stable oxygen permeable membranes in the membrane reactors catalyzing the partial oxidation of methane and the reduction of NO by methane. In addition, Ba/Sr/Fe-based perovskites was found to be one of most excellent oxygen permeable materials. (3)Perovskite oxide of LaGaO_3 doped with Sr and Fe(LSGF) was found to exhibit high electrical conductivity, oxygen permeation rate and chemical stability, and this LSGF could be used for oxygen permeation membrane for CH_4 partial oxidation. Hole conduction is dominant in LSGF in wide Po_2 range and temperature. In addition, oxygen permeation rate in various oxides was investigated and Pr_2NiO_4 doped with Gu was found to give high oxygen permeation rate from air to He. (4)Preparation of porous disk was attempted to fabricate thin films on it for the purpose of improving oxygen permeability of mixed conductive perovskite-type oxides. Oxalate precursor method was found to give porous disks with a narrow distribution of pore diameter even at elevated temperature. The disks obtained by the oxalate precursor method showed high nitrogen-permeability feasible for practical applications.

Report

(4 results)
  • 2003 Annual Research Report   Final Research Report Summary
  • 2002 Annual Research Report
  • 2001 Annual Research Report
  • Research Products

    (48 results)

All Other

All Publications (48 results)

  • [Publications] T.Ishihara: "Partial Oxidation of CH_4 by Oxygen-permeating Membrane Reactor Using LaGaO_3 Doped with Fe and Sr"Journal of the Japan Petroleum Institute. 45. 32-38 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Kinoshita: "Influences of A-site Partial Substitution for BaCo_<0.7>Fe_<0.3>O_3 Oxide on Perovskite Structure and Oxygen Permeability"Chemistry Letters. 2002(2). 344-345 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Kinoshita: "High Temperature PTC Thermistor Using Ba Cobaltite"Chemistry Letters. 2002(2). 412-413 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Kusaba: "Temperature-swing based Oxygen Enrichment by Using Perovskite-type Oxides"Journal of Materials Science Letters. 21. 407-409 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Kusaba: "Oxygen-sorptive and -desorptive Properties of Perovskite-related Oxides under Temperature-swing Conditions for Oxygen Enrichment"Solid State Ionics. 152/153. 689-694 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Ishihara: "Fe-Doped LaGaO_3-Based Perovskite Oxide as an Oxygen-Separating Membrane for CH_4 Partial Oxidation"Materials for Electrochemical Energy Conversion and Storage, Ceramic Transactions. 127. 69-77 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Ishihara: "Mixed Electronic-oxide Ionic Conductor of BaCoO_3 Doped with La for Cathode of Intermediate Temperature-operating Solid Oxide Fuel Cell"Solid State Ionics. 152-153. 609-613 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Ishihara: "Fe doped LaGaO_3 Perovskite Oxide as an Oxygen Separating Membrane for CH_4 Partial Oxidation"Solid State Ionics. 152-153. 709-714 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Y.Teraoka: "Catalytic Effects in Oxygen Permeation through Mixed-conductive LSCF Perovskite Membranes"Solid State Ionics. 152-153. 681-687 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Ishihara: "La(Sr)Ga(Fe)O_3 Perovskite Oxide as a New Mixed Ionic-Electronic Conductor for Oxygen Permeating Membrane"Journal of The Electrochemical Society. 150. 17-23 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 石原達己: "酸素透過性混合伝導体の現状と触媒反応への応用"触媒. 45. 263-268 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Ishihara: "Oxide Ion and Electronic Conductivity in Co Doped La_<0.8>Sr_<0.2>Ga_<0.8>Mg_<0.2>O_3 Perovskite Oxide"Phys.Chem.Chem.Phys. 2002(5). 2257-2263 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Lee: "Oxygen-permeating Property of LaSrBFeO_3 (B=Co, Ga) Perovskite Membrane Surface Modified by LaSrCoO_3"Solid State Ionics. 158. 287-296 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Kinoshita, H.Kusaba, G.Sakai, K.Shimanoe, N.Miura, N.Yamazoe: "Influences of A-site Partial Substitution for BaCo_<0.7>Fe_<0.3>O_3 Oxide on Perovskite Structure and Oxygen Permeability"Chemistry Letters. 2002(2). 344-345 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Ishihara, Y.Tsuruta, T.Todaka, H.Nishiguchi, Y.Takita: "Partial Oxidation of CH_4 by Oxygen-permeating Membrane Reactor Using LaGaO_3 Doped with Fe and Sr."Journal of the Japan Petroleum Institute. 45(1). 32-38 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Kinoshita, H.Kusaba, G.Sakai, K.Shimanoe, N.Miura, N.Yamazoe: "High Temperature PTC Thermistor Using Ba Cobaltite"Chemistry Letters. 2002(2). 412-413 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Kusaba, G.Sakai, K.Shimanoe, N.Miura, N.Yamazoe: "Temperature-swing based Oxygen Enrichment by Using Perovskite-type Oxides"Journal of Materials Science Letters. 21. 407-409 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Kusaba, G.Sakai, K.Shimanoe, N.Miura, N.Yamazoe: "Oxygen-sorptive and-desorptive Properties of Perovskite-related Oxides under Temperature-swing Conditions for Oxygen Enrichment"Solid State Ionics. 152/153. 689-694 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Ishihara, Y.Tsuruta, H.Nishiguchi, Y.Takita: "Fe-Doped LaGaO_3-Based Perovskite Oxide as an Oxygen-Separating Membrane for CH4 Partial Oxidation, Materials for Electrochemical Energy Conversion and Storage"Ceramic Transactions. 127. 69-77 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Ishihara, S.Fukui, H.Nishiguchi, Y.Takita: "Mixed Electronic-oxide Ionic Conductor of BaCoO_3 Doped with La for Cathode of Intermediate Temperature-operating Solid Oxide Fuel Cell"Solid State Ionics. 152-153. 609-613 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Ishihara, Y.Tsuruta, T.Todaka, H.Nishiguchi, Y.Takita: "Fe doped LaGaO_3 Perovskite Oxide as an Oxygen Separating Membrane for CH4 Partial Oxidation"Solid State Ionics. 152-153. 709-714 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Y.Teraoka, Y.Honbe, J.Ishii, H.Furukawa, I.Moriguchi: "Catalytic Effects in Oxygen Permeation through Mixed-conductive LSCF Perovskite Membranes"Solid State Ionics. 152-153. 681-687 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Ishihara, Y.Tsuruta, Y.Chunying, T.Todaka, H.Nishiguchi, Y.Takita: "La(Sr)Ga(Fe)O_3 Perovskite Oxide as a New Mixed Ionic-Electronic Conductor for Oxygen Permeating Membrane"Journal of The Electrochemical Society. 150(1). 17-23 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Ishihara: "Mixed Ionic Electronic Ceramic Membrane for Oxygen Permeation and Its Application for Catalytic Reaction"Shokubai. 45(3). 263-268 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Ishihara, S.Ishikawa, C.Yu, T.Akbay, K.Hosoi, H.Nishiguchi, Y.Takita: "Oxide Ion and Electronic Conductivity in Co Doped La_<0.8>Sr_<0.2>Ga_<0.8>Mg_<0.2>O_3 Perovskite Oxide"Phys.Chem.Chem.Phys.. 2003(5). 2257-2263 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Lee, K.S.Lee, S.K.Woo, J.W.Kim, T.Ishihara, D.K.Kim: "Oxygen-permeating Property of LaSrBFeO_3(B=Co,Ga) Perovskite Membrane Surface Modified by LaSrCoO_3"Solid State Ionics. 158. 287-296 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] N.Miura, Y.Teraoka, T.Ishihara, N.Yamazoe, A.Yamashita: "Membrane Reactor Device and Gas Synthesis System, Japanese Published Patent Application"12401 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Ishihara et al.: "Oxide ion and electronic conductivity in Co doped La_<0.8>Sr_<0.2>Ga_<0.8>Mg_<0.2>O_3 perovskite oxide"Phys.Chem.Chem.Phys.. 2003・5. 2257-2263 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Shiwoo Lee et al.: "Oxygen-permeating property of LaSrBFeO_3 (B=Co, Ga) perovskite membrane surface modified by LaSrCoO_3"Solid State Ionics. 158. 287-296 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 石原達己: "酸素透過性混合伝導体の現状と触媒反応への応用"触媒. 45・No3. 263-268 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Kazuya Kinoshita: "Influence of A-Site Partial Substitution for BaCo0.7Fe0.3O3 Oxide on Perovskite Structure and Oxygen Permeability"Chemistry Letters. 3. 344-345 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Kazuya Kinoshita: "High Temperature PTC Thermistor Using Ba Cobaltite"Chemistry Letters. 3. 412-413 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] H.Kusaba: "Temperature-swing based oxygen enrichment by using perovskite-type oxies"The Journal of Materials Science Letters. 21. 407-409 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] H.Kusaba: "Oxygen-sorptive and -desorptive properties of perovskite-related oxides under temperature-swing conditions for oxygen enrichment"Solid State Ionics. 152-153. 689-694 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Y.Teraoka: "Catalytic Effects in Oxygen Permeation through Mixed-Conductive LSCF Perovskite Membranes"Solid State Ionics. 152-153. 681-687 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Ishihara: "La(Sr)Ga(Fe)O_3 Perovskite Oxide (LSGF) as a New Mixed Ionic-Electronic Conductor for Oxygen Permeating Membrane"J. Electrochem. Soc. 150. E17-E23 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Ishihara: "Fe doped LaGaO_3 perovskite oxide as an oxygen separating membrane for CH_4 partial oxidation"Solid Sate Ionics. 152-153. 709-714 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Ishihara: "Mixed electronic-oxide ionic conductor of BaCO_3 doped with La for cathode of intermediate Temperature operating solid oxide fuel cell"Solid Sate Ionics. 152-153. 609-615 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 石原達己: "Fe, Sr添加LaGaO_3系酸化物を酸素分離膜に用いた膜型反応器によるCH_4部分酸化反応"Japan Petroleum Institute. 45. 32-38 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Kazuya Kinoshita: "Influence of A-Site Partial Substitution for BaCo0.7Fe0.3O3 Oxide on Perovskite Structure and Oxygen Permeability"Chemistry Letters. (印刷中). (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] Kazuya Kinoshita: "High Temperature PTC Thermistor Using Ba Cobaltite"Chemistry Letters. (印刷中). (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] H.Kusaba: "Temperature-swing based oxygen enrichment by using perovskite-type oxies"The Journal of Materials Science Letters. (印刷中). (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] H.Kusaba: "Oxygen-sorptive and -desorptive properties of perovskite-related oxides under temperature-swing conditions for oxygen enrichment"Solid State Ionics. (印刷中). (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] 寺岡靖剛: "酸素イオンと電子を運ぶ酸化物混合導電体-省エネルギー型酸素選択透過膜としての展開"化学. 56・12. 68-69 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Y.Teraoka: "Catalytic effects in oxygen permeation through mixed-conductive LSCF perovskite membranes"Solid State Ionics. (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] 石原達己: "Fe, Sr添加LaGaO3系酸化物を酸素分離膜に用いた膜型反応器によるCH_4部分酸化反応"J.Japan Petroleum Institute. 45. 32-38 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] Y.Tsuruta: "Mixed Electronic-oxide Conductor or Fe doped La(Sr)GaO_3 Perovskite Oxide for Oxygen Permeating Membrane"Electrochem. & Solid-State Lett.. 4・3. 13-15 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] T.Ishihara: "La(Sr)Ga(Fe)O_3 Perovskite Oxide As a New Mixed Conductor For An Oxygen Separating Membrane"Ionics and Mixed Conducting Ceramics, Electrochemical Society. (印刷中). (2002)

    • Related Report
      2001 Annual Research Report

URL: 

Published: 2001-04-01   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi